Dimerization of Phthalate Ion in Non-Aqueous Solvents

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Dimerization of Phthalate Ion in Non-Aqueous Solvents. / Nosov, V. G.; Podryadrova, K. A.; Vasilyeva, M. S.; Bogachev, N. A.; Skripkin, M. Yu ; Mereshchenko, A. S.

In: Russian Journal of General Chemistry, Vol. 91, No. 5, 01.05.2021, p. 753-757.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{034aa801a1514f42a98fb9372da2de30,

title = "Dimerization of Phthalate Ion in Non-Aqueous Solvents",

abstract = "Abstract: Solutions of tetraethylammonium phthalate in non-aqueous solvents (ethanol,dimethylsulfoxide, dimethylformamide, and acetonitrile) were studied byelectronic absorption spectroscopy. It was shown that the phthalate aniondimerizes in acetonitrile and dimethylformamide solutions due to π-stacking, theexperimental equilibrium constants being 550±50 and 900±50, respectively.Dimerization of the phthalate anion was not observed in ethanol anddimethylsulfoxide solutions.",

keywords = "dimerization constant, electronic spectroscopy, tetraethylammonium phthalate, π-stacking, pi-stacking, LIGAND",

author = "Nosov, {V. G.} and Podryadrova, {K. A.} and Vasilyeva, {M. S.} and Bogachev, {N. A.} and Skripkin, {M. Yu} and Mereshchenko, {A. S.}",

year = "2021",

month = may,

day = "1",

doi = "10.1134/s1070363221050017",

language = "English",

volume = "91",

pages = "753--757",

journal = "Russian Journal of General Chemistry",

issn = "1070-3632",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "5",

}

RIS

TY - JOUR

T1 - Dimerization of Phthalate Ion in Non-Aqueous Solvents

AU - Nosov, V. G.

AU - Podryadrova, K. A.

AU - Vasilyeva, M. S.

AU - Bogachev, N. A.

AU - Skripkin, M. Yu

AU - Mereshchenko, A. S.

PY - 2021/5/1

Y1 - 2021/5/1

N2 - Abstract: Solutions of tetraethylammonium phthalate in non-aqueous solvents (ethanol,dimethylsulfoxide, dimethylformamide, and acetonitrile) were studied byelectronic absorption spectroscopy. It was shown that the phthalate aniondimerizes in acetonitrile and dimethylformamide solutions due to π-stacking, theexperimental equilibrium constants being 550±50 and 900±50, respectively.Dimerization of the phthalate anion was not observed in ethanol anddimethylsulfoxide solutions.

AB - Abstract: Solutions of tetraethylammonium phthalate in non-aqueous solvents (ethanol,dimethylsulfoxide, dimethylformamide, and acetonitrile) were studied byelectronic absorption spectroscopy. It was shown that the phthalate aniondimerizes in acetonitrile and dimethylformamide solutions due to π-stacking, theexperimental equilibrium constants being 550±50 and 900±50, respectively.Dimerization of the phthalate anion was not observed in ethanol anddimethylsulfoxide solutions.

KW - dimerization constant

KW - electronic spectroscopy

KW - tetraethylammonium phthalate

KW - π-stacking

KW - pi-stacking

KW - LIGAND

UR - http://www.scopus.com/inward/record.url?scp=85108350764&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/8d0701ef-80f9-3244-a6dd-66b424aecec1/

U2 - 10.1134/s1070363221050017

DO - 10.1134/s1070363221050017

M3 - Article

AN - SCOPUS:85108350764

VL - 91

SP - 753

EP - 757

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 5

ER -

ID: 78244629