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Effect of Electrode Material on Electrodeposition of Tungsten Oxide. / Zhuzhel’skii, D. V.; Tolstopyatova, E. G.; Kondrat’eva, N. E.; Eliseeva, S. N.; Kondrat’ev, V. V.

In: Russian Journal of Applied Chemistry, Vol. 92, No. 7, 01.07.2019, p. 1006-1012.

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Zhuzhel’skii, D. V. ; Tolstopyatova, E. G. ; Kondrat’eva, N. E. ; Eliseeva, S. N. ; Kondrat’ev, V. V. / Effect of Electrode Material on Electrodeposition of Tungsten Oxide. In: Russian Journal of Applied Chemistry. 2019 ; Vol. 92, No. 7. pp. 1006-1012.

BibTeX

@article{6d559f83c6434469ac437c7336554e7a,
title = "Effect of Electrode Material on Electrodeposition of Tungsten Oxide",
abstract = "Influence exerted by the nature of an electrode-substrate on the electrochemical deposition of tungsten oxides from a metastable acid solution of isopolytungstate was studied. As substrates for obtaining tungsten oxide deposits served metallic electrodes made of gold and platinum, films of mixed indium-tin oxide on glass (ITO-electrodes) and also glassy carbon electrodes and glassy carbon electrodes coated with films of conducting polymers: polyaniline, polypyrrole, and poly-3,4-ethylenedioxythiophene. It was shown that the nature of a substrate noticeably affects the electrochemical properties of tungsten oxide deposits. These differences are attributed to the adsorption of hydrogen on platinum in the range of the deposition potentials of tungsten oxide and to the chemical interaction of polytungstate ions with the thiophene sulfur of the polymer.",
keywords = "electrochemical deposition, poly-3,4-ethylenedioxythiophene, polyaniline, polypyrrole, role of the electrode nature, tungsten oxide",
author = "Zhuzhel{\textquoteright}skii, {D. V.} and Tolstopyatova, {E. G.} and Kondrat{\textquoteright}eva, {N. E.} and Eliseeva, {S. N.} and Kondrat{\textquoteright}ev, {V. V.}",
note = "Funding Information: The study was financially supported by the Russian Foundation for Basic Research (grant no. 19-03-00593). Publisher Copyright: {\textcopyright} 2019, Pleiades Publishing, Ltd. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.",
year = "2019",
month = jul,
day = "1",
doi = "10.1134/S1070427219070176",
language = "English",
volume = "92",
pages = "1006--1012",
journal = "Russian Journal of Applied Chemistry",
issn = "1070-4272",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "7",

}

RIS

TY - JOUR

T1 - Effect of Electrode Material on Electrodeposition of Tungsten Oxide

AU - Zhuzhel’skii, D. V.

AU - Tolstopyatova, E. G.

AU - Kondrat’eva, N. E.

AU - Eliseeva, S. N.

AU - Kondrat’ev, V. V.

N1 - Funding Information: The study was financially supported by the Russian Foundation for Basic Research (grant no. 19-03-00593). Publisher Copyright: © 2019, Pleiades Publishing, Ltd. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.

PY - 2019/7/1

Y1 - 2019/7/1

N2 - Influence exerted by the nature of an electrode-substrate on the electrochemical deposition of tungsten oxides from a metastable acid solution of isopolytungstate was studied. As substrates for obtaining tungsten oxide deposits served metallic electrodes made of gold and platinum, films of mixed indium-tin oxide on glass (ITO-electrodes) and also glassy carbon electrodes and glassy carbon electrodes coated with films of conducting polymers: polyaniline, polypyrrole, and poly-3,4-ethylenedioxythiophene. It was shown that the nature of a substrate noticeably affects the electrochemical properties of tungsten oxide deposits. These differences are attributed to the adsorption of hydrogen on platinum in the range of the deposition potentials of tungsten oxide and to the chemical interaction of polytungstate ions with the thiophene sulfur of the polymer.

AB - Influence exerted by the nature of an electrode-substrate on the electrochemical deposition of tungsten oxides from a metastable acid solution of isopolytungstate was studied. As substrates for obtaining tungsten oxide deposits served metallic electrodes made of gold and platinum, films of mixed indium-tin oxide on glass (ITO-electrodes) and also glassy carbon electrodes and glassy carbon electrodes coated with films of conducting polymers: polyaniline, polypyrrole, and poly-3,4-ethylenedioxythiophene. It was shown that the nature of a substrate noticeably affects the electrochemical properties of tungsten oxide deposits. These differences are attributed to the adsorption of hydrogen on platinum in the range of the deposition potentials of tungsten oxide and to the chemical interaction of polytungstate ions with the thiophene sulfur of the polymer.

KW - electrochemical deposition

KW - poly-3,4-ethylenedioxythiophene

KW - polyaniline

KW - polypyrrole

KW - role of the electrode nature

KW - tungsten oxide

UR - http://www.scopus.com/inward/record.url?scp=85071308408&partnerID=8YFLogxK

U2 - 10.1134/S1070427219070176

DO - 10.1134/S1070427219070176

M3 - Article

AN - SCOPUS:85071308408

VL - 92

SP - 1006

EP - 1012

JO - Russian Journal of Applied Chemistry

JF - Russian Journal of Applied Chemistry

SN - 1070-4272

IS - 7

ER -

ID: 72836739