Standard

Electrical properties and the structure of glasses in the xNa 2O-(1 - x)2PbO · B2O3 system. / Sokolov, I. A.; Murin, I. V.; Mel'nikova, N. A.; Pronkin, A. A.

In: Glass Physics and Chemistry, Vol. 28, No. 4, 01.12.2002, p. 239-245.

Research output: Contribution to journal › Article › peer-review

Harvard

Sokolov, IA, Murin, IV, Mel'nikova, NA & Pronkin, AA 2002, 'Electrical properties and the structure of glasses in the xNa 2O-(1 - x)2PbO · B2O3 system', Glass Physics and Chemistry, vol. 28, no. 4, pp. 239-245. https://doi.org/10.1023/A:1019914329375

APA

Sokolov, I. A., Murin, I. V., Mel'nikova, N. A., & Pronkin, A. A. (2002). Electrical properties and the structure of glasses in the xNa 2O-(1 - x)2PbO · B2O3 system. Glass Physics and Chemistry, 28(4), 239-245. https://doi.org/10.1023/A:1019914329375

Vancouver

Sokolov IA, Murin IV, Mel'nikova NA, Pronkin AA. Electrical properties and the structure of glasses in the xNa 2O-(1 - x)2PbO · B2O3 system. Glass Physics and Chemistry. 2002 Dec 1;28(4):239-245. https://doi.org/10.1023/A:1019914329375

Author

Sokolov, I. A. ; Murin, I. V. ; Mel'nikova, N. A. ; Pronkin, A. A. / Electrical properties and the structure of glasses in the xNa 2O-(1 - x)2PbO · B2O3 system. In: Glass Physics and Chemistry. 2002 ; Vol. 28, No. 4. pp. 239-245.

BibTeX

@article{ee6d942d0c4845b0b83e82fb879875cb,
title = "Electrical properties and the structure of glasses in the xNa 2O-(1 - x)2PbO · B2O3 system",
abstract = "The temperature-concentration dependences of the electrical conductivity and the activation energy for electrical conduction of glasses in the Na 2O-B2O3 and Na2O4-2PbO · B2O3 systems are studied. The investigation into the nature of the electrical conduction in these glasses reveals that the contribution from the electronic component (10-3%) of the conductivity is within the sensitivity of the Liang Wagner technique. A considerable alkali conductivity is observed upon introduction of more than ∼12 mol % Na2O. The true transport number of sodium η Na+ is as large as unity at [Na2O] ≒ 15 mol %. It is shown that the observed temperature-concentration dependences of the electrical and transport properties are governed by the ratio between the concentrations of polar and nonpolar structural-chemical units of the Na +[BO4/2]-, Na+[O-BO 2/2] ⇒ Na+[O-BO2/2], Pb 1/2 2+[BO4/2]-, Pb1/2 2+[BO2/2], and [BO3/2] types.",
author = "Sokolov, {I. A.} and Murin, {I. V.} and Mel'nikova, {N. A.} and Pronkin, {A. A.}",
year = "2002",
month = dec,
day = "1",
doi = "10.1023/A:1019914329375",
language = "English",
volume = "28",
pages = "239--245",
journal = "Glass Physics and Chemistry",
issn = "1087-6596",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "4",

}

RIS

TY - JOUR

T1 - Electrical properties and the structure of glasses in the xNa 2O-(1 - x)2PbO · B2O3 system

AU - Sokolov, I. A.

AU - Murin, I. V.

AU - Mel'nikova, N. A.

AU - Pronkin, A. A.

PY - 2002/12/1

Y1 - 2002/12/1

N2 - The temperature-concentration dependences of the electrical conductivity and the activation energy for electrical conduction of glasses in the Na 2O-B2O3 and Na2O4-2PbO · B2O3 systems are studied. The investigation into the nature of the electrical conduction in these glasses reveals that the contribution from the electronic component (10-3%) of the conductivity is within the sensitivity of the Liang Wagner technique. A considerable alkali conductivity is observed upon introduction of more than ∼12 mol % Na2O. The true transport number of sodium η Na+ is as large as unity at [Na2O] ≒ 15 mol %. It is shown that the observed temperature-concentration dependences of the electrical and transport properties are governed by the ratio between the concentrations of polar and nonpolar structural-chemical units of the Na +[BO4/2]-, Na+[O-BO 2/2] ⇒ Na+[O-BO2/2], Pb 1/2 2+[BO4/2]-, Pb1/2 2+[BO2/2], and [BO3/2] types.

AB - The temperature-concentration dependences of the electrical conductivity and the activation energy for electrical conduction of glasses in the Na 2O-B2O3 and Na2O4-2PbO · B2O3 systems are studied. The investigation into the nature of the electrical conduction in these glasses reveals that the contribution from the electronic component (10-3%) of the conductivity is within the sensitivity of the Liang Wagner technique. A considerable alkali conductivity is observed upon introduction of more than ∼12 mol % Na2O. The true transport number of sodium η Na+ is as large as unity at [Na2O] ≒ 15 mol %. It is shown that the observed temperature-concentration dependences of the electrical and transport properties are governed by the ratio between the concentrations of polar and nonpolar structural-chemical units of the Na +[BO4/2]-, Na+[O-BO 2/2] ⇒ Na+[O-BO2/2], Pb 1/2 2+[BO4/2]-, Pb1/2 2+[BO2/2], and [BO3/2] types.

UR - http://www.scopus.com/inward/record.url?scp=0036356171&partnerID=8YFLogxK

U2 - 10.1023/A:1019914329375

DO - 10.1023/A:1019914329375

M3 - Article

AN - SCOPUS:0036356171

VL - 28

SP - 239

EP - 245

JO - Glass Physics and Chemistry

JF - Glass Physics and Chemistry

SN - 1087-6596

IS - 4

ER -

ID: 36321555