Standard

Electronic Structure of Copper Halides CuI and CuCl: A Comparative X-Ray Photoelectron and Absorption Spectroscopy Study. / Generalov, A.V.; Vinogradov, A.S.

In: Physics of the Solid State, Vol. 55, No. 6, 2013, p. 1136-1147.

Research output: Contribution to journal › Article

Harvard

Generalov, AV & Vinogradov, AS 2013, 'Electronic Structure of Copper Halides CuI and CuCl: A Comparative X-Ray Photoelectron and Absorption Spectroscopy Study', Physics of the Solid State, vol. 55, no. 6, pp. 1136-1147. https://doi.org/10.1134/S1063783413060115

APA

Generalov, A. V., & Vinogradov, A. S. (2013). Electronic Structure of Copper Halides CuI and CuCl: A Comparative X-Ray Photoelectron and Absorption Spectroscopy Study. Physics of the Solid State, 55(6), 1136-1147. https://doi.org/10.1134/S1063783413060115

Vancouver

Generalov AV, Vinogradov AS. Electronic Structure of Copper Halides CuI and CuCl: A Comparative X-Ray Photoelectron and Absorption Spectroscopy Study. Physics of the Solid State. 2013;55(6):1136-1147. https://doi.org/10.1134/S1063783413060115

Author

Generalov, A.V. ; Vinogradov, A.S. / Electronic Structure of Copper Halides CuI and CuCl: A Comparative X-Ray Photoelectron and Absorption Spectroscopy Study. In: Physics of the Solid State. 2013 ; Vol. 55, No. 6. pp. 1136-1147.

BibTeX

@article{f86d09cf3b014917a24be60c045b53de,
title = "Electronic Structure of Copper Halides CuI and CuCl: A Comparative X-Ray Photoelectron and Absorption Spectroscopy Study",
abstract = "The energy distributions of the occupied and unoccupied electronic states for copper halides CuCl and CuI have been investigated using Xray photoemission and absorption spectroscopy with a high energy resolution on the equipment of the Russian–German beamline for outlet and monochromatization of synchrotron radiation from the electron storage ring BESSY II. A quasimolecular analysis of the obtained experimental spectra has revealed that there is a fundamental similarity of the energy structures of the valence band and the conduction band of copper halides CuX (X = Cl, I) due to the identical atomic structure of the studied compounds. The differences in the positions of individual energy subbands in the valence band and the conduction band of CuX and in their intensities in the spectra are associated with different degrees of hybridization of the Cu 3d, 4s and X(n + 1)s, np valence states, as well as with different sizes of structural units (CuCl4 and CuI4 quasimolecules) of the studied crystals.",
author = "A.V. Generalov and A.S. Vinogradov",
year = "2013",
doi = "10.1134/S1063783413060115",
language = "English",
volume = "55",
pages = "1136--1147",
journal = "Physics of the Solid State",
issn = "1063-7834",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "6",

}

RIS

TY - JOUR

T1 - Electronic Structure of Copper Halides CuI and CuCl: A Comparative X-Ray Photoelectron and Absorption Spectroscopy Study

AU - Generalov, A.V.

AU - Vinogradov, A.S.

PY - 2013

Y1 - 2013

N2 - The energy distributions of the occupied and unoccupied electronic states for copper halides CuCl and CuI have been investigated using Xray photoemission and absorption spectroscopy with a high energy resolution on the equipment of the Russian–German beamline for outlet and monochromatization of synchrotron radiation from the electron storage ring BESSY II. A quasimolecular analysis of the obtained experimental spectra has revealed that there is a fundamental similarity of the energy structures of the valence band and the conduction band of copper halides CuX (X = Cl, I) due to the identical atomic structure of the studied compounds. The differences in the positions of individual energy subbands in the valence band and the conduction band of CuX and in their intensities in the spectra are associated with different degrees of hybridization of the Cu 3d, 4s and X(n + 1)s, np valence states, as well as with different sizes of structural units (CuCl4 and CuI4 quasimolecules) of the studied crystals.

AB - The energy distributions of the occupied and unoccupied electronic states for copper halides CuCl and CuI have been investigated using Xray photoemission and absorption spectroscopy with a high energy resolution on the equipment of the Russian–German beamline for outlet and monochromatization of synchrotron radiation from the electron storage ring BESSY II. A quasimolecular analysis of the obtained experimental spectra has revealed that there is a fundamental similarity of the energy structures of the valence band and the conduction band of copper halides CuX (X = Cl, I) due to the identical atomic structure of the studied compounds. The differences in the positions of individual energy subbands in the valence band and the conduction band of CuX and in their intensities in the spectra are associated with different degrees of hybridization of the Cu 3d, 4s and X(n + 1)s, np valence states, as well as with different sizes of structural units (CuCl4 and CuI4 quasimolecules) of the studied crystals.

U2 - 10.1134/S1063783413060115

DO - 10.1134/S1063783413060115

M3 - Article

VL - 55

SP - 1136

EP - 1147

JO - Physics of the Solid State

JF - Physics of the Solid State

SN - 1063-7834

IS - 6

ER -

ID: 7406371