Research output: Contribution to journal › Article › peer-review
Experimental Data on Chemical Equilibrium in the System with Ethyl Formate Synthesis Reaction at 298.15 K. / Samarov, Artemiy; Trofimova, Maya; Toikka, Maria; Toikka, Alexander.
In: Journal of Chemical and Engineering Data, Vol. 65, No. 5, 14.05.2020, p. 2578-2582.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Experimental Data on Chemical Equilibrium in the System with Ethyl Formate Synthesis Reaction at 298.15 K
AU - Samarov, Artemiy
AU - Trofimova, Maya
AU - Toikka, Maria
AU - Toikka, Alexander
PY - 2020/5/14
Y1 - 2020/5/14
N2 - Chemical equilibrium (CE) in the quaternary reacting system formic acid-ethanol-ethyl formate-water was experimentally studied at 298.15 K and atmospheric pressure. The CE compositions were determined by gas chromatography analysis. The obtained data gave an opportunity to present the disposition of the surface of CE in a composition tetrahedron. The constants of CE ("concentration" and thermodynamic) were determined on the base of experimental data and UNIFAC model.
AB - Chemical equilibrium (CE) in the quaternary reacting system formic acid-ethanol-ethyl formate-water was experimentally studied at 298.15 K and atmospheric pressure. The CE compositions were determined by gas chromatography analysis. The obtained data gave an opportunity to present the disposition of the surface of CE in a composition tetrahedron. The constants of CE ("concentration" and thermodynamic) were determined on the base of experimental data and UNIFAC model.
KW - FORMIC-ACID
KW - ESTERIFICATION
KW - ETHANOL
KW - PHASE
KW - WATER
UR - http://www.scopus.com/inward/record.url?scp=85082851690&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/8e47203c-f2c9-325b-90b4-f643b8945724/
U2 - 10.1021/acs.jced.9b01205
DO - 10.1021/acs.jced.9b01205
M3 - Article
AN - SCOPUS:85082851690
VL - 65
SP - 2578
EP - 2582
JO - Journal of Chemical & Engineering Data
JF - Journal of Chemical & Engineering Data
SN - 0021-9568
IS - 5
ER -
ID: 62725490