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Dumbbell-like polyionic complexes of dendronized poly(ethylene glycol): synthesis and self-assembly studies. / Khatuntsev, Sergey ; Fanova, Anastasiia ; Fetin, Petr ; Kaberov, Leonid I. ; Girbasova, Nina ; Lezov, Alexey A. ; Zorin, Ivan ; Bilibin, Alexander .

In: Polymer Chemistry, Vol. 14, No. 6, 2023, p. 708-719.

Research output: Contribution to journal › Article › peer-review

Harvard

Khatuntsev, S, Fanova, A, Fetin, P, Kaberov, LI, Girbasova, N, Lezov, AA, Zorin, I & Bilibin, A 2023, 'Dumbbell-like polyionic complexes of dendronized poly(ethylene glycol): synthesis and self-assembly studies', Polymer Chemistry, vol. 14, no. 6, pp. 708-719. https://doi.org/10.1039/d2py01299e

APA

Khatuntsev, S., Fanova, A., Fetin, P., Kaberov, L. I., Girbasova, N., Lezov, A. A., Zorin, I., & Bilibin, A. (2023). Dumbbell-like polyionic complexes of dendronized poly(ethylene glycol): synthesis and self-assembly studies. Polymer Chemistry, 14(6), 708-719. https://doi.org/10.1039/d2py01299e

Vancouver

Khatuntsev S, Fanova A, Fetin P, Kaberov LI, Girbasova N, Lezov AA et al. Dumbbell-like polyionic complexes of dendronized poly(ethylene glycol): synthesis and self-assembly studies. Polymer Chemistry. 2023;14(6):708-719. https://doi.org/10.1039/d2py01299e

Author

Khatuntsev, Sergey ; Fanova, Anastasiia ; Fetin, Petr ; Kaberov, Leonid I. ; Girbasova, Nina ; Lezov, Alexey A. ; Zorin, Ivan ; Bilibin, Alexander . / Dumbbell-like polyionic complexes of dendronized poly(ethylene glycol): synthesis and self-assembly studies. In: Polymer Chemistry. 2023 ; Vol. 14, No. 6. pp. 708-719.

BibTeX

@article{1ec2db6ff1364a12a212515772badb36,
title = "Dumbbell-like polyionic complexes of dendronized poly(ethylene glycol): synthesis and self-assembly studies",
abstract = "Here we report on the synthesis of dumbbell-like linear–dendritic copolymers based on polyethylene glycols bearing aspartic dendrons with terminal amino and carboxylic groups. The ionic complexes of such oppositely charged copolymers demonstrate the ability to self-assemble in water and methanol and form gels in low polar solvents. Differential scanning calorimetry, polarizing optical and atomic force microscopy, and X-ray diffraction methods indicate a lamellar structure of PEG-copolymer complexes. The thickness of the layers, degree of order, and crystallinity of the PEG microphase are determined by the structure of the branched block.",
author = "Sergey Khatuntsev and Anastasiia Fanova and Petr Fetin and Kaberov, {Leonid I.} and Nina Girbasova and Lezov, {Alexey A.} and Ivan Zorin and Alexander Bilibin",
year = "2023",
doi = "10.1039/d2py01299e",
language = "English",
volume = "14",
pages = "708--719",
journal = "Polymer Chemistry",
issn = "1759-9954",
publisher = "Royal Society of Chemistry",
number = "6",

}

RIS

TY - JOUR

T1 - Dumbbell-like polyionic complexes of dendronized poly(ethylene glycol): synthesis and self-assembly studies

AU - Khatuntsev, Sergey

AU - Fanova, Anastasiia

AU - Fetin, Petr

AU - Kaberov, Leonid I.

AU - Girbasova, Nina

AU - Lezov, Alexey A.

AU - Zorin, Ivan

AU - Bilibin, Alexander

PY - 2023

Y1 - 2023

N2 - Here we report on the synthesis of dumbbell-like linear–dendritic copolymers based on polyethylene glycols bearing aspartic dendrons with terminal amino and carboxylic groups. The ionic complexes of such oppositely charged copolymers demonstrate the ability to self-assemble in water and methanol and form gels in low polar solvents. Differential scanning calorimetry, polarizing optical and atomic force microscopy, and X-ray diffraction methods indicate a lamellar structure of PEG-copolymer complexes. The thickness of the layers, degree of order, and crystallinity of the PEG microphase are determined by the structure of the branched block.

AB - Here we report on the synthesis of dumbbell-like linear–dendritic copolymers based on polyethylene glycols bearing aspartic dendrons with terminal amino and carboxylic groups. The ionic complexes of such oppositely charged copolymers demonstrate the ability to self-assemble in water and methanol and form gels in low polar solvents. Differential scanning calorimetry, polarizing optical and atomic force microscopy, and X-ray diffraction methods indicate a lamellar structure of PEG-copolymer complexes. The thickness of the layers, degree of order, and crystallinity of the PEG microphase are determined by the structure of the branched block.

UR - https://www.mendeley.com/catalogue/e3d6a86a-0a54-3592-bb47-e6191e5adc2c/

U2 - 10.1039/d2py01299e

DO - 10.1039/d2py01299e

M3 - Article

VL - 14

SP - 708

EP - 719

JO - Polymer Chemistry

JF - Polymer Chemistry

SN - 1759-9954

IS - 6

ER -

ID: 102223877