Decomposition of pentaammineaquacobalt(III) perchlorate under laser radiation action

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Decomposition of pentaammineaquacobalt(III) perchlorate under laser radiation action. / Abdrashitov, G. O.; Aver’yanov, A. O.; Bal’makov, M. D.; Ilyushin, M. A.; Tverjanovich, A. S.; Tver’yanovich, Yu S.

In: Russian Journal of General Chemistry, Vol. 87, No. 7, 01.07.2017, p. 1451-1455.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{78625609db4849c1973c1dd80d6a31c2,

title = "Decomposition of pentaammineaquacobalt(III) perchlorate under laser radiation action",

abstract = "Photolytic decomposition of the complex [Co(NH3)5(H2O)](ClO4)3 under the action of a laser with a wavelength of 355 nm, which is resonant in energy to the energy of the (1A1g → 1T2g) d–d transition, was studied. Decomposition of the complex is accompanied by a release of ammonia with its subsequent oxidation to nitrogen oxides and by partial cobalt reduction with the formation of the mixed cobalt(II, III) oxide Co3O4.",

keywords = "energy-saturated cobalt complexes, laser-induced decomposition of complexes",

author = "Abdrashitov, {G. O.} and Aver{\textquoteright}yanov, {A. O.} and Bal{\textquoteright}makov, {M. D.} and Ilyushin, {M. A.} and Tverjanovich, {A. S.} and Tver{\textquoteright}yanovich, {Yu S.}",

year = "2017",

month = jul,

day = "1",

doi = "10.1134/S1070363217070015",

language = "English",

volume = "87",

pages = "1451--1455",

journal = "Russian Journal of General Chemistry",

issn = "1070-3632",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "7",

}

RIS

TY - JOUR

T1 - Decomposition of pentaammineaquacobalt(III) perchlorate under laser radiation action

AU - Abdrashitov, G. O.

AU - Aver’yanov, A. O.

AU - Bal’makov, M. D.

AU - Ilyushin, M. A.

AU - Tverjanovich, A. S.

AU - Tver’yanovich, Yu S.

PY - 2017/7/1

Y1 - 2017/7/1

N2 - Photolytic decomposition of the complex [Co(NH3)5(H2O)](ClO4)3 under the action of a laser with a wavelength of 355 nm, which is resonant in energy to the energy of the (1A1g → 1T2g) d–d transition, was studied. Decomposition of the complex is accompanied by a release of ammonia with its subsequent oxidation to nitrogen oxides and by partial cobalt reduction with the formation of the mixed cobalt(II, III) oxide Co3O4.

AB - Photolytic decomposition of the complex [Co(NH3)5(H2O)](ClO4)3 under the action of a laser with a wavelength of 355 nm, which is resonant in energy to the energy of the (1A1g → 1T2g) d–d transition, was studied. Decomposition of the complex is accompanied by a release of ammonia with its subsequent oxidation to nitrogen oxides and by partial cobalt reduction with the formation of the mixed cobalt(II, III) oxide Co3O4.

KW - energy-saturated cobalt complexes

KW - laser-induced decomposition of complexes

UR - http://www.scopus.com/inward/record.url?scp=85028305616&partnerID=8YFLogxK

U2 - 10.1134/S1070363217070015

DO - 10.1134/S1070363217070015

M3 - Article

AN - SCOPUS:85028305616

VL - 87

SP - 1451

EP - 1455

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 7

ER -

ID: 32902476