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Electrooxidation of saturated C1-C3 primary alcohols on platinum : Potential-resolved product analysis with electrochemical real-time mass spectrometry (EC-RTMS). / Khanipour, Peyman; Haschke, Sandra; Bachmann, Julien; Mayrhofer, Karl J.J.; Katsounaros, Ioannis.

In: Electrochimica Acta, Vol. 315, 20.08.2019, p. 67-74.

Research output: Contribution to journal › Article › peer-review

Harvard

Khanipour, P, Haschke, S, Bachmann, J, Mayrhofer, KJJ & Katsounaros, I 2019, 'Electrooxidation of saturated C1-C3 primary alcohols on platinum: Potential-resolved product analysis with electrochemical real-time mass spectrometry (EC-RTMS)', Electrochimica Acta, vol. 315, pp. 67-74. https://doi.org/10.1016/j.electacta.2019.05.070

APA

Khanipour, P., Haschke, S., Bachmann, J., Mayrhofer, K. J. J., & Katsounaros, I. (2019). Electrooxidation of saturated C1-C3 primary alcohols on platinum: Potential-resolved product analysis with electrochemical real-time mass spectrometry (EC-RTMS). Electrochimica Acta, 315, 67-74. https://doi.org/10.1016/j.electacta.2019.05.070

Vancouver

Khanipour P, Haschke S, Bachmann J, Mayrhofer KJJ, Katsounaros I. Electrooxidation of saturated C1-C3 primary alcohols on platinum: Potential-resolved product analysis with electrochemical real-time mass spectrometry (EC-RTMS). Electrochimica Acta. 2019 Aug 20;315:67-74. https://doi.org/10.1016/j.electacta.2019.05.070

Author

Khanipour, Peyman ; Haschke, Sandra ; Bachmann, Julien ; Mayrhofer, Karl J.J. ; Katsounaros, Ioannis. / Electrooxidation of saturated C1-C3 primary alcohols on platinum : Potential-resolved product analysis with electrochemical real-time mass spectrometry (EC-RTMS). In: Electrochimica Acta. 2019 ; Vol. 315. pp. 67-74.

BibTeX

@article{7ed6faa303a143eaacc00fd25e9c271c,
title = "Electrooxidation of saturated C1-C3 primary alcohols on platinum: Potential-resolved product analysis with electrochemical real-time mass spectrometry (EC-RTMS)",
abstract = "Electrochemical real-time mass spectrometry (EC-RTMS) is a novel technique for the real-time monitoring of gaseous and liquid products of electrochemical reactions, independent of their vapor pressure, with excellent temporal and potential resolution. The scope of this manuscript is to provide details on the interpretation of data for this new technique and on the assignment of mass signals to reaction products by studying three model reactions. The bulk products of the electrochemical oxidation of methanol, ethanol and 1-propanol are characterized by EC-RTMS during potentiodynamic measurements, and the capabilities of the method in detecting reaction products in real time are demonstrated. The importance of proton affinity for the detection of reaction products is highlighted.",
keywords = "Alcohol oxidation, DART mass spectrometry, EC-RTMS, Mass spectrometry, Real-time product analysis",
author = "Peyman Khanipour and Sandra Haschke and Julien Bachmann and Mayrhofer, {Karl J.J.} and Ioannis Katsounaros",
note = "Publisher Copyright: {\textcopyright} 2019 Elsevier Ltd",
year = "2019",
month = aug,
day = "20",
doi = "10.1016/j.electacta.2019.05.070",
language = "English",
volume = "315",
pages = "67--74",
journal = "Electrochimica Acta",
issn = "0013-4686",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Electrooxidation of saturated C1-C3 primary alcohols on platinum

T2 - Potential-resolved product analysis with electrochemical real-time mass spectrometry (EC-RTMS)

AU - Khanipour, Peyman

AU - Haschke, Sandra

AU - Bachmann, Julien

AU - Mayrhofer, Karl J.J.

AU - Katsounaros, Ioannis

N1 - Publisher Copyright: © 2019 Elsevier Ltd

PY - 2019/8/20

Y1 - 2019/8/20

N2 - Electrochemical real-time mass spectrometry (EC-RTMS) is a novel technique for the real-time monitoring of gaseous and liquid products of electrochemical reactions, independent of their vapor pressure, with excellent temporal and potential resolution. The scope of this manuscript is to provide details on the interpretation of data for this new technique and on the assignment of mass signals to reaction products by studying three model reactions. The bulk products of the electrochemical oxidation of methanol, ethanol and 1-propanol are characterized by EC-RTMS during potentiodynamic measurements, and the capabilities of the method in detecting reaction products in real time are demonstrated. The importance of proton affinity for the detection of reaction products is highlighted.

AB - Electrochemical real-time mass spectrometry (EC-RTMS) is a novel technique for the real-time monitoring of gaseous and liquid products of electrochemical reactions, independent of their vapor pressure, with excellent temporal and potential resolution. The scope of this manuscript is to provide details on the interpretation of data for this new technique and on the assignment of mass signals to reaction products by studying three model reactions. The bulk products of the electrochemical oxidation of methanol, ethanol and 1-propanol are characterized by EC-RTMS during potentiodynamic measurements, and the capabilities of the method in detecting reaction products in real time are demonstrated. The importance of proton affinity for the detection of reaction products is highlighted.

KW - Alcohol oxidation

KW - DART mass spectrometry

KW - EC-RTMS

KW - Mass spectrometry

KW - Real-time product analysis

UR - http://www.scopus.com/inward/record.url?scp=85066430785&partnerID=8YFLogxK

U2 - 10.1016/j.electacta.2019.05.070

DO - 10.1016/j.electacta.2019.05.070

M3 - Article

AN - SCOPUS:85066430785

VL - 315

SP - 67

EP - 74

JO - Electrochimica Acta

JF - Electrochimica Acta

SN - 0013-4686

ER -

ID: 88009183