Research output: Contribution to journal › Article › peer-review
Effect of vibrations on C 1s photoemission in formaldehyde in the shape resonance region. / De Fanis, A.; Mistrov, D. A.; Kitajima, M.; Hoshino, M.; Shindo, H.; Tanaka, T.; Tanaka, H.; Tamenori, Y.; Pavlychev, A. A.; Ueda, K.
In: Physical Review A - Atomic, Molecular, and Optical Physics, Vol. 71, No. 5, 052510, 01.05.2005.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Effect of vibrations on C 1s photoemission in formaldehyde in the shape resonance region
AU - De Fanis, A.
AU - Mistrov, D. A.
AU - Kitajima, M.
AU - Hoshino, M.
AU - Shindo, H.
AU - Tanaka, T.
AU - Tanaka, H.
AU - Tamenori, Y.
AU - Pavlychev, A. A.
AU - Ueda, K.
PY - 2005/5/1
Y1 - 2005/5/1
N2 - The vibrationally resolved C 1s single-hole ionization cross sections of H2CO are measured in the region of the σ* shape resonance. The energy of the shape resonance is pushed down by the excitation of the C-O stretching vibration v2′. Our calculations, which take account of elastic multiple scattering within the C-O potential box, show that the downward shift of the shape resonance energy is originated from the elongation of the characteristic internuclear C-O distance in the core-ionized molecule with an increase in v2′. The characteristic internuclear distance varies from R+(0,0,0)=1.198 up to R+(0,2,0)=1.415. In addition to the elastic multiple-scattering mechanism, the internal inelastic scattering of the C 1s photoelectron by valence electrons is suggested as a possible mechanism responsible for the enhancement of vibrational excitations through the shape resonance and near threshold.
AB - The vibrationally resolved C 1s single-hole ionization cross sections of H2CO are measured in the region of the σ* shape resonance. The energy of the shape resonance is pushed down by the excitation of the C-O stretching vibration v2′. Our calculations, which take account of elastic multiple scattering within the C-O potential box, show that the downward shift of the shape resonance energy is originated from the elongation of the characteristic internuclear C-O distance in the core-ionized molecule with an increase in v2′. The characteristic internuclear distance varies from R+(0,0,0)=1.198 up to R+(0,2,0)=1.415. In addition to the elastic multiple-scattering mechanism, the internal inelastic scattering of the C 1s photoelectron by valence electrons is suggested as a possible mechanism responsible for the enhancement of vibrational excitations through the shape resonance and near threshold.
UR - http://www.scopus.com/inward/record.url?scp=27144525312&partnerID=8YFLogxK
U2 - 10.1103/PhysRevA.71.052510
DO - 10.1103/PhysRevA.71.052510
M3 - Article
AN - SCOPUS:27144525312
VL - 71
JO - Physical Review A - Atomic, Molecular, and Optical Physics
JF - Physical Review A - Atomic, Molecular, and Optical Physics
SN - 1050-2947
IS - 5
M1 - 052510
ER -
ID: 43207342