Research output: Contribution to journal › Article › peer-review
Electrochemical properties of solid electrolytes based on BaSm 2S4. / Ushakova, Yu N.; Kalinina, L. A.; Yurlov, I. S.; Bayderina, T. V.; Murin, I. V.
In: Russian Journal of Electrochemistry, Vol. 45, No. 6, 06.2009, p. 677-683.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Electrochemical properties of solid electrolytes based on BaSm 2S4
AU - Ushakova, Yu N.
AU - Kalinina, L. A.
AU - Yurlov, I. S.
AU - Bayderina, T. V.
AU - Murin, I. V.
N1 - Funding Information: ACKNOWLEDGMENTS The authors are grateful to V.P. Tolstoy and Yu.G. Metlin for the performed electron microscopy and XRD studies. The work was financially supported by the Russian Foundation for Basic Research (project no. 06-03-96353).
PY - 2009/6
Y1 - 2009/6
N2 - Solid solutions based on BaSm2S4 - x mol % BaS (Sm2S3) are obtained. Oxide intermediates were homogenized using chemical and mechanical mixing methods. The solid solution region is determined. Complex conductivity is studied and conductivity activation energy is calculated for samples with different history. Electrolytic properties of phases based on barium thiosamarate are studied. Vacancy mechanism of defect formation is suggested.
AB - Solid solutions based on BaSm2S4 - x mol % BaS (Sm2S3) are obtained. Oxide intermediates were homogenized using chemical and mechanical mixing methods. The solid solution region is determined. Complex conductivity is studied and conductivity activation energy is calculated for samples with different history. Electrolytic properties of phases based on barium thiosamarate are studied. Vacancy mechanism of defect formation is suggested.
KW - Barium thiosamarate
KW - Ionic and electronic transport numbers
KW - Ionic conductivity
KW - Solid electrolytes
KW - Stoichiometric substances
UR - http://www.scopus.com/inward/record.url?scp=67651162319&partnerID=8YFLogxK
U2 - 10.1134/S1023193509060093
DO - 10.1134/S1023193509060093
M3 - Article
AN - SCOPUS:67651162319
VL - 45
SP - 677
EP - 683
JO - Russian Journal of Electrochemistry
JF - Russian Journal of Electrochemistry
SN - 1023-1935
IS - 6
ER -
ID: 88058208