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Effect of the electrode material on the reduction of La3+ and Ce3+ in fluoride-conducting solid electrolytes. / Turaeva, M. S.; Kot, S. A.; Urchukova, M. M.; Murin, I. V.

In: Russian Journal of Electrochemistry, Vol. 41, No. 5, 05.2005, p. 582-591.

Research output: Contribution to journal › Article › peer-review

Harvard

Turaeva, MS, Kot, SA, Urchukova, MM & Murin, IV 2005, 'Effect of the electrode material on the reduction of La3+ and Ce3+ in fluoride-conducting solid electrolytes', Russian Journal of Electrochemistry, vol. 41, no. 5, pp. 582-591. https://doi.org/10.1007/s11175-005-0110-3

APA

Turaeva, M. S., Kot, S. A., Urchukova, M. M., & Murin, I. V. (2005). Effect of the electrode material on the reduction of La3+ and Ce3+ in fluoride-conducting solid electrolytes. Russian Journal of Electrochemistry, 41(5), 582-591. https://doi.org/10.1007/s11175-005-0110-3

Vancouver

Turaeva MS, Kot SA, Urchukova MM, Murin IV. Effect of the electrode material on the reduction of La3+ and Ce3+ in fluoride-conducting solid electrolytes. Russian Journal of Electrochemistry. 2005 May;41(5):582-591. https://doi.org/10.1007/s11175-005-0110-3

Author

Turaeva, M. S. ; Kot, S. A. ; Urchukova, M. M. ; Murin, I. V. / Effect of the electrode material on the reduction of La3+ and Ce3+ in fluoride-conducting solid electrolytes. In: Russian Journal of Electrochemistry. 2005 ; Vol. 41, No. 5. pp. 582-591.

BibTeX

@article{c0aa7e550ce84a949b306de0a117e58f,
title = "Effect of the electrode material on the reduction of La3+ and Ce3+ in fluoride-conducting solid electrolytes",
abstract = "The reduction of immobile cations La3+ and Ce3+ in fluoride-conducting solid electrolytes (FSE) LaF3 (Eu2+ 0.8 mol %), LaF3 (Sr2+ 5 mol %), and CeF3 (Sr2+ 5 mol %) in contact with Ag, Bi, Si, La, Ce, and Sm working electrodes is studied by chronoamperometry and voltammetry with linear potential scan. Discovered is linear dependence of initial segments of potentiostatic transients of cathodic current on t 1/2 at FSE interfaces with Ag, Bi, La, Ce, and Sm. The dependence is due to diffusion-controlled instantaneous nucleation of Ln and Ce. The La3+ and Ce3+ reduction at the FSE/Ag interface is reversible in a narrow region. The reduction and oxidation of La3+ and Ce3+ (cations of the FSE rigid lattice) at the FSE/Me (Me = La, Ce and Sm, Bi, Si) interface is irreversible and involves a chemical reaction.",
keywords = "Fluoride-conducting solid electrolyte, Potentiostatic current transient, Voltammetry",
author = "Turaeva, {M. S.} and Kot, {S. A.} and Urchukova, {M. M.} and Murin, {I. V.}",
year = "2005",
month = may,
doi = "10.1007/s11175-005-0110-3",
language = "English",
volume = "41",
pages = "582--591",
journal = "Russian Journal of Electrochemistry",
issn = "1023-1935",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "5",

}

RIS

TY - JOUR

T1 - Effect of the electrode material on the reduction of La3+ and Ce3+ in fluoride-conducting solid electrolytes

AU - Turaeva, M. S.

AU - Kot, S. A.

AU - Urchukova, M. M.

AU - Murin, I. V.

PY - 2005/5

Y1 - 2005/5

N2 - The reduction of immobile cations La3+ and Ce3+ in fluoride-conducting solid electrolytes (FSE) LaF3 (Eu2+ 0.8 mol %), LaF3 (Sr2+ 5 mol %), and CeF3 (Sr2+ 5 mol %) in contact with Ag, Bi, Si, La, Ce, and Sm working electrodes is studied by chronoamperometry and voltammetry with linear potential scan. Discovered is linear dependence of initial segments of potentiostatic transients of cathodic current on t 1/2 at FSE interfaces with Ag, Bi, La, Ce, and Sm. The dependence is due to diffusion-controlled instantaneous nucleation of Ln and Ce. The La3+ and Ce3+ reduction at the FSE/Ag interface is reversible in a narrow region. The reduction and oxidation of La3+ and Ce3+ (cations of the FSE rigid lattice) at the FSE/Me (Me = La, Ce and Sm, Bi, Si) interface is irreversible and involves a chemical reaction.

AB - The reduction of immobile cations La3+ and Ce3+ in fluoride-conducting solid electrolytes (FSE) LaF3 (Eu2+ 0.8 mol %), LaF3 (Sr2+ 5 mol %), and CeF3 (Sr2+ 5 mol %) in contact with Ag, Bi, Si, La, Ce, and Sm working electrodes is studied by chronoamperometry and voltammetry with linear potential scan. Discovered is linear dependence of initial segments of potentiostatic transients of cathodic current on t 1/2 at FSE interfaces with Ag, Bi, La, Ce, and Sm. The dependence is due to diffusion-controlled instantaneous nucleation of Ln and Ce. The La3+ and Ce3+ reduction at the FSE/Ag interface is reversible in a narrow region. The reduction and oxidation of La3+ and Ce3+ (cations of the FSE rigid lattice) at the FSE/Me (Me = La, Ce and Sm, Bi, Si) interface is irreversible and involves a chemical reaction.

KW - Fluoride-conducting solid electrolyte

KW - Potentiostatic current transient

KW - Voltammetry

UR - http://www.scopus.com/inward/record.url?scp=21644479037&partnerID=8YFLogxK

U2 - 10.1007/s11175-005-0110-3

DO - 10.1007/s11175-005-0110-3

M3 - Article

AN - SCOPUS:21644479037

VL - 41

SP - 582

EP - 591

JO - Russian Journal of Electrochemistry

JF - Russian Journal of Electrochemistry

SN - 1023-1935

IS - 5

ER -

ID: 88002008