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Emulating exhalative chemistry: synthesis and structural characterization of ilinskite, Na[Cu5O2](SeO3)(2)Cl-3, and its K-analogue. / Kovrugin, Vadim M.; Siidra, Oleg I.; Colmont, Marie; Mentre, Olivier; Krivovichev, Sergey V.

In: Mineralogy and Petrology, Vol. 109, No. 4, 2015, p. 421-430.

Research output: Contribution to journal › Article › peer-review

Harvard

Kovrugin, VM, Siidra, OI, Colmont, M, Mentre, O & Krivovichev, SV 2015, 'Emulating exhalative chemistry: synthesis and structural characterization of ilinskite, Na[Cu5O2](SeO3)(2)Cl-3, and its K-analogue', Mineralogy and Petrology, vol. 109, no. 4, pp. 421-430. https://doi.org/10.1007/s00710-015-0369-3

APA

Kovrugin, V. M., Siidra, O. I., Colmont, M., Mentre, O., & Krivovichev, S. V. (2015). Emulating exhalative chemistry: synthesis and structural characterization of ilinskite, Na[Cu5O2](SeO3)(2)Cl-3, and its K-analogue. Mineralogy and Petrology, 109(4), 421-430. https://doi.org/10.1007/s00710-015-0369-3

Vancouver

Kovrugin VM, Siidra OI, Colmont M, Mentre O, Krivovichev SV. Emulating exhalative chemistry: synthesis and structural characterization of ilinskite, Na[Cu5O2](SeO3)(2)Cl-3, and its K-analogue. Mineralogy and Petrology. 2015;109(4):421-430. https://doi.org/10.1007/s00710-015-0369-3

Author

Kovrugin, Vadim M. ; Siidra, Oleg I. ; Colmont, Marie ; Mentre, Olivier ; Krivovichev, Sergey V. / Emulating exhalative chemistry: synthesis and structural characterization of ilinskite, Na[Cu5O2](SeO3)(2)Cl-3, and its K-analogue. In: Mineralogy and Petrology. 2015 ; Vol. 109, No. 4. pp. 421-430.

BibTeX

@article{acdc487941bd47a9b8b9315e69c4815d,
title = "Emulating exhalative chemistry: synthesis and structural characterization of ilinskite, Na[Cu5O2](SeO3)(2)Cl-3, and its K-analogue",
abstract = "The K- and Na-synthetic analogues of the fumarolic mineral ilinskite have been synthesized by the chemical vapor transport (CVT) reactions method. The A[Cu5O2](SeO3)(2)Cl-3 (A (+) = K+, Na+) compounds crystallize in the orthorhombic space group Pnma: a = 18.1691(6) , b = 6.4483(2) , c = 10.5684(4) , V = 1238.19(7) (3), R (1) = 0.018 for 1957 unique reflections with F > 4 sigma (F) for K[Cu5O2](SeO3)(2)Cl-3 (KI), and a = 17.7489(18) , b = 6.4412(6) , c = 10.4880(12) , V = 1199.0(2) (3), R (1) = 0.049 for 1300 unique reflections with F > 4 sigma (F) for Na[Cu5O2](SeO3)(2)Cl-3 (NaI). The crystal structures of KI and NaI are based upon the [O2Cu5](6+) sheets consisting of corner-sharing (OCu4)(6+) tetrahedra. The Na-for-K substitution results in the significant expansion of the interlayer space and changes in local coordination of some of the Cu2+ cations. The A (+) cation coordination changes from fivefold (for Na+) to ninefold (for K+). The CVT reactions method provides a unique opportunity to model physicochem",
author = "Kovrugin, {Vadim M.} and Siidra, {Oleg I.} and Marie Colmont and Olivier Mentre and Krivovichev, {Sergey V.}",
year = "2015",
doi = "10.1007/s00710-015-0369-3",
language = "English",
volume = "109",
pages = "421--430",
journal = "Mineralogy and Petrology",
issn = "0930-0708",
publisher = "Springer Nature",
number = "4",

}

RIS

TY - JOUR

T1 - Emulating exhalative chemistry: synthesis and structural characterization of ilinskite, Na[Cu5O2](SeO3)(2)Cl-3, and its K-analogue

AU - Kovrugin, Vadim M.

AU - Siidra, Oleg I.

AU - Colmont, Marie

AU - Mentre, Olivier

AU - Krivovichev, Sergey V.

PY - 2015

Y1 - 2015

N2 - The K- and Na-synthetic analogues of the fumarolic mineral ilinskite have been synthesized by the chemical vapor transport (CVT) reactions method. The A[Cu5O2](SeO3)(2)Cl-3 (A (+) = K+, Na+) compounds crystallize in the orthorhombic space group Pnma: a = 18.1691(6) , b = 6.4483(2) , c = 10.5684(4) , V = 1238.19(7) (3), R (1) = 0.018 for 1957 unique reflections with F > 4 sigma (F) for K[Cu5O2](SeO3)(2)Cl-3 (KI), and a = 17.7489(18) , b = 6.4412(6) , c = 10.4880(12) , V = 1199.0(2) (3), R (1) = 0.049 for 1300 unique reflections with F > 4 sigma (F) for Na[Cu5O2](SeO3)(2)Cl-3 (NaI). The crystal structures of KI and NaI are based upon the [O2Cu5](6+) sheets consisting of corner-sharing (OCu4)(6+) tetrahedra. The Na-for-K substitution results in the significant expansion of the interlayer space and changes in local coordination of some of the Cu2+ cations. The A (+) cation coordination changes from fivefold (for Na+) to ninefold (for K+). The CVT reactions method provides a unique opportunity to model physicochem

AB - The K- and Na-synthetic analogues of the fumarolic mineral ilinskite have been synthesized by the chemical vapor transport (CVT) reactions method. The A[Cu5O2](SeO3)(2)Cl-3 (A (+) = K+, Na+) compounds crystallize in the orthorhombic space group Pnma: a = 18.1691(6) , b = 6.4483(2) , c = 10.5684(4) , V = 1238.19(7) (3), R (1) = 0.018 for 1957 unique reflections with F > 4 sigma (F) for K[Cu5O2](SeO3)(2)Cl-3 (KI), and a = 17.7489(18) , b = 6.4412(6) , c = 10.4880(12) , V = 1199.0(2) (3), R (1) = 0.049 for 1300 unique reflections with F > 4 sigma (F) for Na[Cu5O2](SeO3)(2)Cl-3 (NaI). The crystal structures of KI and NaI are based upon the [O2Cu5](6+) sheets consisting of corner-sharing (OCu4)(6+) tetrahedra. The Na-for-K substitution results in the significant expansion of the interlayer space and changes in local coordination of some of the Cu2+ cations. The A (+) cation coordination changes from fivefold (for Na+) to ninefold (for K+). The CVT reactions method provides a unique opportunity to model physicochem

U2 - 10.1007/s00710-015-0369-3

DO - 10.1007/s00710-015-0369-3

M3 - Article

VL - 109

SP - 421

EP - 430

JO - Mineralogy and Petrology

JF - Mineralogy and Petrology

SN - 0930-0708

IS - 4

ER -

ID: 4005358