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Exploring new belousovite-related zinc and cadmium alkali sulfate halides: synthesis and structural variability. / Borisov, Artem S.; Siidra, Oleg I.; Charkin, Dmitri O.; Zagidullin, Karim A.; Burshtynovich, Ruslan K.; Vlasenko, Natalia S.

In: Acta crystallographica Section B, Structural science, crystal engineering and materials, Vol. 78, No. Pt 3 Pt 2, 01.06.2022, p. 499-509.

Research output: Contribution to journal › Article › peer-review

Harvard

Borisov, AS, Siidra, OI, Charkin, DO, Zagidullin, KA, Burshtynovich, RK & Vlasenko, NS 2022, 'Exploring new belousovite-related zinc and cadmium alkali sulfate halides: synthesis and structural variability', Acta crystallographica Section B, Structural science, crystal engineering and materials, vol. 78, no. Pt 3 Pt 2, pp. 499-509. https://doi.org/10.1107/S2052520622003535

APA

Borisov, A. S., Siidra, O. I., Charkin, D. O., Zagidullin, K. A., Burshtynovich, R. K., & Vlasenko, N. S. (2022). Exploring new belousovite-related zinc and cadmium alkali sulfate halides: synthesis and structural variability. Acta crystallographica Section B, Structural science, crystal engineering and materials, 78(Pt 3 Pt 2), 499-509. https://doi.org/10.1107/S2052520622003535

Vancouver

Borisov AS, Siidra OI, Charkin DO, Zagidullin KA, Burshtynovich RK, Vlasenko NS. Exploring new belousovite-related zinc and cadmium alkali sulfate halides: synthesis and structural variability. Acta crystallographica Section B, Structural science, crystal engineering and materials. 2022 Jun 1;78(Pt 3 Pt 2):499-509. https://doi.org/10.1107/S2052520622003535

Author

Borisov, Artem S. ; Siidra, Oleg I. ; Charkin, Dmitri O. ; Zagidullin, Karim A. ; Burshtynovich, Ruslan K. ; Vlasenko, Natalia S. / Exploring new belousovite-related zinc and cadmium alkali sulfate halides: synthesis and structural variability. In: Acta crystallographica Section B, Structural science, crystal engineering and materials. 2022 ; Vol. 78, No. Pt 3 Pt 2. pp. 499-509.

BibTeX

@article{8185523a91e14d31b20d99c1c71728ef,
title = "Exploring new belousovite-related zinc and cadmium alkali sulfate halides: synthesis and structural variability",
abstract = "Fourteen new belousovite-related compounds, AZn(TO4)X (A = K, Rb, Cs, Tl, NH4; T = S, Se; X = Cl, Br, I) have been prepared via melt and evaporation techniques by reacting AX and ZnTO4 either at high temperatures or in hot aqueous solutions. They adopt the layered structure of the belousovite archetype, and constitute a morphotropic series. The apophyllite-type layers in these structures undergo different corrugations, most pronounced in the case of CsZn(SO4)I. In addition, during the study two species unrelated to belousovite, namely Na4Zn(SO4)2Cl2 and Cs2Cd3(SO4)4, were found with framework crystal structures having different topology and belonging to new structure types.",
keywords = "belousovite, halides, inorganic synthesis, morphotropism, sulfates",
author = "Borisov, {Artem S.} and Siidra, {Oleg I.} and Charkin, {Dmitri O.} and Zagidullin, {Karim A.} and Burshtynovich, {Ruslan K.} and Vlasenko, {Natalia S.}",
year = "2022",
month = jun,
day = "1",
doi = "10.1107/S2052520622003535",
language = "English",
volume = "78",
pages = "499--509",
journal = "Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials",
issn = "2052-5192",
publisher = "International Union of Crystallography",
number = "Pt 3 Pt 2",

}

RIS

TY - JOUR

T1 - Exploring new belousovite-related zinc and cadmium alkali sulfate halides: synthesis and structural variability

AU - Borisov, Artem S.

AU - Siidra, Oleg I.

AU - Charkin, Dmitri O.

AU - Zagidullin, Karim A.

AU - Burshtynovich, Ruslan K.

AU - Vlasenko, Natalia S.

PY - 2022/6/1

Y1 - 2022/6/1

N2 - Fourteen new belousovite-related compounds, AZn(TO4)X (A = K, Rb, Cs, Tl, NH4; T = S, Se; X = Cl, Br, I) have been prepared via melt and evaporation techniques by reacting AX and ZnTO4 either at high temperatures or in hot aqueous solutions. They adopt the layered structure of the belousovite archetype, and constitute a morphotropic series. The apophyllite-type layers in these structures undergo different corrugations, most pronounced in the case of CsZn(SO4)I. In addition, during the study two species unrelated to belousovite, namely Na4Zn(SO4)2Cl2 and Cs2Cd3(SO4)4, were found with framework crystal structures having different topology and belonging to new structure types.

AB - Fourteen new belousovite-related compounds, AZn(TO4)X (A = K, Rb, Cs, Tl, NH4; T = S, Se; X = Cl, Br, I) have been prepared via melt and evaporation techniques by reacting AX and ZnTO4 either at high temperatures or in hot aqueous solutions. They adopt the layered structure of the belousovite archetype, and constitute a morphotropic series. The apophyllite-type layers in these structures undergo different corrugations, most pronounced in the case of CsZn(SO4)I. In addition, during the study two species unrelated to belousovite, namely Na4Zn(SO4)2Cl2 and Cs2Cd3(SO4)4, were found with framework crystal structures having different topology and belonging to new structure types.

KW - belousovite

KW - halides

KW - inorganic synthesis

KW - morphotropism

KW - sulfates

UR - http://www.scopus.com/inward/record.url?scp=85132050091&partnerID=8YFLogxK

U2 - 10.1107/S2052520622003535

DO - 10.1107/S2052520622003535

M3 - Article

C2 - 35702967

AN - SCOPUS:85132050091

VL - 78

SP - 499

EP - 509

JO - Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials

JF - Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials

SN - 2052-5192

IS - Pt 3 Pt 2

ER -

ID: 96821019