Standard

Deep eutectic solvents based on carboxylic acids for metals separation from plant samples : Elemental analysis by ICP-OES. / Shishov, Andrey; Gerasimov, Artur; Bulatov, Andrey.

In: Food Chemistry, Vol. 366, 130634, 01.01.2022.

Research output: Contribution to journal › Article › peer-review

Harvard

Shishov, A, Gerasimov, A & Bulatov, A 2022, 'Deep eutectic solvents based on carboxylic acids for metals separation from plant samples: Elemental analysis by ICP-OES', Food Chemistry, vol. 366, 130634. https://doi.org/10.1016/j.foodchem.2021.130634

APA

Shishov, A., Gerasimov, A., & Bulatov, A. (2022). Deep eutectic solvents based on carboxylic acids for metals separation from plant samples: Elemental analysis by ICP-OES. Food Chemistry, 366, [130634]. https://doi.org/10.1016/j.foodchem.2021.130634

Vancouver

Shishov A, Gerasimov A, Bulatov A. Deep eutectic solvents based on carboxylic acids for metals separation from plant samples: Elemental analysis by ICP-OES. Food Chemistry. 2022 Jan 1;366. 130634. https://doi.org/10.1016/j.foodchem.2021.130634

Author

Shishov, Andrey ; Gerasimov, Artur ; Bulatov, Andrey. / Deep eutectic solvents based on carboxylic acids for metals separation from plant samples : Elemental analysis by ICP-OES. In: Food Chemistry. 2022 ; Vol. 366.

BibTeX

@article{e6e24c0d8ef74e068eb949b52967926b,
title = "Deep eutectic solvents based on carboxylic acids for metals separation from plant samples: Elemental analysis by ICP-OES",
abstract = "Deep eutectic solvents based on choline chloride, carboxylic acids, urea, and polyols were investigated for separation of 14 metals from plant samples. It was found that carboxylic acid as precursor of DES played key-role for effective metals separation. It was established that the solvent synthesized from choline chloride and malic acid provided highest extraction recovery (from 73 to 88%). Mixing and heating the solvent and sample for 30 min at a temperature of 70 degrees C provided effective separation of metals from plant sample. The developed procedure is not required a microwave digestion of samples. After separation the solvent phase containing analytes was dissolved in aqueous phase and analyzed. The developed procedure was applied to elemental analysis of plant tobacco and lettuce samples by inductively coupled plasma optical emission spectroscopy. Limits of detection calculated as three times the signal-to-noise ratio were in the range from 0.2 to 17 mg kg-1.",
keywords = "Deep eutectic solvent, Determination of metals, Elemental analysis, Extraction, ICP-OES, Lettuce, Microwave digestion, Plant tobacco, Water, Solvents, Metals, Plants, Carboxylic Acids, CHOLINE CHLORIDE, TOBACCO, CU, ZN, CIGARETTE, PHASE MICROEXTRACTION, TOXIC METALS, FE",
author = "Andrey Shishov and Artur Gerasimov and Andrey Bulatov",
note = "Publisher Copyright: {\textcopyright} 2021 Elsevier Ltd",
year = "2022",
month = jan,
day = "1",
doi = "10.1016/j.foodchem.2021.130634",
language = "English",
volume = "366",
journal = "Food Chemistry",
issn = "0308-8146",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Deep eutectic solvents based on carboxylic acids for metals separation from plant samples

T2 - Elemental analysis by ICP-OES

AU - Shishov, Andrey

AU - Gerasimov, Artur

AU - Bulatov, Andrey

N1 - Publisher Copyright: © 2021 Elsevier Ltd

PY - 2022/1/1

Y1 - 2022/1/1

N2 - Deep eutectic solvents based on choline chloride, carboxylic acids, urea, and polyols were investigated for separation of 14 metals from plant samples. It was found that carboxylic acid as precursor of DES played key-role for effective metals separation. It was established that the solvent synthesized from choline chloride and malic acid provided highest extraction recovery (from 73 to 88%). Mixing and heating the solvent and sample for 30 min at a temperature of 70 degrees C provided effective separation of metals from plant sample. The developed procedure is not required a microwave digestion of samples. After separation the solvent phase containing analytes was dissolved in aqueous phase and analyzed. The developed procedure was applied to elemental analysis of plant tobacco and lettuce samples by inductively coupled plasma optical emission spectroscopy. Limits of detection calculated as three times the signal-to-noise ratio were in the range from 0.2 to 17 mg kg-1.

AB - Deep eutectic solvents based on choline chloride, carboxylic acids, urea, and polyols were investigated for separation of 14 metals from plant samples. It was found that carboxylic acid as precursor of DES played key-role for effective metals separation. It was established that the solvent synthesized from choline chloride and malic acid provided highest extraction recovery (from 73 to 88%). Mixing and heating the solvent and sample for 30 min at a temperature of 70 degrees C provided effective separation of metals from plant sample. The developed procedure is not required a microwave digestion of samples. After separation the solvent phase containing analytes was dissolved in aqueous phase and analyzed. The developed procedure was applied to elemental analysis of plant tobacco and lettuce samples by inductively coupled plasma optical emission spectroscopy. Limits of detection calculated as three times the signal-to-noise ratio were in the range from 0.2 to 17 mg kg-1.

KW - Deep eutectic solvent

KW - Determination of metals

KW - Elemental analysis

KW - Extraction

KW - ICP-OES

KW - Lettuce

KW - Microwave digestion

KW - Plant tobacco

KW - Water

KW - Solvents

KW - Metals

KW - Plants

KW - Carboxylic Acids

KW - CHOLINE CHLORIDE

KW - TOBACCO

KW - CU

KW - ZN

KW - CIGARETTE

KW - PHASE MICROEXTRACTION

KW - TOXIC METALS

KW - FE

UR - http://www.scopus.com/inward/record.url?scp=85111303320&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/e5945213-e7d3-33e7-beb6-f1acecd341c6/

U2 - 10.1016/j.foodchem.2021.130634

DO - 10.1016/j.foodchem.2021.130634

M3 - Article

C2 - 34332422

AN - SCOPUS:85111303320

VL - 366

JO - Food Chemistry

JF - Food Chemistry

SN - 0308-8146

M1 - 130634

ER -

ID: 87375661