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Electrical and EPR studies of heterovalent solid solutions based on superionic β-PbF2. / ten Eicken, J.; Gunsser, W.; Chernov, S. V.; Glumov, A. V.; Murin, I. V.

In: Solid State Ionics, Vol. 53-56, No. PART 2, 1992, p. 843-848.

Research output: Contribution to journal › Article › peer-review

Harvard

ten Eicken, J, Gunsser, W, Chernov, SV, Glumov, AV & Murin, IV 1992, 'Electrical and EPR studies of heterovalent solid solutions based on superionic β-PbF2', Solid State Ionics, vol. 53-56, no. PART 2, pp. 843-848. https://doi.org/10.1016/0167-2738(92)90263-O

APA

ten Eicken, J., Gunsser, W., Chernov, S. V., Glumov, A. V., & Murin, I. V. (1992). Electrical and EPR studies of heterovalent solid solutions based on superionic β-PbF2. Solid State Ionics, 53-56(PART 2), 843-848. https://doi.org/10.1016/0167-2738(92)90263-O

Vancouver

ten Eicken J, Gunsser W, Chernov SV, Glumov AV, Murin IV. Electrical and EPR studies of heterovalent solid solutions based on superionic β-PbF2. Solid State Ionics. 1992;53-56(PART 2):843-848. https://doi.org/10.1016/0167-2738(92)90263-O

Author

ten Eicken, J. ; Gunsser, W. ; Chernov, S. V. ; Glumov, A. V. ; Murin, I. V. / Electrical and EPR studies of heterovalent solid solutions based on superionic β-PbF2. In: Solid State Ionics. 1992 ; Vol. 53-56, No. PART 2. pp. 843-848.

BibTeX

@article{2b07582eb2c946cc8ff7a84ef68cc4b9,
title = "Electrical and EPR studies of heterovalent solid solutions based on superionic β-PbF2",
abstract = "Ionic thermocurrent (ITC), ac-conductivity, and electron paramagnetic resonance (EPR) experiments have been performed on solid solutions Pb1-xRExF2+x. These hetrovalent solid solutions were prepared as crystals and powders by different te chniques. The differences in the dependence on concentration of the electrical properties are explained by the nature of defect structures. Using the ITC method we were able to distinguish different types of dipole defects created by the RE3+ cation and the charge compensating interstitial fluoride. The activation energies for all these complexes were determined and correlated with structural aspects. EPR-spectra (0.1 mol% GdF3 as a probe) for both polycrystalline and single crystals show three different RE-sites and are compared to spectra obtained from other Gd-doped fluorite-structured solid solutions.",
author = "{ten Eicken}, J. and W. Gunsser and Chernov, {S. V.} and Glumov, {A. V.} and Murin, {I. V.}",
note = "Funding Information: We gratefully appreciate the support given to one of us (J.t.E.) by the Alfried Krupp von Bohlen und Halbach Stiftung, and, furthermore, we want to thank Dr. Hofst~itter from the University of GieBen, Germany, for providing the doped CaF2 single crystal, Mrs. E. Seemann for the X-ray analysis, and Mr. U. K6nig for crystal cuts.",
year = "1992",
doi = "10.1016/0167-2738(92)90263-O",
language = "English",
volume = "53-56",
pages = "843--848",
journal = "Solid State Ionics",
issn = "0167-2738",
publisher = "Elsevier",
number = "PART 2",

}

RIS

TY - JOUR

T1 - Electrical and EPR studies of heterovalent solid solutions based on superionic β-PbF2

AU - ten Eicken, J.

AU - Gunsser, W.

AU - Chernov, S. V.

AU - Glumov, A. V.

AU - Murin, I. V.

N1 - Funding Information: We gratefully appreciate the support given to one of us (J.t.E.) by the Alfried Krupp von Bohlen und Halbach Stiftung, and, furthermore, we want to thank Dr. Hofst~itter from the University of GieBen, Germany, for providing the doped CaF2 single crystal, Mrs. E. Seemann for the X-ray analysis, and Mr. U. K6nig for crystal cuts.

PY - 1992

Y1 - 1992

N2 - Ionic thermocurrent (ITC), ac-conductivity, and electron paramagnetic resonance (EPR) experiments have been performed on solid solutions Pb1-xRExF2+x. These hetrovalent solid solutions were prepared as crystals and powders by different te chniques. The differences in the dependence on concentration of the electrical properties are explained by the nature of defect structures. Using the ITC method we were able to distinguish different types of dipole defects created by the RE3+ cation and the charge compensating interstitial fluoride. The activation energies for all these complexes were determined and correlated with structural aspects. EPR-spectra (0.1 mol% GdF3 as a probe) for both polycrystalline and single crystals show three different RE-sites and are compared to spectra obtained from other Gd-doped fluorite-structured solid solutions.

AB - Ionic thermocurrent (ITC), ac-conductivity, and electron paramagnetic resonance (EPR) experiments have been performed on solid solutions Pb1-xRExF2+x. These hetrovalent solid solutions were prepared as crystals and powders by different te chniques. The differences in the dependence on concentration of the electrical properties are explained by the nature of defect structures. Using the ITC method we were able to distinguish different types of dipole defects created by the RE3+ cation and the charge compensating interstitial fluoride. The activation energies for all these complexes were determined and correlated with structural aspects. EPR-spectra (0.1 mol% GdF3 as a probe) for both polycrystalline and single crystals show three different RE-sites and are compared to spectra obtained from other Gd-doped fluorite-structured solid solutions.

UR - http://www.scopus.com/inward/record.url?scp=0026896729&partnerID=8YFLogxK

U2 - 10.1016/0167-2738(92)90263-O

DO - 10.1016/0167-2738(92)90263-O

M3 - Article

AN - SCOPUS:0026896729

VL - 53-56

SP - 843

EP - 848

JO - Solid State Ionics

JF - Solid State Ionics

SN - 0167-2738

IS - PART 2

ER -

ID: 88000792