A moderately diverse Early Devonian (Lochkovian) trilobite and brachiopod association has been recovered from the lower part of the volcano-sedimentary Shakshagaily Formation, exposed on the western side of Lake Balkhash in central Kazakhstan. Its discovery demonstrates the presence of Lower Devonian marine deposits in the region. The trilobite assemblage includes representatives of six genera: the dalmanitid Kasachstania alperovichi nov. sp. is the dominant taxon, with other components being Ananaspis?, Leonaspis?, Maurotarion, Trimerus (Edgillia), and Warburgella. Associated brachiopods include species of Glossoleptaena, Leptaena, Protolepstostrophia, Pseudostrophochonetes, and Resserella. Whilst a significant proportion of these taxa show distinct links with the contemporaneous trilobite and brachiopod faunas of the north Balkhash Region, the occurrence of Trimerus (Edgillia) aff. kinglakensis Gill, 1949 suggests a possible link with the Lochkovian trilobite fauna of the Australasian sector of Gondwana. The west Balkhash Region preserves an extensive record of late Silurian to Early Devonian island arc volcanism, slope-rise sedimentation and olistostrome formation, which has invariably been ignored in models favouring early amalgamation of the Kazakhstanian terranes into a single continent by the end of the Ordovician.