Research output: Contribution to journal › Article › peer-review
Dynamics of Guest Water Molecules in Pillared Mordenite Studied by 1H NMR Relaxation. / Шеляпина, Марина Германовна; Nefedov, Denis; Antonenko1, Anastasiia; Hmok, H’Linh; Egorov, Andrei; Egorova, Maria; Ievlev, Alexandr V; Yocupicio-Gaxiola, Rosario I.; Petranovskii, Vitalii; Antúnez-García, Joel; Fuentes, Sergio.
In: Applied Magnetic Resonance, Vol. 54, No. 10, 08.08.2023, p. 915-928.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Dynamics of Guest Water Molecules in Pillared Mordenite Studied by 1H NMR Relaxation
AU - Шеляпина, Марина Германовна
AU - Nefedov, Denis
AU - Antonenko1, Anastasiia
AU - Hmok, H’Linh
AU - Egorov, Andrei
AU - Egorova, Maria
AU - Ievlev, Alexandr V
AU - Yocupicio-Gaxiola, Rosario I.
AU - Petranovskii, Vitalii
AU - Antúnez-García, Joel
AU - Fuentes, Sergio
PY - 2023/8/8
Y1 - 2023/8/8
N2 - The dynamics of H2O molecules confined in mesopores of about 3.4 nm in size, formed by amorphous SiO2 pillars separating 2D mordenite nanolayers, was probed by 1H nuclear magnetic relaxation. 1H nuclear magnetic resonance (NMR) spectra evidence the presence of water with different local surroundings and mobility. The temperature dependence of 1H spin–lattice relaxation T 1 and relaxation in rotating frame T 1ρ indicate the complex behavior of nanoconfined water that can be characterized by different activation energies: freezing (29 kJ/mol), fast rotation (12 kJ/mol), and translational motion (23.6 kJ/mol).
AB - The dynamics of H2O molecules confined in mesopores of about 3.4 nm in size, formed by amorphous SiO2 pillars separating 2D mordenite nanolayers, was probed by 1H nuclear magnetic relaxation. 1H nuclear magnetic resonance (NMR) spectra evidence the presence of water with different local surroundings and mobility. The temperature dependence of 1H spin–lattice relaxation T 1 and relaxation in rotating frame T 1ρ indicate the complex behavior of nanoconfined water that can be characterized by different activation energies: freezing (29 kJ/mol), fast rotation (12 kJ/mol), and translational motion (23.6 kJ/mol).
KW - ЯМР
KW - цеолиты
KW - ЯМР релаксация
UR - https://www.mendeley.com/catalogue/0f76d980-31c0-313e-a859-309c577ad5fc/
U2 - 10.1007/s00723-023-01589-w
DO - 10.1007/s00723-023-01589-w
M3 - Article
VL - 54
SP - 915
EP - 928
JO - Applied Magnetic Resonance
JF - Applied Magnetic Resonance
SN - 0937-9347
IS - 10
ER -
ID: 113795615