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Experimental Data on Chemical Equilibrium in the System with Ethyl Formate Synthesis Reaction at 298.15 K. / Samarov, Artemiy; Trofimova, Maya; Toikka, Maria; Toikka, Alexander.

In: Journal of Chemical and Engineering Data, Vol. 65, No. 5, 14.05.2020, p. 2578-2582.

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@article{b50d66cd056141f08f7964607c01ad2f,
title = "Experimental Data on Chemical Equilibrium in the System with Ethyl Formate Synthesis Reaction at 298.15 K",
abstract = "Chemical equilibrium (CE) in the quaternary reacting system formic acid-ethanol-ethyl formate-water was experimentally studied at 298.15 K and atmospheric pressure. The CE compositions were determined by gas chromatography analysis. The obtained data gave an opportunity to present the disposition of the surface of CE in a composition tetrahedron. The constants of CE ({"}concentration{"} and thermodynamic) were determined on the base of experimental data and UNIFAC model.",
keywords = "FORMIC-ACID, ESTERIFICATION, ETHANOL, PHASE, WATER",
author = "Artemiy Samarov and Maya Trofimova and Maria Toikka and Alexander Toikka",
year = "2020",
month = may,
day = "14",
doi = "10.1021/acs.jced.9b01205",
language = "English",
volume = "65",
pages = "2578--2582",
journal = "Journal of Chemical & Engineering Data",
issn = "0021-9568",
publisher = "American Chemical Society",
number = "5",

}

RIS

TY - JOUR

T1 - Experimental Data on Chemical Equilibrium in the System with Ethyl Formate Synthesis Reaction at 298.15 K

AU - Samarov, Artemiy

AU - Trofimova, Maya

AU - Toikka, Maria

AU - Toikka, Alexander

PY - 2020/5/14

Y1 - 2020/5/14

N2 - Chemical equilibrium (CE) in the quaternary reacting system formic acid-ethanol-ethyl formate-water was experimentally studied at 298.15 K and atmospheric pressure. The CE compositions were determined by gas chromatography analysis. The obtained data gave an opportunity to present the disposition of the surface of CE in a composition tetrahedron. The constants of CE ("concentration" and thermodynamic) were determined on the base of experimental data and UNIFAC model.

AB - Chemical equilibrium (CE) in the quaternary reacting system formic acid-ethanol-ethyl formate-water was experimentally studied at 298.15 K and atmospheric pressure. The CE compositions were determined by gas chromatography analysis. The obtained data gave an opportunity to present the disposition of the surface of CE in a composition tetrahedron. The constants of CE ("concentration" and thermodynamic) were determined on the base of experimental data and UNIFAC model.

KW - FORMIC-ACID

KW - ESTERIFICATION

KW - ETHANOL

KW - PHASE

KW - WATER

UR - http://www.scopus.com/inward/record.url?scp=85082851690&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/8e47203c-f2c9-325b-90b4-f643b8945724/

U2 - 10.1021/acs.jced.9b01205

DO - 10.1021/acs.jced.9b01205

M3 - Article

AN - SCOPUS:85082851690

VL - 65

SP - 2578

EP - 2582

JO - Journal of Chemical & Engineering Data

JF - Journal of Chemical & Engineering Data

SN - 0021-9568

IS - 5

ER -

ID: 62725490