Standard

Electrical properties and the structure of halogen-containing lead borate glasses : I. The PbF2-2PbO · B2O3 system. / Sokolov, I. A.; Murin, I. V.; Mel'nikova, N. A.; Pronkin, A. A.

In: Glass Physics and Chemistry, Vol. 28, No. 5, 01.12.2002, p. 296-302.

Research output: Contribution to journal › Article › peer-review

Harvard

Sokolov, IA, Murin, IV, Mel'nikova, NA & Pronkin, AA 2002, 'Electrical properties and the structure of halogen-containing lead borate glasses: I. The PbF2-2PbO · B2O3 system', Glass Physics and Chemistry, vol. 28, no. 5, pp. 296-302. https://doi.org/10.1023/A:1020796526729

APA

Sokolov, I. A., Murin, I. V., Mel'nikova, N. A., & Pronkin, A. A. (2002). Electrical properties and the structure of halogen-containing lead borate glasses: I. The PbF2-2PbO · B2O3 system. Glass Physics and Chemistry, 28(5), 296-302. https://doi.org/10.1023/A:1020796526729

Vancouver

Sokolov IA, Murin IV, Mel'nikova NA, Pronkin AA. Electrical properties and the structure of halogen-containing lead borate glasses: I. The PbF2-2PbO · B2O3 system. Glass Physics and Chemistry. 2002 Dec 1;28(5):296-302. https://doi.org/10.1023/A:1020796526729

Author

Sokolov, I. A. ; Murin, I. V. ; Mel'nikova, N. A. ; Pronkin, A. A. / Electrical properties and the structure of halogen-containing lead borate glasses : I. The PbF2-2PbO · B2O3 system. In: Glass Physics and Chemistry. 2002 ; Vol. 28, No. 5. pp. 296-302.

BibTeX

@article{40feb8f2fffe4cd898991eaf58691c12,
title = "Electrical properties and the structure of halogen-containing lead borate glasses: I. The PbF2-2PbO · B2O3 system",
abstract = "The concentration and temperature dependences of the dc electrical conductivity σ of glasses in the PbF2-2PbO · B 2O3 system is investigated. It is found that, at 20-25 mol % PbF2, the dependences logσ = f([F]) and E σ = f([F]) exhibit kinks. The concentration dependence of the true transport number of fluorine ions ηF- is studied using the Tubandt method. It is shown that the introduction of 20-25 mol % PbF 2 leads to a crossover from the protonic conductivity to the unipolar fluorine ionic conductivity (ηF- = 1.00). The results obtained are discussed in terms of the Myuller theory of the microinhomogeneous glass structure associated with the selective interaction of the components during the synthesis.",
author = "Sokolov, {I. A.} and Murin, {I. V.} and Mel'nikova, {N. A.} and Pronkin, {A. A.}",
year = "2002",
month = dec,
day = "1",
doi = "10.1023/A:1020796526729",
language = "English",
volume = "28",
pages = "296--302",
journal = "Glass Physics and Chemistry",
issn = "1087-6596",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "5",

}

RIS

TY - JOUR

T1 - Electrical properties and the structure of halogen-containing lead borate glasses

T2 - I. The PbF2-2PbO · B2O3 system

AU - Sokolov, I. A.

AU - Murin, I. V.

AU - Mel'nikova, N. A.

AU - Pronkin, A. A.

PY - 2002/12/1

Y1 - 2002/12/1

N2 - The concentration and temperature dependences of the dc electrical conductivity σ of glasses in the PbF2-2PbO · B 2O3 system is investigated. It is found that, at 20-25 mol % PbF2, the dependences logσ = f([F]) and E σ = f([F]) exhibit kinks. The concentration dependence of the true transport number of fluorine ions ηF- is studied using the Tubandt method. It is shown that the introduction of 20-25 mol % PbF 2 leads to a crossover from the protonic conductivity to the unipolar fluorine ionic conductivity (ηF- = 1.00). The results obtained are discussed in terms of the Myuller theory of the microinhomogeneous glass structure associated with the selective interaction of the components during the synthesis.

AB - The concentration and temperature dependences of the dc electrical conductivity σ of glasses in the PbF2-2PbO · B 2O3 system is investigated. It is found that, at 20-25 mol % PbF2, the dependences logσ = f([F]) and E σ = f([F]) exhibit kinks. The concentration dependence of the true transport number of fluorine ions ηF- is studied using the Tubandt method. It is shown that the introduction of 20-25 mol % PbF 2 leads to a crossover from the protonic conductivity to the unipolar fluorine ionic conductivity (ηF- = 1.00). The results obtained are discussed in terms of the Myuller theory of the microinhomogeneous glass structure associated with the selective interaction of the components during the synthesis.

UR - http://www.scopus.com/inward/record.url?scp=0036033505&partnerID=8YFLogxK

U2 - 10.1023/A:1020796526729

DO - 10.1023/A:1020796526729

M3 - Article

AN - SCOPUS:0036033505

VL - 28

SP - 296

EP - 302

JO - Glass Physics and Chemistry

JF - Glass Physics and Chemistry

SN - 1087-6596

IS - 5

ER -

ID: 36321740