Double-doped YVO4 nanoparticles as optical dual-center ratiometric thermometers

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Double-doped YVO₄ nanoparticles as optical dual-center ratiometric thermometers. / Kolesnikov, Ilya E.; Mamonova, Daria V.; Kurochkin, Mikhail A.; Medvedev, Vassily A.; Bai, Gongxun; Ivanova, Tatiana Yu ; Borisov, Evgenii V.; Kolesnikov, Evgenii Yu.

In: Physical Chemistry Chemical Physics, Vol. 24, No. 25, 25.05.2022, p. 15349-15356.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{0022a7cfcf544f4093f332411801a612,

title = "Double-doped YVO4 nanoparticles as optical dual-center ratiometric thermometers",

abstract = "Crystalline inorganic nanoparticles doped with rare earth ions are widely used in a variety of scientific and industry applications due to the unique spectroscopic properties. The temperature dependence of their luminescence parameters makes them promising candidates for self-referencing thermal sensing. Here we report single phase YVO4 nanoparticles doped with different pairs of rare earth ions (Nd3+/Er3+, Tm3+/Er3+ and Nd3+/Tm3+) for contactless ratiometric thermometry within a wide temperature range of 298-573 K. The presence of dual luminescence centers in the optical thermometer allows one to circumvent the fundamental limitation of sensitivity inherent to thermometers based on thermally coupled levels. Important parameters for temperature sensing, such as relative thermal sensitivity and temperature resolution, were calculated for all synthesized samples and compared with the literature data. The YVO4:Tm3+,Er3+ sample displayed a relative sensitivity of 0.28% K−1 at room temperature, and the YVO4:Nd3+,Er3+ phosphor exhibited a high sensitivity of 0.56% K−1 at 573 K, while YVO4:Nd3+,Tm3+ demonstrated sub-degree thermal resolution. These findings demonstrate the good potential of dual-center ratiometric YVO4 thermometers and open the way toward future enhancement of their thermometric performances through variation of the doping concentration.",

author = "Kolesnikov, {Ilya E.} and Mamonova, {Daria V.} and Kurochkin, {Mikhail A.} and Medvedev, {Vassily A.} and Gongxun Bai and Ivanova, {Tatiana Yu} and Borisov, {Evgenii V.} and Kolesnikov, {Evgenii Yu}",

note = "Publisher Copyright: {\textcopyright} 2022 The Royal Society of Chemistry.",

year = "2022",

month = may,

day = "25",

doi = "10.1039/d2cp01543a",

language = "English",

volume = "24",

pages = "15349--15356",

journal = "Physical Chemistry Chemical Physics",

issn = "1463-9076",

publisher = "Royal Society of Chemistry",

number = "25",

}

RIS

TY - JOUR

T1 - Double-doped YVO4 nanoparticles as optical dual-center ratiometric thermometers

AU - Kolesnikov, Ilya E.

AU - Mamonova, Daria V.

AU - Kurochkin, Mikhail A.

AU - Medvedev, Vassily A.

AU - Bai, Gongxun

AU - Ivanova, Tatiana Yu

AU - Borisov, Evgenii V.

AU - Kolesnikov, Evgenii Yu

PY - 2022/5/25

Y1 - 2022/5/25

N2 - Crystalline inorganic nanoparticles doped with rare earth ions are widely used in a variety of scientific and industry applications due to the unique spectroscopic properties. The temperature dependence of their luminescence parameters makes them promising candidates for self-referencing thermal sensing. Here we report single phase YVO4 nanoparticles doped with different pairs of rare earth ions (Nd3+/Er3+, Tm3+/Er3+ and Nd3+/Tm3+) for contactless ratiometric thermometry within a wide temperature range of 298-573 K. The presence of dual luminescence centers in the optical thermometer allows one to circumvent the fundamental limitation of sensitivity inherent to thermometers based on thermally coupled levels. Important parameters for temperature sensing, such as relative thermal sensitivity and temperature resolution, were calculated for all synthesized samples and compared with the literature data. The YVO4:Tm3+,Er3+ sample displayed a relative sensitivity of 0.28% K−1 at room temperature, and the YVO4:Nd3+,Er3+ phosphor exhibited a high sensitivity of 0.56% K−1 at 573 K, while YVO4:Nd3+,Tm3+ demonstrated sub-degree thermal resolution. These findings demonstrate the good potential of dual-center ratiometric YVO4 thermometers and open the way toward future enhancement of their thermometric performances through variation of the doping concentration.

AB - Crystalline inorganic nanoparticles doped with rare earth ions are widely used in a variety of scientific and industry applications due to the unique spectroscopic properties. The temperature dependence of their luminescence parameters makes them promising candidates for self-referencing thermal sensing. Here we report single phase YVO4 nanoparticles doped with different pairs of rare earth ions (Nd3+/Er3+, Tm3+/Er3+ and Nd3+/Tm3+) for contactless ratiometric thermometry within a wide temperature range of 298-573 K. The presence of dual luminescence centers in the optical thermometer allows one to circumvent the fundamental limitation of sensitivity inherent to thermometers based on thermally coupled levels. Important parameters for temperature sensing, such as relative thermal sensitivity and temperature resolution, were calculated for all synthesized samples and compared with the literature data. The YVO4:Tm3+,Er3+ sample displayed a relative sensitivity of 0.28% K−1 at room temperature, and the YVO4:Nd3+,Er3+ phosphor exhibited a high sensitivity of 0.56% K−1 at 573 K, while YVO4:Nd3+,Tm3+ demonstrated sub-degree thermal resolution. These findings demonstrate the good potential of dual-center ratiometric YVO4 thermometers and open the way toward future enhancement of their thermometric performances through variation of the doping concentration.

UR - http://www.scopus.com/inward/record.url?scp=85132213901&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/4ec78242-764f-3a5d-80f5-b59da11294ad/

U2 - 10.1039/d2cp01543a

DO - 10.1039/d2cp01543a

M3 - Article

C2 - 35703368

AN - SCOPUS:85132213901

VL - 24

SP - 15349

EP - 15356

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

SN - 1463-9076

IS - 25

ER -

ID: 98303888