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FAST METHOD FOR STUDYING THE EXTRACTION OF THE MAIN HLW COMPONENTS WITH CROWN ETHERS IN NEW FLUORINE-CONTAINING DILUENTS. / Timoshenko, V. V.; Brechalov, A. A.; Ermolenko, Y. E.; Smirnov, I. V.

In: RAD Conference Proceedings, Vol. 5, 01.01.2021, p. 42-47.

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@article{736b826948324c14acfbae2285eaa9b5,
title = "FAST METHOD FOR STUDYING THE EXTRACTION OF THE MAIN HLW COMPONENTS WITH CROWN ETHERS IN NEW FLUORINE-CONTAINING DILUENTS",
abstract = "The study of the interphase distribution of a large number of target and impurity components of highly radioactive wastes is a necessary and very laborious stage in the creation of new extraction systems. With the quantitative extraction of cesium-137 and strontium-90 from spent nuclear fuel for the purposes of further industrial and commercial use, difficulties arise associated with competing complexation and the concomitant extraction of impurities of stable elements. We have developed an express method for determining the distribution ratios of metals using inductively coupled plasma mass spectrometry (ICP-MS). A feature of the proposed method is the joint extraction of trace amounts of all studied metals, followed by direct ICP-MS analysis of equilibrium aqueous and organic phases.",
keywords = "Cesium, crown ethers, distribution ratios, extraction, fluorinated diluents, High Level Radioactive Waste (HLW), Inductively Coupled Plasma Mass Spectrometry (ICP-MS), separation of radionuclides, spent nuclear fuel (SNF), strontium",
author = "Timoshenko, {V. V.} and Brechalov, {A. A.} and Ermolenko, {Y. E.} and Smirnov, {I. V.}",
note = "V.V. Timoshenko, A.A. Brechalov, Y.E. Ermolenko, I.V. Smirnov, {"}Fast method for studying the extraction of the main hlw components with crown ethers in new fluorine-containing diluents{"}, RAD Conf. Proc, vol. 5, 2021, pp. 42-47, http://doi.org/10.21175/RadProc.2021.08",
year = "2021",
month = jan,
day = "1",
doi = "10.21175/RadProc.2021.08",
language = "English",
volume = "5",
pages = "42--47",
journal = "RAD Conference Proceedings",
issn = "2466-4626",
publisher = "RAD Association",

}

RIS

TY - JOUR

T1 - FAST METHOD FOR STUDYING THE EXTRACTION OF THE MAIN HLW COMPONENTS WITH CROWN ETHERS IN NEW FLUORINE-CONTAINING DILUENTS

AU - Timoshenko, V. V.

AU - Brechalov, A. A.

AU - Ermolenko, Y. E.

AU - Smirnov, I. V.

N1 - V.V. Timoshenko, A.A. Brechalov, Y.E. Ermolenko, I.V. Smirnov, "Fast method for studying the extraction of the main hlw components with crown ethers in new fluorine-containing diluents", RAD Conf. Proc, vol. 5, 2021, pp. 42-47, http://doi.org/10.21175/RadProc.2021.08

PY - 2021/1/1

Y1 - 2021/1/1

N2 - The study of the interphase distribution of a large number of target and impurity components of highly radioactive wastes is a necessary and very laborious stage in the creation of new extraction systems. With the quantitative extraction of cesium-137 and strontium-90 from spent nuclear fuel for the purposes of further industrial and commercial use, difficulties arise associated with competing complexation and the concomitant extraction of impurities of stable elements. We have developed an express method for determining the distribution ratios of metals using inductively coupled plasma mass spectrometry (ICP-MS). A feature of the proposed method is the joint extraction of trace amounts of all studied metals, followed by direct ICP-MS analysis of equilibrium aqueous and organic phases.

AB - The study of the interphase distribution of a large number of target and impurity components of highly radioactive wastes is a necessary and very laborious stage in the creation of new extraction systems. With the quantitative extraction of cesium-137 and strontium-90 from spent nuclear fuel for the purposes of further industrial and commercial use, difficulties arise associated with competing complexation and the concomitant extraction of impurities of stable elements. We have developed an express method for determining the distribution ratios of metals using inductively coupled plasma mass spectrometry (ICP-MS). A feature of the proposed method is the joint extraction of trace amounts of all studied metals, followed by direct ICP-MS analysis of equilibrium aqueous and organic phases.

KW - Cesium

KW - crown ethers

KW - distribution ratios

KW - extraction

KW - fluorinated diluents

KW - High Level Radioactive Waste (HLW)

KW - Inductively Coupled Plasma Mass Spectrometry (ICP-MS)

KW - separation of radionuclides

KW - spent nuclear fuel (SNF)

KW - strontium

UR - http://www.scopus.com/inward/record.url?scp=85131860725&partnerID=8YFLogxK

U2 - 10.21175/RadProc.2021.08

DO - 10.21175/RadProc.2021.08

M3 - Article

AN - SCOPUS:85131860725

VL - 5

SP - 42

EP - 47

JO - RAD Conference Proceedings

JF - RAD Conference Proceedings

SN - 2466-4626

ER -

ID: 102400896