Electron attachment spectroscopy as a tool to study internal rotations in isolated negative ions

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Electron attachment spectroscopy as a tool to study internal rotations in isolated negative ions. / Pshenichnyuk, Stanislav A.; Modelli, Alberto; Asfandiarov, Nail L.; Rakhmeyev, Rustam G.; Tayupov, Mansaf M.; Komolov, Alexei S.

In: Physical Review Research, Vol. 2, No. 1, 012030, 02.2020.

Research output: Contribution to journal › Article › peer-review

Author

Pshenichnyuk, Stanislav A. ; Modelli, Alberto ; Asfandiarov, Nail L. ; Rakhmeyev, Rustam G. ; Tayupov, Mansaf M. ; Komolov, Alexei S. / Electron attachment spectroscopy as a tool to study internal rotations in isolated negative ions. In: Physical Review Research. 2020 ; Vol. 2, No. 1.

BibTeX

@article{3395076385bd41cda8e3b0e8bab6f2eb,

title = "Electron attachment spectroscopy as a tool to study internal rotations in isolated negative ions",

abstract = "Electron-driven processes in the triclosan molecule are studied under gas-phase conditions using dissociative electron attachment (DEA) spectroscopy with the support of density functional theory calculations. Several decay channels of the short-lived (less than 17 μs) molecular anion of triclosan are associated with excitation of internal rotations of the phenyl rings around the C-O bonds. This leads to production of a dioxin anion by elimination of a neutral HCl molecule or negatively charged hypochlorous acid and dibenzofuran as the neutral counterpart. These decays are accompanied by cleavage and formation of several covalent bonds and appear on the microsecond timescale as confirmed by detection of metastable anions. On the basis of the present and earlier findings, DEA spectroscopy demonstrates to be a suitable technique for studying internal rotations in negative ions, although quite differently from the experimental techniques - microwave and Raman spectroscopies - usually employed to study internal rotations in neutral molecules.",

author = "Pshenichnyuk, {Stanislav A.} and Alberto Modelli and Asfandiarov, {Nail L.} and Rakhmeyev, {Rustam G.} and Tayupov, {Mansaf M.} and Komolov, {Alexei S.}",

note = "Publisher Copyright: {\textcopyright} 2020 authors. Published by the American Physical Society. Published by the American Physical Society under the terms of the Creative Commons Attribution 4.0 International license. Further distribution of this work must maintain attribution to the author(s) and the published article's title, journal citation, and DOI.",

year = "2020",

month = feb,

doi = "10.1103/PhysRevResearch.2.012030",

language = "English",

volume = "2",

journal = "Physical Review Research",

issn = "2643-1564",

publisher = "American Physical Society",

number = "1",

}

RIS

TY - JOUR

T1 - Electron attachment spectroscopy as a tool to study internal rotations in isolated negative ions

AU - Pshenichnyuk, Stanislav A.

AU - Modelli, Alberto

AU - Asfandiarov, Nail L.

AU - Rakhmeyev, Rustam G.

AU - Tayupov, Mansaf M.

AU - Komolov, Alexei S.

N1 - Publisher Copyright: © 2020 authors. Published by the American Physical Society. Published by the American Physical Society under the terms of the Creative Commons Attribution 4.0 International license. Further distribution of this work must maintain attribution to the author(s) and the published article's title, journal citation, and DOI.

PY - 2020/2

Y1 - 2020/2

N2 - Electron-driven processes in the triclosan molecule are studied under gas-phase conditions using dissociative electron attachment (DEA) spectroscopy with the support of density functional theory calculations. Several decay channels of the short-lived (less than 17 μs) molecular anion of triclosan are associated with excitation of internal rotations of the phenyl rings around the C-O bonds. This leads to production of a dioxin anion by elimination of a neutral HCl molecule or negatively charged hypochlorous acid and dibenzofuran as the neutral counterpart. These decays are accompanied by cleavage and formation of several covalent bonds and appear on the microsecond timescale as confirmed by detection of metastable anions. On the basis of the present and earlier findings, DEA spectroscopy demonstrates to be a suitable technique for studying internal rotations in negative ions, although quite differently from the experimental techniques - microwave and Raman spectroscopies - usually employed to study internal rotations in neutral molecules.

AB - Electron-driven processes in the triclosan molecule are studied under gas-phase conditions using dissociative electron attachment (DEA) spectroscopy with the support of density functional theory calculations. Several decay channels of the short-lived (less than 17 μs) molecular anion of triclosan are associated with excitation of internal rotations of the phenyl rings around the C-O bonds. This leads to production of a dioxin anion by elimination of a neutral HCl molecule or negatively charged hypochlorous acid and dibenzofuran as the neutral counterpart. These decays are accompanied by cleavage and formation of several covalent bonds and appear on the microsecond timescale as confirmed by detection of metastable anions. On the basis of the present and earlier findings, DEA spectroscopy demonstrates to be a suitable technique for studying internal rotations in negative ions, although quite differently from the experimental techniques - microwave and Raman spectroscopies - usually employed to study internal rotations in neutral molecules.

UR - http://www.scopus.com/inward/record.url?scp=85092045963&partnerID=8YFLogxK

U2 - 10.1103/PhysRevResearch.2.012030

DO - 10.1103/PhysRevResearch.2.012030

M3 - Article

AN - SCOPUS:85092045963

VL - 2

JO - Physical Review Research

JF - Physical Review Research

SN - 2643-1564

IS - 1

M1 - 012030

ER -

ID: 87681076