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Electrical properties and the structure of halogen-containing lead borate glasses : II. The PbF2-PbO · B2O3 system. / Sokolov, I. A.; Murin, I. V.; Mel'nikova, N. A.; Pronkin, A. A.

In: Glass Physics and Chemistry, Vol. 28, No. 5, 01.12.2002, p. 303-308.

Research output: Contribution to journal › Article › peer-review

Harvard

Sokolov, IA, Murin, IV, Mel'nikova, NA & Pronkin, AA 2002, 'Electrical properties and the structure of halogen-containing lead borate glasses: II. The PbF2-PbO · B2O3 system', Glass Physics and Chemistry, vol. 28, no. 5, pp. 303-308. https://doi.org/10.1023/A:1020748610799

APA

Sokolov, I. A., Murin, I. V., Mel'nikova, N. A., & Pronkin, A. A. (2002). Electrical properties and the structure of halogen-containing lead borate glasses: II. The PbF2-PbO · B2O3 system. Glass Physics and Chemistry, 28(5), 303-308. https://doi.org/10.1023/A:1020748610799

Vancouver

Sokolov IA, Murin IV, Mel'nikova NA, Pronkin AA. Electrical properties and the structure of halogen-containing lead borate glasses: II. The PbF2-PbO · B2O3 system. Glass Physics and Chemistry. 2002 Dec 1;28(5):303-308. https://doi.org/10.1023/A:1020748610799

Author

Sokolov, I. A. ; Murin, I. V. ; Mel'nikova, N. A. ; Pronkin, A. A. / Electrical properties and the structure of halogen-containing lead borate glasses : II. The PbF2-PbO · B2O3 system. In: Glass Physics and Chemistry. 2002 ; Vol. 28, No. 5. pp. 303-308.

BibTeX

@article{9134868fcf184eb0b5795d7fa7cb6d2a,
title = "Electrical properties and the structure of halogen-containing lead borate glasses: II. The PbF2-PbO · B2O3 system",
abstract = "The temperature and concentration dependences of the dc electrical conductivity of glasses in the PbF2-PbO · B2O 3 system are investigated. It is found that the dependences logσ = f([PbF2]) and Eσ = [PbF2]) for glasses containing ∼20 and ∼35 mol% PbF2 exhibit kinks, which are interpreted from the standpoint of the microinhomogeneous structure associated with the selective interaction of the components during the synthesis of glasses. Analysis of the transport numbers has revealed that the unipolar fluorine ionic conductivity is observed upon introduction of more than 35 mol% PbF2. It is shown that, in the concentration range from 0 to 35 mol% PbF2, the electric current is provided by both protons and fluorine ions.",
author = "Sokolov, {I. A.} and Murin, {I. V.} and Mel'nikova, {N. A.} and Pronkin, {A. A.}",
year = "2002",
month = dec,
day = "1",
doi = "10.1023/A:1020748610799",
language = "English",
volume = "28",
pages = "303--308",
journal = "Glass Physics and Chemistry",
issn = "1087-6596",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "5",

}

RIS

TY - JOUR

T1 - Electrical properties and the structure of halogen-containing lead borate glasses

T2 - II. The PbF2-PbO · B2O3 system

AU - Sokolov, I. A.

AU - Murin, I. V.

AU - Mel'nikova, N. A.

AU - Pronkin, A. A.

PY - 2002/12/1

Y1 - 2002/12/1

N2 - The temperature and concentration dependences of the dc electrical conductivity of glasses in the PbF2-PbO · B2O 3 system are investigated. It is found that the dependences logσ = f([PbF2]) and Eσ = [PbF2]) for glasses containing ∼20 and ∼35 mol% PbF2 exhibit kinks, which are interpreted from the standpoint of the microinhomogeneous structure associated with the selective interaction of the components during the synthesis of glasses. Analysis of the transport numbers has revealed that the unipolar fluorine ionic conductivity is observed upon introduction of more than 35 mol% PbF2. It is shown that, in the concentration range from 0 to 35 mol% PbF2, the electric current is provided by both protons and fluorine ions.

AB - The temperature and concentration dependences of the dc electrical conductivity of glasses in the PbF2-PbO · B2O 3 system are investigated. It is found that the dependences logσ = f([PbF2]) and Eσ = [PbF2]) for glasses containing ∼20 and ∼35 mol% PbF2 exhibit kinks, which are interpreted from the standpoint of the microinhomogeneous structure associated with the selective interaction of the components during the synthesis of glasses. Analysis of the transport numbers has revealed that the unipolar fluorine ionic conductivity is observed upon introduction of more than 35 mol% PbF2. It is shown that, in the concentration range from 0 to 35 mol% PbF2, the electric current is provided by both protons and fluorine ions.

UR - http://www.scopus.com/inward/record.url?scp=0036033233&partnerID=8YFLogxK

U2 - 10.1023/A:1020748610799

DO - 10.1023/A:1020748610799

M3 - Article

AN - SCOPUS:0036033233

VL - 28

SP - 303

EP - 308

JO - Glass Physics and Chemistry

JF - Glass Physics and Chemistry

SN - 1087-6596

IS - 5

ER -

ID: 36321376