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ELECTROCHEMICAL PROPERTIES AND SPECTROPHOTOMETRY OF MEMBRANES BASED ON HOLMIUM TETRAPHENYLPORPHYRINCHLORIDE. / Valiotti, A.B.; Vasil'eva, O.E.; Starikova, T.A.; Shumilova, G.I.; Semeikin, A.S.

In: Russian Journal of General Chemistry, Vol. 81, No. 4, 2011, p. 762-767.

Research output: Contribution to journal › Article › peer-review

Harvard

Valiotti, AB, Vasil'eva, OE, Starikova, TA, Shumilova, GI & Semeikin, AS 2011, 'ELECTROCHEMICAL PROPERTIES AND SPECTROPHOTOMETRY OF MEMBRANES BASED ON HOLMIUM TETRAPHENYLPORPHYRINCHLORIDE', Russian Journal of General Chemistry, vol. 81, no. 4, pp. 762-767. https://doi.org/DOI: 10.1134/S1070363211040256

APA

Valiotti, A. B., Vasil'eva, O. E., Starikova, T. A., Shumilova, G. I., & Semeikin, A. S. (2011). ELECTROCHEMICAL PROPERTIES AND SPECTROPHOTOMETRY OF MEMBRANES BASED ON HOLMIUM TETRAPHENYLPORPHYRINCHLORIDE. Russian Journal of General Chemistry, 81(4), 762-767. https://doi.org/DOI: 10.1134/S1070363211040256

Vancouver

Valiotti AB, Vasil'eva OE, Starikova TA, Shumilova GI, Semeikin AS. ELECTROCHEMICAL PROPERTIES AND SPECTROPHOTOMETRY OF MEMBRANES BASED ON HOLMIUM TETRAPHENYLPORPHYRINCHLORIDE. Russian Journal of General Chemistry. 2011;81(4):762-767. https://doi.org/DOI: 10.1134/S1070363211040256

Author

Valiotti, A.B. ; Vasil'eva, O.E. ; Starikova, T.A. ; Shumilova, G.I. ; Semeikin, A.S. / ELECTROCHEMICAL PROPERTIES AND SPECTROPHOTOMETRY OF MEMBRANES BASED ON HOLMIUM TETRAPHENYLPORPHYRINCHLORIDE. In: Russian Journal of General Chemistry. 2011 ; Vol. 81, No. 4. pp. 762-767.

BibTeX

@article{ef18db2f4b0e4829b12ba0617aa7f323,
title = "ELECTROCHEMICAL PROPERTIES AND SPECTROPHOTOMETRY OF MEMBRANES BASED ON HOLMIUM TETRAPHENYLPORPHYRINCHLORIDE",
abstract = "—Protolytic properties of holmium tetraphenyl-porphyrinchloride were studied by the method of twophase spectrophotometric titration with potentiometric monitoring of pH of the medium. Apparent constants of the heterophase reaction of the exchange of an anion for the hydroxide ion were determined. It was found that the membranes based on holmium tetraphenylporphyrinchloride with dibutyl phthalate as a solvent-softener are selective to ions of alkaline earth metals (Ca2+ and Ba2+) in the region of pH > 7 over the concentration range from 1 up to 1×10–4 M. Selectivity coefficients were determined by two independent methods: the method of biion potentials and the method of mixed solutions. The found selectivity series coincides with traditional Hofmeister series for cations.",
keywords = "holmium tetraphenyl-porphyrinchloride spectrophotometric titration selectivity coefficients Hofmeister series",
author = "A.B. Valiotti and O.E. Vasil'eva and T.A. Starikova and G.I. Shumilova and A.S Semeikin",
year = "2011",
doi = "DOI: 10.1134/S1070363211040256",
language = "English",
volume = "81",
pages = "762--767",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "4",

}

RIS

TY - JOUR

T1 - ELECTROCHEMICAL PROPERTIES AND SPECTROPHOTOMETRY OF MEMBRANES BASED ON HOLMIUM TETRAPHENYLPORPHYRINCHLORIDE

AU - Valiotti, A.B.

AU - Vasil'eva, O.E.

AU - Starikova, T.A.

AU - Shumilova, G.I.

AU - Semeikin, A.S

PY - 2011

Y1 - 2011

N2 - —Protolytic properties of holmium tetraphenyl-porphyrinchloride were studied by the method of twophase spectrophotometric titration with potentiometric monitoring of pH of the medium. Apparent constants of the heterophase reaction of the exchange of an anion for the hydroxide ion were determined. It was found that the membranes based on holmium tetraphenylporphyrinchloride with dibutyl phthalate as a solvent-softener are selective to ions of alkaline earth metals (Ca2+ and Ba2+) in the region of pH > 7 over the concentration range from 1 up to 1×10–4 M. Selectivity coefficients were determined by two independent methods: the method of biion potentials and the method of mixed solutions. The found selectivity series coincides with traditional Hofmeister series for cations.

AB - —Protolytic properties of holmium tetraphenyl-porphyrinchloride were studied by the method of twophase spectrophotometric titration with potentiometric monitoring of pH of the medium. Apparent constants of the heterophase reaction of the exchange of an anion for the hydroxide ion were determined. It was found that the membranes based on holmium tetraphenylporphyrinchloride with dibutyl phthalate as a solvent-softener are selective to ions of alkaline earth metals (Ca2+ and Ba2+) in the region of pH > 7 over the concentration range from 1 up to 1×10–4 M. Selectivity coefficients were determined by two independent methods: the method of biion potentials and the method of mixed solutions. The found selectivity series coincides with traditional Hofmeister series for cations.

KW - holmium tetraphenyl-porphyrinchloride spectrophotometric titration selectivity coefficients Hofmeister series

U2 - DOI: 10.1134/S1070363211040256

DO - DOI: 10.1134/S1070363211040256

M3 - Article

VL - 81

SP - 762

EP - 767

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 4

ER -

ID: 5544705