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Effect of the nature of fluid and structure of β-diketone on supercritical extraction of metal β-diketonate complexes. / Babain, V. A.; Kamachev, V. A.; Kiseleva, R. N.; Murzin, A. A.; Smirnov, I. V.; Shadrin, A. Yu; Yakimovich, S. I.; Zerova, I. V.

In: Radiochemistry, Vol. 45, No. 6, 01.11.2003, p. 602-604.

Research output: Contribution to journalArticlepeer-review

Harvard

Babain, VA, Kamachev, VA, Kiseleva, RN, Murzin, AA, Smirnov, IV, Shadrin, AY, Yakimovich, SI & Zerova, IV 2003, 'Effect of the nature of fluid and structure of β-diketone on supercritical extraction of metal β-diketonate complexes', Radiochemistry, vol. 45, no. 6, pp. 602-604. https://doi.org/10.1023/B:RACH.0000015759.79741.b7

APA

Babain, V. A., Kamachev, V. A., Kiseleva, R. N., Murzin, A. A., Smirnov, I. V., Shadrin, A. Y., Yakimovich, S. I., & Zerova, I. V. (2003). Effect of the nature of fluid and structure of β-diketone on supercritical extraction of metal β-diketonate complexes. Radiochemistry, 45(6), 602-604. https://doi.org/10.1023/B:RACH.0000015759.79741.b7

Vancouver

Author

Babain, V. A. ; Kamachev, V. A. ; Kiseleva, R. N. ; Murzin, A. A. ; Smirnov, I. V. ; Shadrin, A. Yu ; Yakimovich, S. I. ; Zerova, I. V. / Effect of the nature of fluid and structure of β-diketone on supercritical extraction of metal β-diketonate complexes. In: Radiochemistry. 2003 ; Vol. 45, No. 6. pp. 602-604.

BibTeX

@article{36774bc68ee243aa832226606df71b70,
title = "Effect of the nature of fluid and structure of β-diketone on supercritical extraction of metal β-diketonate complexes",
abstract = "Extraction of uranium with trifluoromethyl alkyl diketones differing in the length of the alkyl chain was studied. The size of the alkyl group only slightly affects the extraction. Extraction of complexes formed by uranyl nitrate with β-diketones in pentafluoroethane (Freon-125) was studied. The complexes are efficiently extracted with both super- and subcritical Freon-125. In contrast to extraction of these complexes in supercritical CO2, in extraction with Freon-125 the complexes do not decompose.",
author = "Babain, {V. A.} and Kamachev, {V. A.} and Kiseleva, {R. N.} and Murzin, {A. A.} and Smirnov, {I. V.} and Shadrin, {A. Yu} and Yakimovich, {S. I.} and Zerova, {I. V.}",
year = "2003",
month = nov,
day = "1",
doi = "10.1023/B:RACH.0000015759.79741.b7",
language = "English",
volume = "45",
pages = "602--604",
journal = "Radiochemistry",
issn = "1066-3622",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "6",

}

RIS

TY - JOUR

T1 - Effect of the nature of fluid and structure of β-diketone on supercritical extraction of metal β-diketonate complexes

AU - Babain, V. A.

AU - Kamachev, V. A.

AU - Kiseleva, R. N.

AU - Murzin, A. A.

AU - Smirnov, I. V.

AU - Shadrin, A. Yu

AU - Yakimovich, S. I.

AU - Zerova, I. V.

PY - 2003/11/1

Y1 - 2003/11/1

N2 - Extraction of uranium with trifluoromethyl alkyl diketones differing in the length of the alkyl chain was studied. The size of the alkyl group only slightly affects the extraction. Extraction of complexes formed by uranyl nitrate with β-diketones in pentafluoroethane (Freon-125) was studied. The complexes are efficiently extracted with both super- and subcritical Freon-125. In contrast to extraction of these complexes in supercritical CO2, in extraction with Freon-125 the complexes do not decompose.

AB - Extraction of uranium with trifluoromethyl alkyl diketones differing in the length of the alkyl chain was studied. The size of the alkyl group only slightly affects the extraction. Extraction of complexes formed by uranyl nitrate with β-diketones in pentafluoroethane (Freon-125) was studied. The complexes are efficiently extracted with both super- and subcritical Freon-125. In contrast to extraction of these complexes in supercritical CO2, in extraction with Freon-125 the complexes do not decompose.

UR - http://www.scopus.com/inward/record.url?scp=3843131690&partnerID=8YFLogxK

U2 - 10.1023/B:RACH.0000015759.79741.b7

DO - 10.1023/B:RACH.0000015759.79741.b7

M3 - Article

AN - SCOPUS:3843131690

VL - 45

SP - 602

EP - 604

JO - Radiochemistry

JF - Radiochemistry

SN - 1066-3622

IS - 6

ER -

ID: 53580405