Research output: Contribution to journal › Article › peer-review
Electrochemical Properties of the closo-Decaborate Anion [B10H10]2– and a New Method for Preparation of the [B20H18]2– Anion. / Voinova, V. V.; Klyukin, I. N.; Novikov, A. S.; Koz’menkova, A. Ya; Zhdanov, A. P.; Zhizhin, K. Yu; Kuznetsov, N. T.
In: Russian Journal of Inorganic Chemistry, Vol. 66, No. 3, 01.03.2021, p. 295-304.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Electrochemical Properties of the closo-Decaborate Anion [B10H10]2– and a New Method for Preparation of the [B20H18]2– Anion
AU - Voinova, V. V.
AU - Klyukin, I. N.
AU - Novikov, A. S.
AU - Koz’menkova, A. Ya
AU - Zhdanov, A. P.
AU - Zhizhin, K. Yu
AU - Kuznetsov, N. T.
N1 - Publisher Copyright: © 2021, Pleiades Publishing, Ltd. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.
PY - 2021/3/1
Y1 - 2021/3/1
N2 - The work is devoted to the theoretical and experimental study of the electrochemical characteristics of the closo-decaborate anion. The regions of electrochemical transformations of the [B10H10](2-) anion for non-aqueous solvents of different structures (acetonitrile, dichloromethane, and tetrahydrofuran) have been studied by the method of cyclic voltammetry. It has been shown that, under the conditions of anodic oxidation, a dimerization product, the [B20H18](2-) anion, is formed. For the synthesis of octadecahydroeicosaborate anion, electrochemical synthesis has been used for the first time.
AB - The work is devoted to the theoretical and experimental study of the electrochemical characteristics of the closo-decaborate anion. The regions of electrochemical transformations of the [B10H10](2-) anion for non-aqueous solvents of different structures (acetonitrile, dichloromethane, and tetrahydrofuran) have been studied by the method of cyclic voltammetry. It has been shown that, under the conditions of anodic oxidation, a dimerization product, the [B20H18](2-) anion, is formed. For the synthesis of octadecahydroeicosaborate anion, electrochemical synthesis has been used for the first time.
KW - closo-decaborate anion
KW - cyclic voltammetry
KW - electrochemical oxidation
UR - http://www.scopus.com/inward/record.url?scp=85102741159&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/e0d39b6a-a7a7-361c-bdb9-0845fd26375b/
U2 - 10.1134/S0036023621030190
DO - 10.1134/S0036023621030190
M3 - Article
AN - SCOPUS:85102741159
VL - 66
SP - 295
EP - 304
JO - Russian Journal of Inorganic Chemistry
JF - Russian Journal of Inorganic Chemistry
SN - 0036-0236
IS - 3
ER -
ID: 77246344