TY - JOUR

T1 - Deep eutectic solvents are not only effective extractants

AU - Shishov, Andrey

AU - Pochivalov, Aleksei

AU - Nugbienyo, Lawrence

AU - Andruch, Vasil

AU - Bulatov, Andrey

N1 - Funding Information: Andrey Bulatov gratefully acknowledges the Russian Foundation for Basic Research (project no. 18-33-20004) Russian Federation. Andrey Shishov gratefully acknowledges a grant from the President of the Russian Federation MK-1154.2020.3 . Russian Federation Vasil Andruch would like to thanks to the internal grant system of P.J. Šafárik University ( vvgs-2020-1439 ), Slovakia for partial financial support. Publisher Copyright: © 2020 Elsevier B.V. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/8/1

Y1 - 2020/8/1

N2 - Deep eutectic solvents are compounds formed by a donor and an acceptor of hydrogen bond; and are in liquid state at ambient temperature. They are non-volatile, with high thermal stability and readily dissolve many organic and inorganic compounds. They are recognized as green and cheap alternatives to ionic liquids. They have recently appeared in analytical practice but have already found wide application in various fields of analytical chemistry; mainly as effective extractants. However, their use as extractants does not limit the scope of their capabilities. This review is primarily devoted to the description of new possibilities of applications of deep eutectic solvents in analytical chemistry; including such areas as chromatographic separation, electrochemical analysis, sample preparation, synthesis and modification of new sorption materials. In addition, the stability of deep eutectic solvents, terminology, classification, further trends and some errors and inaccuracies associated with their applications are discussed.

AB - Deep eutectic solvents are compounds formed by a donor and an acceptor of hydrogen bond; and are in liquid state at ambient temperature. They are non-volatile, with high thermal stability and readily dissolve many organic and inorganic compounds. They are recognized as green and cheap alternatives to ionic liquids. They have recently appeared in analytical practice but have already found wide application in various fields of analytical chemistry; mainly as effective extractants. However, their use as extractants does not limit the scope of their capabilities. This review is primarily devoted to the description of new possibilities of applications of deep eutectic solvents in analytical chemistry; including such areas as chromatographic separation, electrochemical analysis, sample preparation, synthesis and modification of new sorption materials. In addition, the stability of deep eutectic solvents, terminology, classification, further trends and some errors and inaccuracies associated with their applications are discussed.

KW - Absorption

KW - Chromatographic analysis

KW - Classification

KW - Deep eutectic solvents

KW - Electrochemical analysis

KW - Extraction

KW - Sample preparation

KW - Sorption materials

KW - LIQUID-PHASE MICROEXTRACTION

KW - MOLECULARLY IMPRINTED POLYMERS

KW - MAGNETIC BUCKY GELS

KW - HUMAN URINE SAMPLES

KW - GLASSY-CARBON

KW - CHOLINE CHLORIDE

KW - AROMATIC-HYDROCARBONS

KW - MODIFIED SILICA

KW - CARBON-DIOXIDE

KW - DETERMINING CU

UR - http://www.scopus.com/inward/record.url?scp=85087390541&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/f8e5fe64-606e-359c-ade6-f2aa6685cbd7/

U2 - 10.1016/j.trac.2020.115956

DO - 10.1016/j.trac.2020.115956

M3 - Review article

AN - SCOPUS:85087390541

VL - 129

JO - TrAC - Trends in Analytical Chemistry

JF - TrAC - Trends in Analytical Chemistry

SN - 0165-9936

M1 - 115956

ER -