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Effect of Structure of Polymeric Nickel Complexes with Salen-Type Ligands on the Rate of Their Electroactivity Decay in Solutions of Water-Containing Electrolytes. / Ershov, V. A.; Alekseeva, E. V.; Konev, A. S.; Chirkov, N. S.; Stelmashuk, T. A.; Levin, O. V.

In: Russian Journal of General Chemistry, Vol. 88, No. 2, 01.02.2018, p. 277-283.

Research output: Contribution to journal › Article › peer-review

Harvard

Ershov, VA, Alekseeva, EV, Konev, AS, Chirkov, NS, Stelmashuk, TA & Levin, OV 2018, 'Effect of Structure of Polymeric Nickel Complexes with Salen-Type Ligands on the Rate of Their Electroactivity Decay in Solutions of Water-Containing Electrolytes', Russian Journal of General Chemistry, vol. 88, no. 2, pp. 277-283. https://doi.org/10.1134/S1070363218020147

APA

Ershov, V. A., Alekseeva, E. V., Konev, A. S., Chirkov, N. S., Stelmashuk, T. A., & Levin, O. V. (2018). Effect of Structure of Polymeric Nickel Complexes with Salen-Type Ligands on the Rate of Their Electroactivity Decay in Solutions of Water-Containing Electrolytes. Russian Journal of General Chemistry, 88(2), 277-283. https://doi.org/10.1134/S1070363218020147

Vancouver

Ershov VA, Alekseeva EV, Konev AS, Chirkov NS, Stelmashuk TA, Levin OV. Effect of Structure of Polymeric Nickel Complexes with Salen-Type Ligands on the Rate of Their Electroactivity Decay in Solutions of Water-Containing Electrolytes. Russian Journal of General Chemistry. 2018 Feb 1;88(2):277-283. https://doi.org/10.1134/S1070363218020147

Author

Ershov, V. A. ; Alekseeva, E. V. ; Konev, A. S. ; Chirkov, N. S. ; Stelmashuk, T. A. ; Levin, O. V. / Effect of Structure of Polymeric Nickel Complexes with Salen-Type Ligands on the Rate of Their Electroactivity Decay in Solutions of Water-Containing Electrolytes. In: Russian Journal of General Chemistry. 2018 ; Vol. 88, No. 2. pp. 277-283.

BibTeX

@article{9b4c0d9393da4c47bc198a2eb34fd22f,
title = "Effect of Structure of Polymeric Nickel Complexes with Salen-Type Ligands on the Rate of Their Electroactivity Decay in Solutions of Water-Containing Electrolytes",
abstract = "The influence of the structure of diimine bridge in the Schiff{\textquoteright}s bases (derivatives of N,N'-ethylenebissalicylimine) on the rate of the loss of electroactivity of their complexes with nickel in acetonitrile containing 0.1 M of tetraethylammonium tetrafluoroborate (anhydrous and upon addition of 1 wt % of water) has been studied. It has been shown that the presence of bulky yet light methyl groups in the structure of diimine bridge significantly reduced the loss of electroactivity (37% of the initial capacity retained after 50 cycles) as compared to the ligand containing no substituents and containing phenyl group as the substituent (17 and 20%, respectively, of initial capacity retained after 50 cycles).",
keywords = "aqueous electrolytes, degradation of electroactivity, polymer-modified electrodes, Schiff{\textquoteright}s bases, specific capacity",
author = "Ershov, {V. A.} and Alekseeva, {E. V.} and Konev, {A. S.} and Chirkov, {N. S.} and Stelmashuk, {T. A.} and Levin, {O. V.}",
year = "2018",
month = feb,
day = "1",
doi = "10.1134/S1070363218020147",
language = "English",
volume = "88",
pages = "277--283",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "2",

}

RIS

TY - JOUR

T1 - Effect of Structure of Polymeric Nickel Complexes with Salen-Type Ligands on the Rate of Their Electroactivity Decay in Solutions of Water-Containing Electrolytes

AU - Ershov, V. A.

AU - Alekseeva, E. V.

AU - Konev, A. S.

AU - Chirkov, N. S.

AU - Stelmashuk, T. A.

AU - Levin, O. V.

PY - 2018/2/1

Y1 - 2018/2/1

N2 - The influence of the structure of diimine bridge in the Schiff’s bases (derivatives of N,N'-ethylenebissalicylimine) on the rate of the loss of electroactivity of their complexes with nickel in acetonitrile containing 0.1 M of tetraethylammonium tetrafluoroborate (anhydrous and upon addition of 1 wt % of water) has been studied. It has been shown that the presence of bulky yet light methyl groups in the structure of diimine bridge significantly reduced the loss of electroactivity (37% of the initial capacity retained after 50 cycles) as compared to the ligand containing no substituents and containing phenyl group as the substituent (17 and 20%, respectively, of initial capacity retained after 50 cycles).

AB - The influence of the structure of diimine bridge in the Schiff’s bases (derivatives of N,N'-ethylenebissalicylimine) on the rate of the loss of electroactivity of their complexes with nickel in acetonitrile containing 0.1 M of tetraethylammonium tetrafluoroborate (anhydrous and upon addition of 1 wt % of water) has been studied. It has been shown that the presence of bulky yet light methyl groups in the structure of diimine bridge significantly reduced the loss of electroactivity (37% of the initial capacity retained after 50 cycles) as compared to the ligand containing no substituents and containing phenyl group as the substituent (17 and 20%, respectively, of initial capacity retained after 50 cycles).

KW - aqueous electrolytes

KW - degradation of electroactivity

KW - polymer-modified electrodes

KW - Schiff’s bases

KW - specific capacity

UR - http://www.scopus.com/inward/record.url?scp=85044224145&partnerID=8YFLogxK

UR - http://www.mendeley.com/research/effect-structure-polymeric-nickel-complexes-salentype-ligands-rate-electroactivity-decay-solutions-w

U2 - 10.1134/S1070363218020147

DO - 10.1134/S1070363218020147

M3 - Article

AN - SCOPUS:85044224145

VL - 88

SP - 277

EP - 283

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 2

ER -

ID: 34507324