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Determination of AsSI-SbSI glasses short-range structure via raman spectroscopy, XPS and XRD. / Kurushkin, Mikhail V.; Markov, Viktor A.; Semencha, Alexandr V.; Mikhailov, Mikhail D.; Tverjanovich, Andrey S.; Shakhmin, Aleksandr L.; Larionova, Tatiana V.; Andreeva, Valentina D.

In: International Journal of Applied Glass Science, Vol. 9, No. 1, 01.01.2018, p. 85-89.

Research output: Contribution to journal › Article › peer-review

Harvard

Kurushkin, MV, Markov, VA, Semencha, AV, Mikhailov, MD, Tverjanovich, AS, Shakhmin, AL, Larionova, TV & Andreeva, VD 2018, 'Determination of AsSI-SbSI glasses short-range structure via raman spectroscopy, XPS and XRD', International Journal of Applied Glass Science, vol. 9, no. 1, pp. 85-89. https://doi.org/10.1111/ijag.12279

APA

Kurushkin, M. V., Markov, V. A., Semencha, A. V., Mikhailov, M. D., Tverjanovich, A. S., Shakhmin, A. L., Larionova, T. V., & Andreeva, V. D. (2018). Determination of AsSI-SbSI glasses short-range structure via raman spectroscopy, XPS and XRD. International Journal of Applied Glass Science, 9(1), 85-89. https://doi.org/10.1111/ijag.12279

Vancouver

Kurushkin MV, Markov VA, Semencha AV, Mikhailov MD, Tverjanovich AS, Shakhmin AL et al. Determination of AsSI-SbSI glasses short-range structure via raman spectroscopy, XPS and XRD. International Journal of Applied Glass Science. 2018 Jan 1;9(1):85-89. https://doi.org/10.1111/ijag.12279

Author

Kurushkin, Mikhail V. ; Markov, Viktor A. ; Semencha, Alexandr V. ; Mikhailov, Mikhail D. ; Tverjanovich, Andrey S. ; Shakhmin, Aleksandr L. ; Larionova, Tatiana V. ; Andreeva, Valentina D. / Determination of AsSI-SbSI glasses short-range structure via raman spectroscopy, XPS and XRD. In: International Journal of Applied Glass Science. 2018 ; Vol. 9, No. 1. pp. 85-89.

BibTeX

@article{a57bb2781aa940ad935c30db8c2df3db,
title = "Determination of AsSI-SbSI glasses short-range structure via raman spectroscopy, XPS and XRD",
abstract = "The ability to predict the influence of dopants (such as antimony) on the shortrange structure of As-S-I glasses has the potential to help design glasses with modified properties. In the present work, the short-range structure of As-Sb-S-I glasses has been investigated along AsSI-SbSI section of fixed sulfur and iodine concentrations and equivalent arsenic by antimony substitution. At high arsenic content (As:Sb≥2:1) antimony substitutes arsenic in AsI3 molecules justified by Raman spectroscopy and XPS. Further antimony introduction (As:Sb<2:1) leads to the substitution of arsenic by antimony in -S-As-S-polymeric chains, leading to SbSI crystallization justified by XRD. The resulting two-dimensional schematic diagrams represent the AsSI-SbSI glasses short-range structure and show the mechanism of arsenic by antimony substitution.",
keywords = "Characterization, Microstructure, Raman spectroscopy, Structure, X-ray diffraction, X-ray photoelectron spectroscopy",
author = "Kurushkin, {Mikhail V.} and Markov, {Viktor A.} and Semencha, {Alexandr V.} and Mikhailov, {Mikhail D.} and Tverjanovich, {Andrey S.} and Shakhmin, {Aleksandr L.} and Larionova, {Tatiana V.} and Andreeva, {Valentina D.}",
year = "2018",
month = jan,
day = "1",
doi = "10.1111/ijag.12279",
language = "English",
volume = "9",
pages = "85--89",
journal = "International Journal of Applied Glass Science",
issn = "2041-1286",
publisher = "Wiley-Blackwell",
number = "1",

}

RIS

TY - JOUR

T1 - Determination of AsSI-SbSI glasses short-range structure via raman spectroscopy, XPS and XRD

AU - Kurushkin, Mikhail V.

AU - Markov, Viktor A.

AU - Semencha, Alexandr V.

AU - Mikhailov, Mikhail D.

AU - Tverjanovich, Andrey S.

AU - Shakhmin, Aleksandr L.

AU - Larionova, Tatiana V.

AU - Andreeva, Valentina D.

PY - 2018/1/1

Y1 - 2018/1/1

N2 - The ability to predict the influence of dopants (such as antimony) on the shortrange structure of As-S-I glasses has the potential to help design glasses with modified properties. In the present work, the short-range structure of As-Sb-S-I glasses has been investigated along AsSI-SbSI section of fixed sulfur and iodine concentrations and equivalent arsenic by antimony substitution. At high arsenic content (As:Sb≥2:1) antimony substitutes arsenic in AsI3 molecules justified by Raman spectroscopy and XPS. Further antimony introduction (As:Sb<2:1) leads to the substitution of arsenic by antimony in -S-As-S-polymeric chains, leading to SbSI crystallization justified by XRD. The resulting two-dimensional schematic diagrams represent the AsSI-SbSI glasses short-range structure and show the mechanism of arsenic by antimony substitution.

AB - The ability to predict the influence of dopants (such as antimony) on the shortrange structure of As-S-I glasses has the potential to help design glasses with modified properties. In the present work, the short-range structure of As-Sb-S-I glasses has been investigated along AsSI-SbSI section of fixed sulfur and iodine concentrations and equivalent arsenic by antimony substitution. At high arsenic content (As:Sb≥2:1) antimony substitutes arsenic in AsI3 molecules justified by Raman spectroscopy and XPS. Further antimony introduction (As:Sb<2:1) leads to the substitution of arsenic by antimony in -S-As-S-polymeric chains, leading to SbSI crystallization justified by XRD. The resulting two-dimensional schematic diagrams represent the AsSI-SbSI glasses short-range structure and show the mechanism of arsenic by antimony substitution.

KW - Characterization

KW - Microstructure

KW - Raman spectroscopy

KW - Structure

KW - X-ray diffraction

KW - X-ray photoelectron spectroscopy

UR - http://www.scopus.com/inward/record.url?scp=85021306149&partnerID=8YFLogxK

UR - http://www.mendeley.com/research/determination-assisbsi-glasses-shortrange-structure-via-raman-spectroscopy-xps-xrd

U2 - 10.1111/ijag.12279

DO - 10.1111/ijag.12279

M3 - Article

AN - SCOPUS:85021306149

VL - 9

SP - 85

EP - 89

JO - International Journal of Applied Glass Science

JF - International Journal of Applied Glass Science

SN - 2041-1286

IS - 1

ER -

ID: 32901941