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Dendron brushes and dendronized polymers: a theoretical outlook. / Borisov, O.V.; Polotsky, A.A.; Rud, O.V.; Zhulina, E.B.; Leermakers, F.A.M.; Birshtein, T.M.

In: Soft Matter, Vol. 10, No. 13, 2014, p. 2093-2101.

Research output: Contribution to journalArticlepeer-review

Harvard

Borisov, OV, Polotsky, AA, Rud, OV, Zhulina, EB, Leermakers, FAM & Birshtein, TM 2014, 'Dendron brushes and dendronized polymers: a theoretical outlook', Soft Matter, vol. 10, no. 13, pp. 2093-2101. https://doi.org/10.1039/c3sm53019a

APA

Borisov, O. V., Polotsky, A. A., Rud, O. V., Zhulina, E. B., Leermakers, F. A. M., & Birshtein, T. M. (2014). Dendron brushes and dendronized polymers: a theoretical outlook. Soft Matter, 10(13), 2093-2101. https://doi.org/10.1039/c3sm53019a

Vancouver

Borisov OV, Polotsky AA, Rud OV, Zhulina EB, Leermakers FAM, Birshtein TM. Dendron brushes and dendronized polymers: a theoretical outlook. Soft Matter. 2014;10(13):2093-2101. https://doi.org/10.1039/c3sm53019a

Author

Borisov, O.V. ; Polotsky, A.A. ; Rud, O.V. ; Zhulina, E.B. ; Leermakers, F.A.M. ; Birshtein, T.M. / Dendron brushes and dendronized polymers: a theoretical outlook. In: Soft Matter. 2014 ; Vol. 10, No. 13. pp. 2093-2101.

BibTeX

@article{85d933776bef4853ba48f892aba60621,
title = "Dendron brushes and dendronized polymers: a theoretical outlook",
abstract = "Dendron brushes are molecular structures built up of treelike macromolecules, with multiple generations of branches, grafted with a root segment to a surface (particle) or to a backbone chain (dendronized polymer) with a sufficiently high grafting density so that the dendrons interact laterally. Recent advances in the theory of dendron brushes are highlighted and complemented by insights from numerical self-consistent field modelling. Our focus is on controversial issues, which are still under debate, such as, the strain distribution in individual dendrons and the appearance of distinct populations with a different extent of stretching for dendrons in planar brushes. We anticipate that dendritic brushes (i) show a strong resistance against bending, which may manifest in a high apparent persistence length of dendronized polymers, and (ii) have an unusually large beneficial effect on the colloidal stability due to the sharp steric repulsive interaction observed when these surface layers are pushed towards the o",
author = "O.V. Borisov and A.A. Polotsky and O.V. Rud and E.B. Zhulina and F.A.M. Leermakers and T.M. Birshtein",
year = "2014",
doi = "10.1039/c3sm53019a",
language = "English",
volume = "10",
pages = "2093--2101",
journal = "Soft Matter",
issn = "1744-683X",
publisher = "Royal Society of Chemistry",
number = "13",

}

RIS

TY - JOUR

T1 - Dendron brushes and dendronized polymers: a theoretical outlook

AU - Borisov, O.V.

AU - Polotsky, A.A.

AU - Rud, O.V.

AU - Zhulina, E.B.

AU - Leermakers, F.A.M.

AU - Birshtein, T.M.

PY - 2014

Y1 - 2014

N2 - Dendron brushes are molecular structures built up of treelike macromolecules, with multiple generations of branches, grafted with a root segment to a surface (particle) or to a backbone chain (dendronized polymer) with a sufficiently high grafting density so that the dendrons interact laterally. Recent advances in the theory of dendron brushes are highlighted and complemented by insights from numerical self-consistent field modelling. Our focus is on controversial issues, which are still under debate, such as, the strain distribution in individual dendrons and the appearance of distinct populations with a different extent of stretching for dendrons in planar brushes. We anticipate that dendritic brushes (i) show a strong resistance against bending, which may manifest in a high apparent persistence length of dendronized polymers, and (ii) have an unusually large beneficial effect on the colloidal stability due to the sharp steric repulsive interaction observed when these surface layers are pushed towards the o

AB - Dendron brushes are molecular structures built up of treelike macromolecules, with multiple generations of branches, grafted with a root segment to a surface (particle) or to a backbone chain (dendronized polymer) with a sufficiently high grafting density so that the dendrons interact laterally. Recent advances in the theory of dendron brushes are highlighted and complemented by insights from numerical self-consistent field modelling. Our focus is on controversial issues, which are still under debate, such as, the strain distribution in individual dendrons and the appearance of distinct populations with a different extent of stretching for dendrons in planar brushes. We anticipate that dendritic brushes (i) show a strong resistance against bending, which may manifest in a high apparent persistence length of dendronized polymers, and (ii) have an unusually large beneficial effect on the colloidal stability due to the sharp steric repulsive interaction observed when these surface layers are pushed towards the o

U2 - 10.1039/c3sm53019a

DO - 10.1039/c3sm53019a

M3 - Article

VL - 10

SP - 2093

EP - 2101

JO - Soft Matter

JF - Soft Matter

SN - 1744-683X

IS - 13

ER -

ID: 5722712