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Donor-acceptor "dressing" of "naked" group 13-15 cubanes. / Timoshkin, Alexey Y.

In: Inorganic Chemistry, Vol. 48, No. 17, 07.09.2009, p. 8145-8153.

Research output: Contribution to journal › Article › peer-review

Harvard

Timoshkin, AY 2009, 'Donor-acceptor "dressing" of "naked" group 13-15 cubanes', Inorganic Chemistry, vol. 48, no. 17, pp. 8145-8153. https://doi.org/10.1021/ic900270c

APA

Timoshkin, A. Y. (2009). Donor-acceptor "dressing" of "naked" group 13-15 cubanes. Inorganic Chemistry, 48(17), 8145-8153. https://doi.org/10.1021/ic900270c

Vancouver

Timoshkin AY. Donor-acceptor "dressing" of "naked" group 13-15 cubanes. Inorganic Chemistry. 2009 Sep 7;48(17):8145-8153. https://doi.org/10.1021/ic900270c

Author

Timoshkin, Alexey Y. / Donor-acceptor "dressing" of "naked" group 13-15 cubanes. In: Inorganic Chemistry. 2009 ; Vol. 48, No. 17. pp. 8145-8153.

BibTeX

@article{16d40165c9674f1999ac66e8500ae945,
title = "Donor-acceptor {"}dressing{"} of {"}naked{"} group 13-15 cubanes",
abstract = "The structures and stability of the group 13-15 inorganic cubane clusters, stabilized by donor-acceptor interactions, are theoretically explored at the B3LYP/TZVP level of theory. [DMYA]4 compounds (M, Y = group 13 and 15 elements; D, A = donor and acceptor molecules NH3 and BH 3, respectively) are predicted to be true minima on the potential energy surface. It is shown that donor-acceptor {"}dressing{"} significantly stabilizes {"}naked{"} [MY]4 cubanes. Possible synthetic approaches and potential uses of these novel [DMYA]4 compounds as single-source precursors to group 13-15 materials are discussed.",
author = "Timoshkin, {Alexey Y.}",
year = "2009",
month = sep,
day = "7",
doi = "10.1021/ic900270c",
language = "English",
volume = "48",
pages = "8145--8153",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "17",

}

RIS

TY - JOUR

T1 - Donor-acceptor "dressing" of "naked" group 13-15 cubanes

AU - Timoshkin, Alexey Y.

PY - 2009/9/7

Y1 - 2009/9/7

N2 - The structures and stability of the group 13-15 inorganic cubane clusters, stabilized by donor-acceptor interactions, are theoretically explored at the B3LYP/TZVP level of theory. [DMYA]4 compounds (M, Y = group 13 and 15 elements; D, A = donor and acceptor molecules NH3 and BH 3, respectively) are predicted to be true minima on the potential energy surface. It is shown that donor-acceptor "dressing" significantly stabilizes "naked" [MY]4 cubanes. Possible synthetic approaches and potential uses of these novel [DMYA]4 compounds as single-source precursors to group 13-15 materials are discussed.

AB - The structures and stability of the group 13-15 inorganic cubane clusters, stabilized by donor-acceptor interactions, are theoretically explored at the B3LYP/TZVP level of theory. [DMYA]4 compounds (M, Y = group 13 and 15 elements; D, A = donor and acceptor molecules NH3 and BH 3, respectively) are predicted to be true minima on the potential energy surface. It is shown that donor-acceptor "dressing" significantly stabilizes "naked" [MY]4 cubanes. Possible synthetic approaches and potential uses of these novel [DMYA]4 compounds as single-source precursors to group 13-15 materials are discussed.

UR - http://www.scopus.com/inward/record.url?scp=69549088757&partnerID=8YFLogxK

U2 - 10.1021/ic900270c

DO - 10.1021/ic900270c

M3 - Article

AN - SCOPUS:69549088757

VL - 48

SP - 8145

EP - 8153

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 17

ER -

ID: 17372026