Electron-vibrational suppression of magnetic-dipole electronic transitions in MeF2:Tm2+ crystals. / Ignatev, I. V.; Ovsyankin, V. V.
In: Proceedings of SPIE - The International Society for Optical Engineering, Vol. 2706, 1996, p. 142-148.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Electron-vibrational suppression of magnetic-dipole electronic transitions in MeF2:Tm2+ crystals
AU - Ignatev, I. V.
AU - Ovsyankin, V. V.
PY - 1996
Y1 - 1996
N2 - Elecironic iransiiions between i/ic Stark components of 2F712 and 2F512 terms in 4f'3 configuraiion are observed in ihe CaF2:Tm2+ and CaF2:Tm2+ absorption and luminescence spec1ra. The transitions are magneiicdipole. Theoreiical analysis in LSJ represeniaiion allows to deiermine the relation beiween electronic transition probabilities. Experimental relations between observed transition probabilities are estimated using vibronic sideband integral intensity of the F I transition for normalization. The theoretical results vary from the experimental ones. The analysis of discrepancy possible reasons has been performed. Suppression of the I, r7 transition is associated with the resonant reabsorption of radiation. Suppression of F7 —÷r transition in absorption is caused by intensity transfer to vibronic transitions due to the interaction of Tm2+ ions with the even I'3g and I'5g vibrations. Degree of this suppression was evaluated in the framework of electrostatic approximation. Results of the calculation are in agr
AB - Elecironic iransiiions between i/ic Stark components of 2F712 and 2F512 terms in 4f'3 configuraiion are observed in ihe CaF2:Tm2+ and CaF2:Tm2+ absorption and luminescence spec1ra. The transitions are magneiicdipole. Theoreiical analysis in LSJ represeniaiion allows to deiermine the relation beiween electronic transition probabilities. Experimental relations between observed transition probabilities are estimated using vibronic sideband integral intensity of the F I transition for normalization. The theoretical results vary from the experimental ones. The analysis of discrepancy possible reasons has been performed. Suppression of the I, r7 transition is associated with the resonant reabsorption of radiation. Suppression of F7 —÷r transition in absorption is caused by intensity transfer to vibronic transitions due to the interaction of Tm2+ ions with the even I'3g and I'5g vibrations. Degree of this suppression was evaluated in the framework of electrostatic approximation. Results of the calculation are in agr
M3 - статья
VL - 2706
SP - 142
EP - 148
JO - Proceedings of SPIE - The International Society for Optical Engineering
JF - Proceedings of SPIE - The International Society for Optical Engineering
SN - 0277-786X
ER -
ID: 5327466