Research output: Contribution to journal › Article › peer-review
Electrochemical behavior of nickel bis-(2,6-diisopropylphenyl) diazobutadiene-1,4 dibromide in an aprotic solvent. / Matveev, D. A.; Sagitova, E. F.; Kraykivskii, P. B.; Petrovskii, S. K.; Gurinovich, N. S.; Saraev, V. V.
In: Russian Journal of Electrochemistry, Vol. 50, No. 3, 03.2014, p. 239-242.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Electrochemical behavior of nickel bis-(2,6-diisopropylphenyl) diazobutadiene-1,4 dibromide in an aprotic solvent
AU - Matveev, D. A.
AU - Sagitova, E. F.
AU - Kraykivskii, P. B.
AU - Petrovskii, S. K.
AU - Gurinovich, N. S.
AU - Saraev, V. V.
PY - 2014/3
Y1 - 2014/3
N2 - The electrochemical behavior of bis-(2,6-diisopropylphenyl)diazobutadiene- 1,4 and its nickel dibromide complex on dropping mercury and glassy carbon electrodes in an aprotic solvent was studied by AC polarography and cyclic voltammetry. Both the ligand and the nickel ion complex were shown to undergo electroreduction. The electrochemical reduction of nickel bis-(2,6- diisopropylphenyl)diazobutadiene-1,4 dibromide occurred stepwise and formed intermediate nickel(I) species.
AB - The electrochemical behavior of bis-(2,6-diisopropylphenyl)diazobutadiene- 1,4 and its nickel dibromide complex on dropping mercury and glassy carbon electrodes in an aprotic solvent was studied by AC polarography and cyclic voltammetry. Both the ligand and the nickel ion complex were shown to undergo electroreduction. The electrochemical reduction of nickel bis-(2,6- diisopropylphenyl)diazobutadiene-1,4 dibromide occurred stepwise and formed intermediate nickel(I) species.
KW - cyclic voltammetry
KW - electrochemical reduction
KW - nickel complexes
KW - polarography
UR - http://www.scopus.com/inward/record.url?scp=84897390643&partnerID=8YFLogxK
U2 - 10.1134/S1023193514030094
DO - 10.1134/S1023193514030094
M3 - Article
AN - SCOPUS:84897390643
VL - 50
SP - 239
EP - 242
JO - Russian Journal of Electrochemistry
JF - Russian Journal of Electrochemistry
SN - 1023-1935
IS - 3
ER -
ID: 51890937