Excess Enthalpies and Heat of Esterification Reaction in Acetic Acid–n-Butanol–n-Butyl Acetate–Water System at 313.15 K

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Excess Enthalpies and Heat of Esterification Reaction in Acetic Acid–n-Butanol–n-Butyl Acetate–Water System at 313.15 K. / Golikova, Alexandra; Anufrikov, Yuri; Shasherina, Anna; Misikov, Georgii ; Toikka, Maria ; Samarov, Artemiy ; Toikka, Alexander.

In: Russian Journal of General Chemistry, Vol. 94, No. Suppl 1, 21.03.2024, p. S177–S183.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{15310f3f5e0148768ba46106f07d6c6c,

title = "Excess Enthalpies and Heat of Esterification Reaction in Acetic Acid–n-Butanol–n-Butyl Acetate–Water System at 313.15 K",

abstract = "The excess enthalpies of the acetic acid–n-butanol–n-butyl acetate–water system in chemically equilibrium states were measured at 313.15 K and atmospheric pressure. Over the entire range of mole fractions, the system displayed positive excess enthalpy values. The heat of the esterification reaction was determined based on the mixture{\textquoteright}s heat effects and was calculated to be –4.7±0.3 kJ/mol. The correlation of the data was carried out using NRTL model.",

keywords = "thermochemistry,, excess enthalpy,, heat of esterification reaction,, calorimetry, calorimetry, excess enthalpy, heat of esterification reaction, thermochemistry",

author = "Alexandra Golikova and Yuri Anufrikov and Anna Shasherina and Georgii Misikov and Maria Toikka and Artemiy Samarov and Alexander Toikka",

year = "2024",

month = mar,

day = "21",

doi = "10.1134/s1070363224140184",

language = "English",

volume = "94",

pages = "S177–S183",

journal = "Russian Journal of General Chemistry",

issn = "1070-3632",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "Suppl 1",

}

RIS

TY - JOUR

T1 - Excess Enthalpies and Heat of Esterification Reaction in Acetic Acid–n-Butanol–n-Butyl Acetate–Water System at 313.15 K

AU - Golikova, Alexandra

AU - Anufrikov, Yuri

AU - Shasherina, Anna

AU - Misikov, Georgii

AU - Toikka, Maria

AU - Samarov, Artemiy

AU - Toikka, Alexander

PY - 2024/3/21

Y1 - 2024/3/21

N2 - The excess enthalpies of the acetic acid–n-butanol–n-butyl acetate–water system in chemically equilibrium states were measured at 313.15 K and atmospheric pressure. Over the entire range of mole fractions, the system displayed positive excess enthalpy values. The heat of the esterification reaction was determined based on the mixture’s heat effects and was calculated to be –4.7±0.3 kJ/mol. The correlation of the data was carried out using NRTL model.

AB - The excess enthalpies of the acetic acid–n-butanol–n-butyl acetate–water system in chemically equilibrium states were measured at 313.15 K and atmospheric pressure. Over the entire range of mole fractions, the system displayed positive excess enthalpy values. The heat of the esterification reaction was determined based on the mixture’s heat effects and was calculated to be –4.7±0.3 kJ/mol. The correlation of the data was carried out using NRTL model.

KW - thermochemistry,

KW - excess enthalpy,

KW - heat of esterification reaction,

KW - calorimetry

KW - excess enthalpy

KW - heat of esterification reaction

KW - thermochemistry

UR - https://www.mendeley.com/catalogue/47ba8d49-7ed2-33a0-805e-4b68c386d3fd/

U2 - 10.1134/s1070363224140184

DO - 10.1134/s1070363224140184

M3 - Article

VL - 94

SP - S177–S183

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - Suppl 1

ER -

ID: 118221217