Research output: Contribution to journal › Article › peer-review
Effect of copper content on the structure and phase transformations in melt-spun TiNi–TiCu alloys. / Shelyakov, A. V.; Khabibullina, I. A.; Mitina, N. A.; Resnina, N. N.
In: Inorganic Materials: Applied Research, Vol. 9, No. 2, 01.01.2018, p. 279-285.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Effect of copper content on the structure and phase transformations in melt-spun TiNi–TiCu alloys
AU - Shelyakov, A. V.
AU - Khabibullina, I. A.
AU - Mitina, N. A.
AU - Resnina, N. N.
PY - 2018/1/1
Y1 - 2018/1/1
N2 - Thin ribbons 30–50 μm thick of the Ti50Ni50 –xCux (x = 25, 26, 28, 30, 32, 34; 36, 38 at %) alloys are produced by the melt-spinning technique at a cooling rate of approximately 106 K/s. It is revealed that at the content of copper 25 and 26 at % the alloys are in the amorphous-crystalline state, while at the content of copper above 26 at % the alloys are in the amorphous state. It is shown that isothermal crystallization of alloys with the copper content from 25 to 32 at % leads to formation of single-phase B2 structure, which upon cooling transforms into the martensite phase B19. A noticeable decrease in characteristic temperatures of martensitic transformation at the increase in content of copper is revealed. In the alloys with the content of copper more than 32 аt % after crystallization, the two-phase structure of B2 + B11 is formed; at the same time, the B11 phase (TiCu) substantially prevents B19 ↔ B2 transformation in the alloy with 34 at % copper and blocks all structural transformations in the alloys with 36 and 38 at % copper.
AB - Thin ribbons 30–50 μm thick of the Ti50Ni50 –xCux (x = 25, 26, 28, 30, 32, 34; 36, 38 at %) alloys are produced by the melt-spinning technique at a cooling rate of approximately 106 K/s. It is revealed that at the content of copper 25 and 26 at % the alloys are in the amorphous-crystalline state, while at the content of copper above 26 at % the alloys are in the amorphous state. It is shown that isothermal crystallization of alloys with the copper content from 25 to 32 at % leads to formation of single-phase B2 structure, which upon cooling transforms into the martensite phase B19. A noticeable decrease in characteristic temperatures of martensitic transformation at the increase in content of copper is revealed. In the alloys with the content of copper more than 32 аt % after crystallization, the two-phase structure of B2 + B11 is formed; at the same time, the B11 phase (TiCu) substantially prevents B19 ↔ B2 transformation in the alloy with 34 at % copper and blocks all structural transformations in the alloys with 36 and 38 at % copper.
KW - Amorphous state
KW - Amorphous-crystalline state
KW - Martensitic transformation
KW - Melt-spinning technique
KW - Shape memory alloys
UR - http://www.scopus.com/inward/record.url?scp=85054179943&partnerID=8YFLogxK
U2 - 10.1134/S2075113318020260
DO - 10.1134/S2075113318020260
M3 - Article
AN - SCOPUS:85054179943
VL - 9
SP - 279
EP - 285
JO - Inorganic Materials: Applied Research
JF - Inorganic Materials: Applied Research
SN - 2075-1133
IS - 2
ER -
ID: 39158644