Research output: Contribution to journal › Article › peer-review
ELECTRODE PROPERTIES OF MEMBRANES BASED ON SOLVENT MIXTURES. RELATION BETWEEN MEMBRANE SELECTIVITY AND IONIC SOLVATION. / Mikhel'son, K. N.; Lutov, V. M.; Grekovich, A. L.; Materova, E. A.; Dement'eva, L. P.
In: SOVIET ELECTROCHEMISTRY, Vol. 20, No. 11, 11.1984, p. 1348-1354.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - ELECTRODE PROPERTIES OF MEMBRANES BASED ON SOLVENT MIXTURES. RELATION BETWEEN MEMBRANE SELECTIVITY AND IONIC SOLVATION.
AU - Mikhel'son, K. N.
AU - Lutov, V. M.
AU - Grekovich, A. L.
AU - Materova, E. A.
AU - Dement'eva, L. P.
PY - 1984/11
Y1 - 1984/11
N2 - For the electric potential and electrode selectivity of membranes based on solvent mixtures, expressions were obtained which allow for the transport of cations in the form of solvates with these solvents. The model was tested for polyvinyl chloride membranes containing mixtures of dioctyl phthalate and trioctyl phosphate in different concentration ratios. There is mutual agreement between data for the stoichiometry of cation solvation by trioctyl phosphate obtained by analysis of electrode properties and those obtained by analysis of extraction properties of the membranes.
AB - For the electric potential and electrode selectivity of membranes based on solvent mixtures, expressions were obtained which allow for the transport of cations in the form of solvates with these solvents. The model was tested for polyvinyl chloride membranes containing mixtures of dioctyl phthalate and trioctyl phosphate in different concentration ratios. There is mutual agreement between data for the stoichiometry of cation solvation by trioctyl phosphate obtained by analysis of electrode properties and those obtained by analysis of extraction properties of the membranes.
UR - http://www.scopus.com/inward/record.url?scp=0021524136&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0021524136
VL - 20
SP - 1348
EP - 1354
JO - Russian Journal of Electrochemistry
JF - Russian Journal of Electrochemistry
SN - 1023-1935
IS - 11
ER -
ID: 92362055