Research output: Contribution to journal › Article
Electro-optic research of polarizability dispersion in aqueous polydisperse suspensions of nanodiamonds. / Petrov, M.P.; Shilov, V.N.; Trusov, A.A.; Voitylov, A.V.; Vojtylov, V.V.
In: Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 506, 2016, p. 40-49.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Electro-optic research of polarizability dispersion in aqueous polydisperse suspensions of nanodiamonds
AU - Petrov, M.P.
AU - Shilov, V.N.
AU - Trusov, A.A.
AU - Voitylov, A.V.
AU - Vojtylov, V.V.
PY - 2016
Y1 - 2016
N2 - In this paper we present the results of electro-optical research of aqueous colloids of nanodiamonds. Application of external electric field to such colloids causes particle orientation, and optical anisotropy caused by such particle orientation can then be easily measured experimentally. These effects allow to determine particle polarizability anisotropy in a wide frequency range. The theory of particle polarizability that takes into account both Maxwell-Wagner and α-dispersion is then used to obtain the magnitude of particle surface conductivity. Since nanodiamond particles are polydisperse and polymorphic, the equations that govern the influence of polydispersity and polymorphism of particles on the observed effects are discussed. To determine the ranges of applicability of particle polarizability theory in electrolyte solutions to diamond particles in aqueous colloids, we studied electro-optical stationary effect in weak electric fields in frequency range 500 Hz–4 MHz at different ionic strengths of the
AB - In this paper we present the results of electro-optical research of aqueous colloids of nanodiamonds. Application of external electric field to such colloids causes particle orientation, and optical anisotropy caused by such particle orientation can then be easily measured experimentally. These effects allow to determine particle polarizability anisotropy in a wide frequency range. The theory of particle polarizability that takes into account both Maxwell-Wagner and α-dispersion is then used to obtain the magnitude of particle surface conductivity. Since nanodiamond particles are polydisperse and polymorphic, the equations that govern the influence of polydispersity and polymorphism of particles on the observed effects are discussed. To determine the ranges of applicability of particle polarizability theory in electrolyte solutions to diamond particles in aqueous colloids, we studied electro-optical stationary effect in weak electric fields in frequency range 500 Hz–4 MHz at different ionic strengths of the
KW - Nanodiamond
KW - Suspension
KW - Surface conductivity
KW - Polarizability dispersion
KW - Polydispersity
KW - Polymorphism
U2 - 10.1016/j.colsurfa.2016.05.087
DO - 10.1016/j.colsurfa.2016.05.087
M3 - Article
VL - 506
SP - 40
EP - 49
JO - Colloids and Surfaces A: Physicochemical and Engineering Aspects
JF - Colloids and Surfaces A: Physicochemical and Engineering Aspects
SN - 0927-7757
ER -
ID: 7585249