Standard

Domino Cyclization Reaction of o-Diisocyanoarenes for the Synthesis of Imidazo[1,2-a]pyridinobenzimidazole Backbones. / Дарьин, Дмитрий Викторович; Красавин, Михаил Юрьевич; Balalaie, Saeed; Rezaei-Gohar, Mohammad; Rominger, Frank .

In: Organic Letters, Vol. 25, No. 30, 24.07.2023, p. 5682-5686.

Research output: Contribution to journal › Article › peer-review

Harvard

Дарьин, ДВ, Красавин, МЮ, Balalaie, S, Rezaei-Gohar, M & Rominger, F 2023, 'Domino Cyclization Reaction of o-Diisocyanoarenes for the Synthesis of Imidazo[1,2-a]pyridinobenzimidazole Backbones', Organic Letters, vol. 25, no. 30, pp. 5682-5686. https://doi.org/10.1021/acs.orglett.3c02137

APA

Дарьин, Д. В., Красавин, М. Ю., Balalaie, S., Rezaei-Gohar, M., & Rominger, F. (2023). Domino Cyclization Reaction of o-Diisocyanoarenes for the Synthesis of Imidazo[1,2-a]pyridinobenzimidazole Backbones. Organic Letters, 25(30), 5682-5686. https://doi.org/10.1021/acs.orglett.3c02137

Vancouver

Дарьин ДВ, Красавин МЮ, Balalaie S, Rezaei-Gohar M, Rominger F. Domino Cyclization Reaction of o-Diisocyanoarenes for the Synthesis of Imidazo[1,2-a]pyridinobenzimidazole Backbones. Organic Letters. 2023 Jul 24;25(30):5682-5686. https://doi.org/10.1021/acs.orglett.3c02137

Author

Дарьин, Дмитрий Викторович ; Красавин, Михаил Юрьевич ; Balalaie, Saeed ; Rezaei-Gohar, Mohammad ; Rominger, Frank . / Domino Cyclization Reaction of o-Diisocyanoarenes for the Synthesis of Imidazo[1,2-a]pyridinobenzimidazole Backbones. In: Organic Letters. 2023 ; Vol. 25, No. 30. pp. 5682-5686.

BibTeX

@article{5e8c0185b4444650a8cd02af0c474998,
title = "Domino Cyclization Reaction of o-Diisocyanoarenes for the Synthesis of Imidazo[1,2-a]pyridinobenzimidazole Backbones",
abstract = "An efficient procedure to access a variety of connected imidazo[1,2-a]pyridine and benzimidazole skeletons through the C-N bond was described as a new type of Buchwald-Hartwig reaction. Furthermore, the bis(imidazo[1,2-a]pyridin-3-yl)aryl-1,2-diamine scaffolds were obtained by changing the equivalent ratio of the starting materials. Some advantages of the protocol are the formation of four new bonds (C═C, C-N), a transition-metal-free reaction, a broad substrate scope, high yields, and mild reaction conditions. The reaction mechanism was confirmed on the basis of DFT calculations.",
author = "Дарьин, {Дмитрий Викторович} and Красавин, {Михаил Юрьевич} and Saeed Balalaie and Mohammad Rezaei-Gohar and Frank Rominger",
year = "2023",
month = jul,
day = "24",
doi = "10.1021/acs.orglett.3c02137",
language = "English",
volume = "25",
pages = "5682--5686",
journal = "Organic Letters",
issn = "1523-7060",
publisher = "American Chemical Society",
number = "30",

}

RIS

TY - JOUR

T1 - Domino Cyclization Reaction of o-Diisocyanoarenes for the Synthesis of Imidazo[1,2-a]pyridinobenzimidazole Backbones

AU - Дарьин, Дмитрий Викторович

AU - Красавин, Михаил Юрьевич

AU - Balalaie, Saeed

AU - Rezaei-Gohar, Mohammad

AU - Rominger, Frank

PY - 2023/7/24

Y1 - 2023/7/24

N2 - An efficient procedure to access a variety of connected imidazo[1,2-a]pyridine and benzimidazole skeletons through the C-N bond was described as a new type of Buchwald-Hartwig reaction. Furthermore, the bis(imidazo[1,2-a]pyridin-3-yl)aryl-1,2-diamine scaffolds were obtained by changing the equivalent ratio of the starting materials. Some advantages of the protocol are the formation of four new bonds (C═C, C-N), a transition-metal-free reaction, a broad substrate scope, high yields, and mild reaction conditions. The reaction mechanism was confirmed on the basis of DFT calculations.

AB - An efficient procedure to access a variety of connected imidazo[1,2-a]pyridine and benzimidazole skeletons through the C-N bond was described as a new type of Buchwald-Hartwig reaction. Furthermore, the bis(imidazo[1,2-a]pyridin-3-yl)aryl-1,2-diamine scaffolds were obtained by changing the equivalent ratio of the starting materials. Some advantages of the protocol are the formation of four new bonds (C═C, C-N), a transition-metal-free reaction, a broad substrate scope, high yields, and mild reaction conditions. The reaction mechanism was confirmed on the basis of DFT calculations.

UR - https://www.mendeley.com/catalogue/bf92781b-5ac9-39b9-9bfa-56c400225e99/

U2 - 10.1021/acs.orglett.3c02137

DO - 10.1021/acs.orglett.3c02137

M3 - Article

VL - 25

SP - 5682

EP - 5686

JO - Organic Letters

JF - Organic Letters

SN - 1523-7060

IS - 30

ER -

ID: 113685656