TY - JOUR

T1 - Development and Study of Novel Ultrafiltration Membranes Based on Cellulose Acetate

AU - Кузьминова, Анна Игоревна

AU - Дмитренко, Мария Евгеньевна

AU - Дубовенко, Роман Русланович

AU - Пузикова, Маргарита Егоровна

AU - Микулан, Анна Ярославовна

AU - Коровина, Александра

AU - Королева, Александра Владимировна

AU - Селютин, Артем Александрович

AU - Семёнов, Константин Николаевич

AU - Su, Rongxin

AU - Пенькова, Анастасия Владимировна

PY - 2024/4/28

Y1 - 2024/4/28

N2 - Recently, increasing attention of researchers in the field of membrane technology has been paid to the development of membranes based on biopolymers. One of the well-proven polymers for the development of porous membranes is cellulose acetate (CA). This paper is devoted to the study of the influence of different parameters on ultrafiltration CA membrane formation and their transport properties, such as the variation in coagulation bath temperature, membrane shrinkage (post-treatment at 80 °C), introduction to casting CA solution of polymers (polyethylene glycol (PEG), polysulfone (PS), and Pluronic F127 (PL)) and carbon nanoparticles (SWCNTs, MWCNTs, GO, and C 60). The structural and physicochemical properties of developed membranes were studied by scanning electron and atomic force microscopies, Fourier-transform infrared spectroscopy, X-ray photoelectron spectroscopy, and contact angle measurements. The transport properties of developed CA-based membranes were evaluated in ultrafiltration of bovine serum albumin (BSA), dextran 110 and PVP K-90. All developed membranes rejected 90% compounds with a molecular weight from ~270,000 g/mol. It was shown that the combination of modifications (addition of PEG, PS, PL, PS-PL, and 0.5 wt% C 60) led to an increase in the fluxes and BSA rejection coefficients with slight decrease in the flux recovery ratio. These changes were due to an increased macrovoid number, formation of a more open porous structure and/or thinner top selective, and decreased surface roughness and hydrophobization during C 60 modification of blend membranes. Optimal transport properties were found for CA-PEG+C 60 (the highest water-394 L/(m 2h) and BSA-212 L/(m 2h) fluxes) and CA-PS+C 60 (maximal rejection coefficient of BSA-59%) membranes.

AB - Recently, increasing attention of researchers in the field of membrane technology has been paid to the development of membranes based on biopolymers. One of the well-proven polymers for the development of porous membranes is cellulose acetate (CA). This paper is devoted to the study of the influence of different parameters on ultrafiltration CA membrane formation and their transport properties, such as the variation in coagulation bath temperature, membrane shrinkage (post-treatment at 80 °C), introduction to casting CA solution of polymers (polyethylene glycol (PEG), polysulfone (PS), and Pluronic F127 (PL)) and carbon nanoparticles (SWCNTs, MWCNTs, GO, and C 60). The structural and physicochemical properties of developed membranes were studied by scanning electron and atomic force microscopies, Fourier-transform infrared spectroscopy, X-ray photoelectron spectroscopy, and contact angle measurements. The transport properties of developed CA-based membranes were evaluated in ultrafiltration of bovine serum albumin (BSA), dextran 110 and PVP K-90. All developed membranes rejected 90% compounds with a molecular weight from ~270,000 g/mol. It was shown that the combination of modifications (addition of PEG, PS, PL, PS-PL, and 0.5 wt% C 60) led to an increase in the fluxes and BSA rejection coefficients with slight decrease in the flux recovery ratio. These changes were due to an increased macrovoid number, formation of a more open porous structure and/or thinner top selective, and decreased surface roughness and hydrophobization during C 60 modification of blend membranes. Optimal transport properties were found for CA-PEG+C 60 (the highest water-394 L/(m 2h) and BSA-212 L/(m 2h) fluxes) and CA-PS+C 60 (maximal rejection coefficient of BSA-59%) membranes.

KW - cellulose acetate

KW - carbon nanoparticles

KW - ultrafiltration

KW - post-treatment

KW - carbon nanoparticles

KW - cellulose acetate

KW - post-treatment

KW - ultrafiltration

UR - https://www.mendeley.com/catalogue/51ae3404-d2c7-3d80-a906-92a74d3d6b7d/

U2 - 10.3390/polym16091236

DO - 10.3390/polym16091236

M3 - Article

C2 - 38732705

VL - 16

JO - Polymers

JF - Polymers

SN - 2073-4360

IS - 9

M1 - 1236

ER -