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Dimensionality Mediated Highly Repeatable and Fast Transformation of Coordination Polymer Single Crystals for All-Optical Data Processing. / Kulachenkov, Nikita; Barsukova, Marina; Alekseevskiy, Pavel; Sapianik, Aleksandr A.; Sergeev, Maxim; Yankin, Andrei; Krasilin, Andrei A.; Bachinin, Semyon; Shipilovskikh, Sergei; Poturaev, Petr; Medvedeva, Natalia; Denislamova, Ekaterina; Zelenovskiy, Pavel S.; Shilovskikh, Vladimir V.; Kenzhebayeva, Yuliya; Efimova, Anastasiia; Novikov, Alexander S.; Lunev, Artem; Fedin, Vladimir P.; Milichko, Valentin A.

In: Nano Letters, Vol. 22, No. 17, 14.09.2022, p. 6972–6981.

Research output: Contribution to journal › Article › peer-review

Harvard

Kulachenkov, N, Barsukova, M, Alekseevskiy, P, Sapianik, AA, Sergeev, M, Yankin, A, Krasilin, AA, Bachinin, S, Shipilovskikh, S, Poturaev, P, Medvedeva, N, Denislamova, E, Zelenovskiy, PS, Shilovskikh, VV, Kenzhebayeva, Y, Efimova, A, Novikov, AS, Lunev, A, Fedin, VP & Milichko, VA 2022, 'Dimensionality Mediated Highly Repeatable and Fast Transformation of Coordination Polymer Single Crystals for All-Optical Data Processing', Nano Letters, vol. 22, no. 17, pp. 6972–6981. https://doi.org/10.1021/acs.nanolett.2c01770

APA

Kulachenkov, N., Barsukova, M., Alekseevskiy, P., Sapianik, A. A., Sergeev, M., Yankin, A., Krasilin, A. A., Bachinin, S., Shipilovskikh, S., Poturaev, P., Medvedeva, N., Denislamova, E., Zelenovskiy, P. S., Shilovskikh, V. V., Kenzhebayeva, Y., Efimova, A., Novikov, A. S., Lunev, A., Fedin, V. P., & Milichko, V. A. (2022). Dimensionality Mediated Highly Repeatable and Fast Transformation of Coordination Polymer Single Crystals for All-Optical Data Processing. Nano Letters, 22(17), 6972–6981. https://doi.org/10.1021/acs.nanolett.2c01770

Vancouver

Kulachenkov N, Barsukova M, Alekseevskiy P, Sapianik AA, Sergeev M, Yankin A et al. Dimensionality Mediated Highly Repeatable and Fast Transformation of Coordination Polymer Single Crystals for All-Optical Data Processing. Nano Letters. 2022 Sep 14;22(17):6972–6981. https://doi.org/10.1021/acs.nanolett.2c01770

Author

Kulachenkov, Nikita ; Barsukova, Marina ; Alekseevskiy, Pavel ; Sapianik, Aleksandr A. ; Sergeev, Maxim ; Yankin, Andrei ; Krasilin, Andrei A. ; Bachinin, Semyon ; Shipilovskikh, Sergei ; Poturaev, Petr ; Medvedeva, Natalia ; Denislamova, Ekaterina ; Zelenovskiy, Pavel S. ; Shilovskikh, Vladimir V. ; Kenzhebayeva, Yuliya ; Efimova, Anastasiia ; Novikov, Alexander S. ; Lunev, Artem ; Fedin, Vladimir P. ; Milichko, Valentin A. / Dimensionality Mediated Highly Repeatable and Fast Transformation of Coordination Polymer Single Crystals for All-Optical Data Processing. In: Nano Letters. 2022 ; Vol. 22, No. 17. pp. 6972–6981.

BibTeX

@article{1e7011dc6935474b92b49ffd571a21ce,
title = "Dimensionality Mediated Highly Repeatable and Fast Transformation of Coordination Polymer Single Crystals for All-Optical Data Processing",
abstract = "A family of coordination polymers (CPs) based on dynamic structural elements are of great fundamental and commercial interest addressing modern problems in controlled molecular separation, catalysis, and even data processing. Herein, the endurance and fast structural dynamics of such materials at ambient conditions are still a fundamental challenge. Here, we report on the design of a series of Cu-based CPs [Cu(bImB)Cl2] and [Cu(bImB)2Cl2] with flexible ligand bImB (1,4-bis(imidazol-1-yl)butane) packed into one- and two-dimensional (1D, 2D) structures demonstrating dimensionality mediated flexibility and reversible structural transformations. Using the laser pulses as a fast source of activation energy, we initiate CP heating followed by anisotropic thermal expansion and 0.2-0.8% volume changes with the record transformation rates from 2220 to 1640 s-1 for 1D and 2D CPs, respectively. The endurance over 103 cycles of structural transformations, achieved for the CPs at ambient conditions, allows demonstrating optical fiber integrated all-optical data processing.",
keywords = "Coordination polymers, data processing, flexibility, in situ spectroscopy, low-dimensional structures, structural transformation",
author = "Nikita Kulachenkov and Marina Barsukova and Pavel Alekseevskiy and Sapianik, {Aleksandr A.} and Maxim Sergeev and Andrei Yankin and Krasilin, {Andrei A.} and Semyon Bachinin and Sergei Shipilovskikh and Petr Poturaev and Natalia Medvedeva and Ekaterina Denislamova and Zelenovskiy, {Pavel S.} and Shilovskikh, {Vladimir V.} and Yuliya Kenzhebayeva and Anastasiia Efimova and Novikov, {Alexander S.} and Artem Lunev and Fedin, {Vladimir P.} and Milichko, {Valentin A.}",
note = "Publisher Copyright: {\textcopyright} XXXX The Authors. Published by American Chemical Society.",
year = "2022",
month = sep,
day = "14",
doi = "10.1021/acs.nanolett.2c01770",
language = "English",
volume = "22",
pages = "6972–6981",
journal = "Nano Letters",
issn = "1530-6984",
publisher = "American Chemical Society",
number = "17",

}

RIS

TY - JOUR

T1 - Dimensionality Mediated Highly Repeatable and Fast Transformation of Coordination Polymer Single Crystals for All-Optical Data Processing

AU - Kulachenkov, Nikita

AU - Barsukova, Marina

AU - Alekseevskiy, Pavel

AU - Sapianik, Aleksandr A.

AU - Sergeev, Maxim

AU - Yankin, Andrei

AU - Krasilin, Andrei A.

AU - Bachinin, Semyon

AU - Shipilovskikh, Sergei

AU - Poturaev, Petr

AU - Medvedeva, Natalia

AU - Denislamova, Ekaterina

AU - Zelenovskiy, Pavel S.

AU - Shilovskikh, Vladimir V.

AU - Kenzhebayeva, Yuliya

AU - Efimova, Anastasiia

AU - Novikov, Alexander S.

AU - Lunev, Artem

AU - Fedin, Vladimir P.

AU - Milichko, Valentin A.

N1 - Publisher Copyright: © XXXX The Authors. Published by American Chemical Society.

PY - 2022/9/14

Y1 - 2022/9/14

N2 - A family of coordination polymers (CPs) based on dynamic structural elements are of great fundamental and commercial interest addressing modern problems in controlled molecular separation, catalysis, and even data processing. Herein, the endurance and fast structural dynamics of such materials at ambient conditions are still a fundamental challenge. Here, we report on the design of a series of Cu-based CPs [Cu(bImB)Cl2] and [Cu(bImB)2Cl2] with flexible ligand bImB (1,4-bis(imidazol-1-yl)butane) packed into one- and two-dimensional (1D, 2D) structures demonstrating dimensionality mediated flexibility and reversible structural transformations. Using the laser pulses as a fast source of activation energy, we initiate CP heating followed by anisotropic thermal expansion and 0.2-0.8% volume changes with the record transformation rates from 2220 to 1640 s-1 for 1D and 2D CPs, respectively. The endurance over 103 cycles of structural transformations, achieved for the CPs at ambient conditions, allows demonstrating optical fiber integrated all-optical data processing.

AB - A family of coordination polymers (CPs) based on dynamic structural elements are of great fundamental and commercial interest addressing modern problems in controlled molecular separation, catalysis, and even data processing. Herein, the endurance and fast structural dynamics of such materials at ambient conditions are still a fundamental challenge. Here, we report on the design of a series of Cu-based CPs [Cu(bImB)Cl2] and [Cu(bImB)2Cl2] with flexible ligand bImB (1,4-bis(imidazol-1-yl)butane) packed into one- and two-dimensional (1D, 2D) structures demonstrating dimensionality mediated flexibility and reversible structural transformations. Using the laser pulses as a fast source of activation energy, we initiate CP heating followed by anisotropic thermal expansion and 0.2-0.8% volume changes with the record transformation rates from 2220 to 1640 s-1 for 1D and 2D CPs, respectively. The endurance over 103 cycles of structural transformations, achieved for the CPs at ambient conditions, allows demonstrating optical fiber integrated all-optical data processing.

KW - Coordination polymers

KW - data processing

KW - flexibility

KW - in situ spectroscopy

KW - low-dimensional structures

KW - structural transformation

UR - http://www.scopus.com/inward/record.url?scp=85137291257&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/1f7776f0-c6bb-35ac-a0bf-9eb37d29ec62/

U2 - 10.1021/acs.nanolett.2c01770

DO - 10.1021/acs.nanolett.2c01770

M3 - Article

AN - SCOPUS:85137291257

VL - 22

SP - 6972

EP - 6981

JO - Nano Letters

JF - Nano Letters

SN - 1530-6984

IS - 17

ER -

ID: 98879193