Research output: Contribution to journal › Article › peer-review
Dielectric properties and phase transition in the PbSe + PbSeO3 composite material. / Tomaev, V. V.; Miroshkin, V. P.; Gar'kin, L. N.; Tikhonov, P. A.
In: Glass Physics and Chemistry, Vol. 31, No. 6, 11.2005, p. 812-819.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Dielectric properties and phase transition in the PbSe + PbSeO3 composite material
AU - Tomaev, V. V.
AU - Miroshkin, V. P.
AU - Gar'kin, L. N.
AU - Tikhonov, P. A.
N1 - Copyright: Copyright 2008 Elsevier B.V., All rights reserved.
PY - 2005/11
Y1 - 2005/11
N2 - Electrochemical cells in the form of pressed pellets and polycrystalline films prepared from the PbSe + PbSeO3 two-phase composite are investigated by impedance spectroscopy. The dispersion analysis of the frequencies of the real and imaginary parts of the complex impedance made it possible to reveal a unified equivalent electric circuit for these cells and to calculate its parameters. The optical (εhf) and static (εlf) permittivities of the PbSe and PbSeO3 phases are determined. The permittivities εhf = 20-45 and εlf = 200-280 obtained for the PbSe phase are in reasonable agreement with the data available in the literature. The temperature dependences of the ac and dc resistances indicate that the PbSe + PbSeO3 composite undergoes a phase transition at a temperature T c ≅ 363 K.
AB - Electrochemical cells in the form of pressed pellets and polycrystalline films prepared from the PbSe + PbSeO3 two-phase composite are investigated by impedance spectroscopy. The dispersion analysis of the frequencies of the real and imaginary parts of the complex impedance made it possible to reveal a unified equivalent electric circuit for these cells and to calculate its parameters. The optical (εhf) and static (εlf) permittivities of the PbSe and PbSeO3 phases are determined. The permittivities εhf = 20-45 and εlf = 200-280 obtained for the PbSe phase are in reasonable agreement with the data available in the literature. The temperature dependences of the ac and dc resistances indicate that the PbSe + PbSeO3 composite undergoes a phase transition at a temperature T c ≅ 363 K.
UR - http://www.scopus.com/inward/record.url?scp=29344468479&partnerID=8YFLogxK
U2 - 10.1007/s10720-005-0130-9
DO - 10.1007/s10720-005-0130-9
M3 - Article
VL - 31
SP - 812
EP - 819
JO - Glass Physics and Chemistry
JF - Glass Physics and Chemistry
SN - 1087-6596
IS - 6
ER -
ID: 5127162