Determination of interfacial parameters of a soluble particle in a nonideal solution from measured deliquescence and efﬂorescence humidities

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Determination of interfacial parameters of a soluble particle in a nonideal solution from measured deliquescence and efﬂorescence humidities. / Hellmuth, O.; Shchekin, A. K.

In: Atmospheric Chemistry and Physics, Vol. 15, 2015, p. 3851–3871.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{098e6852a01f4b108501b2818afe0677,

title = "Determination of interfacial parameters of a soluble particle in a nonideal solution from measured deliquescence and efﬂorescence humidities",

abstract = "In order to study the growth/shrinking of a hygroscopic nanoparticle during hydration/dehydration in an atmosphere of water vapour, we have employed a thermodynamic approach proposed by Shchekin et al. (2008). This approach uses the mechanic and thermodynamic concept of disjoining pressure of thin ﬁlms and allows, among others, the prediction of the humidity growth factor of both (i) a homogeneous solution droplet with completely dissolved residual core and (ii) a heterogeneous solution droplet with partially dissolved residual core as a function of the ambient relative humidity. For application to a nanometric sodium chloride particle we have extended the original approach by (i) considering the nonideality of the solution through the dependence of molecular volumes of the solvent and solute molecules and the solute and solvent activities on the solution concentration, (ii) deriving an equation for the estimation of the efﬂorescence properties of a homogeneous solution droplet, and (iii) combining the empiri",

author = "O. Hellmuth and Shchekin, {A. K.}",

year = "2015",

doi = "10.5194/acp-15-3851-2015",

language = "English",

volume = "15",

pages = "3851–3871",

journal = "Atmospheric Chemistry and Physics",

issn = "1680-7316",

publisher = "Copernicus GmbH ",

}

RIS

TY - JOUR

T1 - Determination of interfacial parameters of a soluble particle in a nonideal solution from measured deliquescence and efﬂorescence humidities

AU - Hellmuth, O.

AU - Shchekin, A. K.

PY - 2015

Y1 - 2015

N2 - In order to study the growth/shrinking of a hygroscopic nanoparticle during hydration/dehydration in an atmosphere of water vapour, we have employed a thermodynamic approach proposed by Shchekin et al. (2008). This approach uses the mechanic and thermodynamic concept of disjoining pressure of thin ﬁlms and allows, among others, the prediction of the humidity growth factor of both (i) a homogeneous solution droplet with completely dissolved residual core and (ii) a heterogeneous solution droplet with partially dissolved residual core as a function of the ambient relative humidity. For application to a nanometric sodium chloride particle we have extended the original approach by (i) considering the nonideality of the solution through the dependence of molecular volumes of the solvent and solute molecules and the solute and solvent activities on the solution concentration, (ii) deriving an equation for the estimation of the efﬂorescence properties of a homogeneous solution droplet, and (iii) combining the empiri

AB - In order to study the growth/shrinking of a hygroscopic nanoparticle during hydration/dehydration in an atmosphere of water vapour, we have employed a thermodynamic approach proposed by Shchekin et al. (2008). This approach uses the mechanic and thermodynamic concept of disjoining pressure of thin ﬁlms and allows, among others, the prediction of the humidity growth factor of both (i) a homogeneous solution droplet with completely dissolved residual core and (ii) a heterogeneous solution droplet with partially dissolved residual core as a function of the ambient relative humidity. For application to a nanometric sodium chloride particle we have extended the original approach by (i) considering the nonideality of the solution through the dependence of molecular volumes of the solvent and solute molecules and the solute and solvent activities on the solution concentration, (ii) deriving an equation for the estimation of the efﬂorescence properties of a homogeneous solution droplet, and (iii) combining the empiri

U2 - 10.5194/acp-15-3851-2015

DO - 10.5194/acp-15-3851-2015

M3 - Article

VL - 15

SP - 3851

EP - 3871

JO - Atmospheric Chemistry and Physics

JF - Atmospheric Chemistry and Physics

SN - 1680-7316

ER -

ID: 5767583