Research output: Contribution to journal › Review article › peer-review
Effect of Modifiers on the Electrophoretic Separation and Intercapillary Preconcentration of Biologically Active Compounds. / Kravchenko, A. V. ; Kartsova, L. A. .
In: Journal of Analytical Chemistry, Vol. 76, No. 9, 09.2021, p. 1043-1050.Research output: Contribution to journal › Review article › peer-review
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TY - JOUR
T1 - Effect of Modifiers on the Electrophoretic Separation and Intercapillary Preconcentration of Biologically Active Compounds
AU - Kravchenko, A. V.
AU - Kartsova, L. A.
N1 - Publisher Copyright: © 2021, Pleiades Publishing, Ltd.
PY - 2021/9
Y1 - 2021/9
N2 - The use of modifiers in the electrophoretic separation of multicomponent mixtures makes it possible to significantly expand the analytical capabilities of capillary electrophoresis. Modifiers of electrophoretic systems, different in nature and properties, can perform different functions: form stationary and pseudo-stationary phases, prevent the adsorption of analytes on the walls of a quartz capillary, help to reduce the limits of detection for analytes during preconcentration, etc. In this review, various versions of the application of modifiers to the electrophoretic separation and preconcentration of analytes of different nature are considered on an example of imidazolium ionic liquids, which can act as stationary and pseudo-stationary phases, and also directly participate in the online preconcentration of analytes of hydrophilic and hydrophobic nature.
AB - The use of modifiers in the electrophoretic separation of multicomponent mixtures makes it possible to significantly expand the analytical capabilities of capillary electrophoresis. Modifiers of electrophoretic systems, different in nature and properties, can perform different functions: form stationary and pseudo-stationary phases, prevent the adsorption of analytes on the walls of a quartz capillary, help to reduce the limits of detection for analytes during preconcentration, etc. In this review, various versions of the application of modifiers to the electrophoretic separation and preconcentration of analytes of different nature are considered on an example of imidazolium ionic liquids, which can act as stationary and pseudo-stationary phases, and also directly participate in the online preconcentration of analytes of hydrophilic and hydrophobic nature.
KW - capillary electrophoresis
KW - capillary electrochromatography
KW - Micellar electrokinetic chromatography
KW - modifiers
KW - online preconcentration
KW - Imidazolium ionic liquids
KW - imidazolium ionic liquids
KW - micellar electrokinetic chromatography
KW - MICELLE
KW - IONIC LIQUID
KW - ONLINE PRECONCENTRATION
KW - SOLVENT
KW - BETA-AGONISTS
KW - AMINO-ACIDS
KW - SAMPLE CONCENTRATION
KW - ELECTROKINETIC CHROMATOGRAPHY
KW - POLYMER
KW - CAPILLARY-ELECTROPHORESIS
UR - http://www.scopus.com/inward/record.url?scp=85114429208&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/88114381-3671-3321-953a-49465558f6b8/
U2 - 10.1134/S1061934821090069
DO - 10.1134/S1061934821090069
M3 - Review article
VL - 76
SP - 1043
EP - 1050
JO - Journal of Analytical Chemistry
JF - Journal of Analytical Chemistry
SN - 1061-9348
IS - 9
ER -
ID: 86617583