Fabrication and characterization of polyamide-fullerenol thin film nanocomposite hollow fiber membranes with enhanced antifouling performance

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Fabrication and characterization of polyamide-fullerenol thin film nanocomposite hollow fiber membranes with enhanced antifouling performance. / Plisko, Tatiana V.; Liubimova, Alena S.; Bildyukevich, Alexandr V.; Penkova, Anastasia V.; Dmitrenko, Maria E.; Mikhailovskii, Vladimir Y.; Melnikova, Galina B.; Semenov, Konstantin N.; Doroshkevich, Nelya V.; Kuzminova, Anna I.

In: Journal of Membrane Science, Vol. 551, 01.04.2018, p. 20-36.

Research output: Contribution to journal › Article › peer-review

Author

Plisko, Tatiana V. ; Liubimova, Alena S. ; Bildyukevich, Alexandr V. ; Penkova, Anastasia V. ; Dmitrenko, Maria E. ; Mikhailovskii, Vladimir Y. ; Melnikova, Galina B. ; Semenov, Konstantin N. ; Doroshkevich, Nelya V. ; Kuzminova, Anna I. / Fabrication and characterization of polyamide-fullerenol thin film nanocomposite hollow fiber membranes with enhanced antifouling performance. In: Journal of Membrane Science. 2018 ; Vol. 551. pp. 20-36.

BibTeX

@article{8e8d133b58884137b3a6ce4aa1b8d255,

title = "Fabrication and characterization of polyamide-fullerenol thin film nanocomposite hollow fiber membranes with enhanced antifouling performance",

abstract = "Fullerenol C60(OH)22 – 24 was incorporated into the polyamide (PA) selective layer to develop novel thin film nanocomposite (TFN) hollow fiber membranes for low molecular weight cut-off ultrafiltration. TFN membranes were fabricated via interfacial polymerization technique by alternately pumping fullerenol dispersion in triethylenetetramine (TETA) aqueous solution and isophthaloyl chloride solution in hexane through polysulfone hollow fiber membranes. Developed TFN PA/fullerenol membranes were investigated by FTIR, Raman spectroscopy, SEM, TEM, AFM, contact angle measurements and evaluated by determining the permeability, rejection and antifouling performance. Introduction of fullerenol to the PA skin layer was revealed to yield in the decrease of pure water flux and slight increase of lysozyme rejection which is attributed to the increase of the thickness of PA layer. Water contact angle of the skin layer was found to decrease sharply from 34° to 21° when the concentration of fullerenol increased up to 0.5 wt% in the TETA aqueous solution. Antifouling properties of the PA/fullerenol membranes were found to be superior to initial membrane. Fouling recovery ratio increased from 54% for the pristine membrane to 93% for the membrane with 0.5 wt% of fullerenol in the TETA aqueous solution. Irreversible fouling ratio was found to decrease from 38% to 6%, respectively. A correlation between surface properties and fouling behavior of TFN membranes upon increase of fullerenol concentration was established.",

keywords = "Fouling, Fullerenol, Hollow fiber membrane, Interfacial polymerization, Thin film nanocomposite membrane, GRAPHENE OXIDE, WATER DESALINATION, REVERSE-OSMOSIS MEMBRANES, COMPOSITE MEMBRANES, SILVER NANOPARTICLES, CARBON NANOTUBES, INTERFACIAL POLYMERIZATION, SILICA NANOPARTICLES, NANOFILTRATION MEMBRANE, TIO2 NANOPARTICLES",

author = "Plisko, {Tatiana V.} and Liubimova, {Alena S.} and Bildyukevich, {Alexandr V.} and Penkova, {Anastasia V.} and Dmitrenko, {Maria E.} and Mikhailovskii, {Vladimir Y.} and Melnikova, {Galina B.} and Semenov, {Konstantin N.} and Doroshkevich, {Nelya V.} and Kuzminova, {Anna I.}",

year = "2018",

month = apr,

day = "1",

doi = "10.1016/j.memsci.2018.01.015",

language = "English",

volume = "551",

pages = "20--36",

journal = "Journal of Membrane Science",

issn = "0376-7388",

publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Fabrication and characterization of polyamide-fullerenol thin film nanocomposite hollow fiber membranes with enhanced antifouling performance

AU - Plisko, Tatiana V.

AU - Liubimova, Alena S.

AU - Bildyukevich, Alexandr V.

AU - Penkova, Anastasia V.

AU - Dmitrenko, Maria E.

AU - Mikhailovskii, Vladimir Y.

AU - Melnikova, Galina B.

AU - Semenov, Konstantin N.

AU - Doroshkevich, Nelya V.

AU - Kuzminova, Anna I.

PY - 2018/4/1

Y1 - 2018/4/1

N2 - Fullerenol C60(OH)22 – 24 was incorporated into the polyamide (PA) selective layer to develop novel thin film nanocomposite (TFN) hollow fiber membranes for low molecular weight cut-off ultrafiltration. TFN membranes were fabricated via interfacial polymerization technique by alternately pumping fullerenol dispersion in triethylenetetramine (TETA) aqueous solution and isophthaloyl chloride solution in hexane through polysulfone hollow fiber membranes. Developed TFN PA/fullerenol membranes were investigated by FTIR, Raman spectroscopy, SEM, TEM, AFM, contact angle measurements and evaluated by determining the permeability, rejection and antifouling performance. Introduction of fullerenol to the PA skin layer was revealed to yield in the decrease of pure water flux and slight increase of lysozyme rejection which is attributed to the increase of the thickness of PA layer. Water contact angle of the skin layer was found to decrease sharply from 34° to 21° when the concentration of fullerenol increased up to 0.5 wt% in the TETA aqueous solution. Antifouling properties of the PA/fullerenol membranes were found to be superior to initial membrane. Fouling recovery ratio increased from 54% for the pristine membrane to 93% for the membrane with 0.5 wt% of fullerenol in the TETA aqueous solution. Irreversible fouling ratio was found to decrease from 38% to 6%, respectively. A correlation between surface properties and fouling behavior of TFN membranes upon increase of fullerenol concentration was established.

AB - Fullerenol C60(OH)22 – 24 was incorporated into the polyamide (PA) selective layer to develop novel thin film nanocomposite (TFN) hollow fiber membranes for low molecular weight cut-off ultrafiltration. TFN membranes were fabricated via interfacial polymerization technique by alternately pumping fullerenol dispersion in triethylenetetramine (TETA) aqueous solution and isophthaloyl chloride solution in hexane through polysulfone hollow fiber membranes. Developed TFN PA/fullerenol membranes were investigated by FTIR, Raman spectroscopy, SEM, TEM, AFM, contact angle measurements and evaluated by determining the permeability, rejection and antifouling performance. Introduction of fullerenol to the PA skin layer was revealed to yield in the decrease of pure water flux and slight increase of lysozyme rejection which is attributed to the increase of the thickness of PA layer. Water contact angle of the skin layer was found to decrease sharply from 34° to 21° when the concentration of fullerenol increased up to 0.5 wt% in the TETA aqueous solution. Antifouling properties of the PA/fullerenol membranes were found to be superior to initial membrane. Fouling recovery ratio increased from 54% for the pristine membrane to 93% for the membrane with 0.5 wt% of fullerenol in the TETA aqueous solution. Irreversible fouling ratio was found to decrease from 38% to 6%, respectively. A correlation between surface properties and fouling behavior of TFN membranes upon increase of fullerenol concentration was established.

KW - Fouling

KW - Fullerenol

KW - Hollow fiber membrane

KW - Interfacial polymerization

KW - Thin film nanocomposite membrane

KW - GRAPHENE OXIDE

KW - WATER DESALINATION

KW - REVERSE-OSMOSIS MEMBRANES

KW - COMPOSITE MEMBRANES

KW - SILVER NANOPARTICLES

KW - CARBON NANOTUBES

KW - INTERFACIAL POLYMERIZATION

KW - SILICA NANOPARTICLES

KW - NANOFILTRATION MEMBRANE

KW - TIO2 NANOPARTICLES

UR - http://www.scopus.com/inward/record.url?scp=85041478201&partnerID=8YFLogxK

U2 - 10.1016/j.memsci.2018.01.015

DO - 10.1016/j.memsci.2018.01.015

M3 - Article

AN - SCOPUS:85041478201

VL - 551

SP - 20

EP - 36

JO - Journal of Membrane Science

JF - Journal of Membrane Science

SN - 0376-7388

ER -

ID: 14729302