Effect of synthesis conditions on structural, morphological and luminescence properties of MgAl2O4:Eu3+ nanopowders

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Effect of synthesis conditions on structural, morphological and luminescence properties of MgAl₂O₄:Eu³⁺ nanopowders. / Golyeva, E. V.; Kolesnikov, I. E.; Lähderanta, E.; Kurochkin, A. V.; Mikhailov, M. D.

In: Journal of Luminescence, Vol. 194, 02.2018, p. 387-393.

Research output: Contribution to journal › Article › peer-review

Author

Golyeva, E. V. ; Kolesnikov, I. E. ; Lähderanta, E. ; Kurochkin, A. V. ; Mikhailov, M. D. / Effect of synthesis conditions on structural, morphological and luminescence properties of MgAl₂O₄:Eu³⁺ nanopowders. In: Journal of Luminescence. 2018 ; Vol. 194. pp. 387-393.

BibTeX

@article{42b2942444d145589e75f409c582a41b,

title = "Effect of synthesis conditions on structural, morphological and luminescence properties of MgAl2O4:Eu3+ nanopowders",

abstract = "Nanocrystalline aluminium magnesium spinel doped with europium ions powders were synthesized via modified Pechini method. The effect of synthesis conditions (calcination temperature and duration) on structural, morphological and luminescence properties of obtained nanopowders was studied. Both X-ray diffraction and Rietveld analysis showed that samples consist of only one crystalline phase – face-centred cubic spinel. The SEM and SLS analysis demonstrated that average particle size is about 50 nm. It was shown that the solubility limit of europium ions Eu3+ in MgAl2O4 nanocrystals depends on the calcination temperature. When europium is introduced into the aluminium magnesium spinel, the crystalline structure is disordered. It was found that unlike calcination temperature, duration of heat treatment does not affect powders properties. It was shown that strong structural and luminescence changes take place when calcination temperature is near 2/3 of MgAl2O4 melting temperature. The optimal conditions for synthesis nanopowders were determined as follows: Т1=600 °С t1=1.5 h, Т2=850 °С t2=2 h.",

keywords = "SOL-GEL METHOD, PHOTOLUMINESCENCE PROPERTIES, EU3+ CONCENTRATION, PECHINI METHOD, NANOPARTICLES, PHOSPHORS, YVO4, CERAMICS, GLASSES",

author = "Golyeva, {E. V.} and Kolesnikov, {I. E.} and E. L{\"a}hderanta and Kurochkin, {A. V.} and Mikhailov, {M. D.}",

year = "2018",

month = feb,

doi = "10.1016/j.jlumin.2017.10.068",

language = "English",

volume = "194",

pages = "387--393",

journal = "Journal of Luminescence",

issn = "0022-2313",

publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Effect of synthesis conditions on structural, morphological and luminescence properties of MgAl2O4:Eu3+ nanopowders

AU - Golyeva, E. V.

AU - Kolesnikov, I. E.

AU - Lähderanta, E.

AU - Kurochkin, A. V.

AU - Mikhailov, M. D.

PY - 2018/2

Y1 - 2018/2

N2 - Nanocrystalline aluminium magnesium spinel doped with europium ions powders were synthesized via modified Pechini method. The effect of synthesis conditions (calcination temperature and duration) on structural, morphological and luminescence properties of obtained nanopowders was studied. Both X-ray diffraction and Rietveld analysis showed that samples consist of only one crystalline phase – face-centred cubic spinel. The SEM and SLS analysis demonstrated that average particle size is about 50 nm. It was shown that the solubility limit of europium ions Eu3+ in MgAl2O4 nanocrystals depends on the calcination temperature. When europium is introduced into the aluminium magnesium spinel, the crystalline structure is disordered. It was found that unlike calcination temperature, duration of heat treatment does not affect powders properties. It was shown that strong structural and luminescence changes take place when calcination temperature is near 2/3 of MgAl2O4 melting temperature. The optimal conditions for synthesis nanopowders were determined as follows: Т1=600 °С t1=1.5 h, Т2=850 °С t2=2 h.

AB - Nanocrystalline aluminium magnesium spinel doped with europium ions powders were synthesized via modified Pechini method. The effect of synthesis conditions (calcination temperature and duration) on structural, morphological and luminescence properties of obtained nanopowders was studied. Both X-ray diffraction and Rietveld analysis showed that samples consist of only one crystalline phase – face-centred cubic spinel. The SEM and SLS analysis demonstrated that average particle size is about 50 nm. It was shown that the solubility limit of europium ions Eu3+ in MgAl2O4 nanocrystals depends on the calcination temperature. When europium is introduced into the aluminium magnesium spinel, the crystalline structure is disordered. It was found that unlike calcination temperature, duration of heat treatment does not affect powders properties. It was shown that strong structural and luminescence changes take place when calcination temperature is near 2/3 of MgAl2O4 melting temperature. The optimal conditions for synthesis nanopowders were determined as follows: Т1=600 °С t1=1.5 h, Т2=850 °С t2=2 h.

KW - SOL-GEL METHOD

KW - PHOTOLUMINESCENCE PROPERTIES

KW - EU3+ CONCENTRATION

KW - PECHINI METHOD

KW - NANOPARTICLES

KW - PHOSPHORS

KW - YVO4

KW - CERAMICS

KW - GLASSES

UR - http://www.scopus.com/inward/record.url?scp=85032337486&partnerID=8YFLogxK

UR - http://www.mendeley.com/research/effect-synthesis-conditions-structural-morphological-luminescence-properties-mgal2o4eu3nanopowders

U2 - 10.1016/j.jlumin.2017.10.068

DO - 10.1016/j.jlumin.2017.10.068

M3 - Article

AN - SCOPUS:85032337486

VL - 194

SP - 387

EP - 393

JO - Journal of Luminescence

JF - Journal of Luminescence

SN - 0022-2313

ER -

ID: 36095764