Research output: Contribution to journal › Article › peer-review
Diode-Laser Measurements of He-Broadening Coefficients in the v6 Band of 12CH3F. / Grigoriev, Ivan M.; Bouanich, Jean Pierre; Blanquet, Ghislain; Walrand, Jacques; Lepère, Muriel.
In: Journal of Molecular Spectroscopy, Vol. 186, No. 1, 01.01.1997, p. 48-53.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Diode-Laser Measurements of He-Broadening Coefficients in the v6 Band of 12CH3F
AU - Grigoriev, Ivan M.
AU - Bouanich, Jean Pierre
AU - Blanquet, Ghislain
AU - Walrand, Jacques
AU - Lepère, Muriel
PY - 1997/1/1
Y1 - 1997/1/1
N2 - He-broadening coefficients are measured for 28 lines of 12CH3F in the RQO (Ki = 0, ΔK = 1, ΔJ = 0) and RQ6 (Ki = 6, ΔK = 1, ΔJ = 0) branches of the v6 band, using a tunable diode laser spectrometer. The collisional widths obtained by fitting Rautian profiles to the measured shapes of the lines are slightly larger than those derived from Voigt profiles. The broadening coefficients for the lines belonging to the same low J transitions are significantly greater in the RQ0 branch than in the RQ6 branch. Moreover, they decrease on the whole with increasing J in the RQ0 branch and tend to increase from J varying from 7 to 10 in the RQ6 branch. These trends may be approximately reproduced by calculations based on a semiclassical impact theory of collisional broadening.
AB - He-broadening coefficients are measured for 28 lines of 12CH3F in the RQO (Ki = 0, ΔK = 1, ΔJ = 0) and RQ6 (Ki = 6, ΔK = 1, ΔJ = 0) branches of the v6 band, using a tunable diode laser spectrometer. The collisional widths obtained by fitting Rautian profiles to the measured shapes of the lines are slightly larger than those derived from Voigt profiles. The broadening coefficients for the lines belonging to the same low J transitions are significantly greater in the RQ0 branch than in the RQ6 branch. Moreover, they decrease on the whole with increasing J in the RQ0 branch and tend to increase from J varying from 7 to 10 in the RQ6 branch. These trends may be approximately reproduced by calculations based on a semiclassical impact theory of collisional broadening.
UR - http://www.scopus.com/inward/record.url?scp=0009067377&partnerID=8YFLogxK
U2 - 10.1006/jmsp.1997.7415
DO - 10.1006/jmsp.1997.7415
M3 - Article
AN - SCOPUS:0009067377
VL - 186
SP - 48
EP - 53
JO - Journal of Molecular Spectroscopy
JF - Journal of Molecular Spectroscopy
SN - 0022-2852
IS - 1
ER -
ID: 35918217