Research output: Contribution to journal › Article › peer-review
FAST METHOD FOR STUDYING THE EXTRACTION OF THE MAIN HLW COMPONENTS WITH CROWN ETHERS IN NEW FLUORINE-CONTAINING DILUENTS. / Timoshenko, V. V.; Brechalov, A. A.; Ermolenko, Y. E.; Smirnov, I. V.
In: RAD Conference Proceedings, Vol. 5, 01.01.2021, p. 42-47.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - FAST METHOD FOR STUDYING THE EXTRACTION OF THE MAIN HLW COMPONENTS WITH CROWN ETHERS IN NEW FLUORINE-CONTAINING DILUENTS
AU - Timoshenko, V. V.
AU - Brechalov, A. A.
AU - Ermolenko, Y. E.
AU - Smirnov, I. V.
N1 - V.V. Timoshenko, A.A. Brechalov, Y.E. Ermolenko, I.V. Smirnov, "Fast method for studying the extraction of the main hlw components with crown ethers in new fluorine-containing diluents", RAD Conf. Proc, vol. 5, 2021, pp. 42-47, http://doi.org/10.21175/RadProc.2021.08
PY - 2021/1/1
Y1 - 2021/1/1
N2 - The study of the interphase distribution of a large number of target and impurity components of highly radioactive wastes is a necessary and very laborious stage in the creation of new extraction systems. With the quantitative extraction of cesium-137 and strontium-90 from spent nuclear fuel for the purposes of further industrial and commercial use, difficulties arise associated with competing complexation and the concomitant extraction of impurities of stable elements. We have developed an express method for determining the distribution ratios of metals using inductively coupled plasma mass spectrometry (ICP-MS). A feature of the proposed method is the joint extraction of trace amounts of all studied metals, followed by direct ICP-MS analysis of equilibrium aqueous and organic phases.
AB - The study of the interphase distribution of a large number of target and impurity components of highly radioactive wastes is a necessary and very laborious stage in the creation of new extraction systems. With the quantitative extraction of cesium-137 and strontium-90 from spent nuclear fuel for the purposes of further industrial and commercial use, difficulties arise associated with competing complexation and the concomitant extraction of impurities of stable elements. We have developed an express method for determining the distribution ratios of metals using inductively coupled plasma mass spectrometry (ICP-MS). A feature of the proposed method is the joint extraction of trace amounts of all studied metals, followed by direct ICP-MS analysis of equilibrium aqueous and organic phases.
KW - Cesium
KW - crown ethers
KW - distribution ratios
KW - extraction
KW - fluorinated diluents
KW - High Level Radioactive Waste (HLW)
KW - Inductively Coupled Plasma Mass Spectrometry (ICP-MS)
KW - separation of radionuclides
KW - spent nuclear fuel (SNF)
KW - strontium
UR - http://www.scopus.com/inward/record.url?scp=85131860725&partnerID=8YFLogxK
U2 - 10.21175/RadProc.2021.08
DO - 10.21175/RadProc.2021.08
M3 - Article
AN - SCOPUS:85131860725
VL - 5
SP - 42
EP - 47
JO - RAD Conference Proceedings
JF - RAD Conference Proceedings
SN - 2466-4626
ER -
ID: 102400896