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Effect of Modifiers on the Electrophoretic Separation and Intercapillary Preconcentration of Biologically Active Compounds. / Kravchenko, A. V. ; Kartsova, L. A. .

In: Journal of Analytical Chemistry, Vol. 76, No. 9, 09.2021, p. 1043-1050.

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Kravchenko, A. V. ; Kartsova, L. A. . / Effect of Modifiers on the Electrophoretic Separation and Intercapillary Preconcentration of Biologically Active Compounds. In: Journal of Analytical Chemistry. 2021 ; Vol. 76, No. 9. pp. 1043-1050.

BibTeX

@article{49db7bc970d74c0bbe50ee10d8ac97d8,
title = "Effect of Modifiers on the Electrophoretic Separation and Intercapillary Preconcentration of Biologically Active Compounds",
abstract = "The use of modifiers in the electrophoretic separation of multicomponent mixtures makes it possible to significantly expand the analytical capabilities of capillary electrophoresis. Modifiers of electrophoretic systems, different in nature and properties, can perform different functions: form stationary and pseudo-stationary phases, prevent the adsorption of analytes on the walls of a quartz capillary, help to reduce the limits of detection for analytes during preconcentration, etc. In this review, various versions of the application of modifiers to the electrophoretic separation and preconcentration of analytes of different nature are considered on an example of imidazolium ionic liquids, which can act as stationary and pseudo-stationary phases, and also directly participate in the online preconcentration of analytes of hydrophilic and hydrophobic nature.",
keywords = "capillary electrophoresis, capillary electrochromatography, Micellar electrokinetic chromatography, modifiers, online preconcentration, Imidazolium ionic liquids, imidazolium ionic liquids, micellar electrokinetic chromatography, MICELLE, IONIC LIQUID, ONLINE PRECONCENTRATION, SOLVENT, BETA-AGONISTS, AMINO-ACIDS, SAMPLE CONCENTRATION, ELECTROKINETIC CHROMATOGRAPHY, POLYMER, CAPILLARY-ELECTROPHORESIS",
author = "Kravchenko, {A. V.} and Kartsova, {L. A.}",
note = "Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd.",
year = "2021",
month = sep,
doi = "10.1134/S1061934821090069",
language = "English",
volume = "76",
pages = "1043--1050",
journal = "Journal of Analytical Chemistry",
issn = "1061-9348",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "9",

}

RIS

TY - JOUR

T1 - Effect of Modifiers on the Electrophoretic Separation and Intercapillary Preconcentration of Biologically Active Compounds

AU - Kravchenko, A. V.

AU - Kartsova, L. A.

N1 - Publisher Copyright: © 2021, Pleiades Publishing, Ltd.

PY - 2021/9

Y1 - 2021/9

N2 - The use of modifiers in the electrophoretic separation of multicomponent mixtures makes it possible to significantly expand the analytical capabilities of capillary electrophoresis. Modifiers of electrophoretic systems, different in nature and properties, can perform different functions: form stationary and pseudo-stationary phases, prevent the adsorption of analytes on the walls of a quartz capillary, help to reduce the limits of detection for analytes during preconcentration, etc. In this review, various versions of the application of modifiers to the electrophoretic separation and preconcentration of analytes of different nature are considered on an example of imidazolium ionic liquids, which can act as stationary and pseudo-stationary phases, and also directly participate in the online preconcentration of analytes of hydrophilic and hydrophobic nature.

AB - The use of modifiers in the electrophoretic separation of multicomponent mixtures makes it possible to significantly expand the analytical capabilities of capillary electrophoresis. Modifiers of electrophoretic systems, different in nature and properties, can perform different functions: form stationary and pseudo-stationary phases, prevent the adsorption of analytes on the walls of a quartz capillary, help to reduce the limits of detection for analytes during preconcentration, etc. In this review, various versions of the application of modifiers to the electrophoretic separation and preconcentration of analytes of different nature are considered on an example of imidazolium ionic liquids, which can act as stationary and pseudo-stationary phases, and also directly participate in the online preconcentration of analytes of hydrophilic and hydrophobic nature.

KW - capillary electrophoresis

KW - capillary electrochromatography

KW - Micellar electrokinetic chromatography

KW - modifiers

KW - online preconcentration

KW - Imidazolium ionic liquids

KW - imidazolium ionic liquids

KW - micellar electrokinetic chromatography

KW - MICELLE

KW - IONIC LIQUID

KW - ONLINE PRECONCENTRATION

KW - SOLVENT

KW - BETA-AGONISTS

KW - AMINO-ACIDS

KW - SAMPLE CONCENTRATION

KW - ELECTROKINETIC CHROMATOGRAPHY

KW - POLYMER

KW - CAPILLARY-ELECTROPHORESIS

UR - http://www.scopus.com/inward/record.url?scp=85114429208&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/88114381-3671-3321-953a-49465558f6b8/

U2 - 10.1134/S1061934821090069

DO - 10.1134/S1061934821090069

M3 - Review article

VL - 76

SP - 1043

EP - 1050

JO - Journal of Analytical Chemistry

JF - Journal of Analytical Chemistry

SN - 1061-9348

IS - 9

ER -

ID: 86617583