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DARK AND PHOTOCHEMICAL REACTIONS OF CO3RH(CO)12 WITH DIPHENYLACETYLENE. CRYSTAL AND MOLECULAR STRUCTURE OF THE CO3RH(Μ2 - CO)2 (CO)8,(Μ4,Η2 - PHC2PH) CLUSTER. / Tunik, S.P.; Krym, V.R.; Starova, G.L.; Nikol’skii, A.B.; Podkorytov, I.S.; Ooi, S.; Yamasaki, M.; Shiro, M.

In: Journal of Organometallic Chemistry, No. 1, 1994, p. 83-88.

Research output: Contribution to journal › Article

Harvard

Tunik, SP, Krym, VR, Starova, GL, Nikol’skii, AB, Podkorytov, IS, Ooi, S, Yamasaki, M & Shiro, M 1994, 'DARK AND PHOTOCHEMICAL REACTIONS OF CO3RH(CO)12 WITH DIPHENYLACETYLENE. CRYSTAL AND MOLECULAR STRUCTURE OF THE CO3RH(Μ2 - CO)2 (CO)8,(Μ4,Η2 - PHC2PH) CLUSTER', Journal of Organometallic Chemistry, no. 1, pp. 83-88. <http://elibrary.ru/item.asp?id=12742529>

APA

Tunik, S. P., Krym, V. R., Starova, G. L., Nikol’skii, A. B., Podkorytov, I. S., Ooi, S., Yamasaki, M., & Shiro, M. (1994). DARK AND PHOTOCHEMICAL REACTIONS OF CO3RH(CO)12 WITH DIPHENYLACETYLENE. CRYSTAL AND MOLECULAR STRUCTURE OF THE CO3RH(Μ2 - CO)2 (CO)8,(Μ4,Η2 - PHC2PH) CLUSTER. Journal of Organometallic Chemistry, (1), 83-88. http://elibrary.ru/item.asp?id=12742529

Vancouver

Tunik SP, Krym VR, Starova GL, Nikol’skii AB, Podkorytov IS, Ooi S et al. DARK AND PHOTOCHEMICAL REACTIONS OF CO3RH(CO)12 WITH DIPHENYLACETYLENE. CRYSTAL AND MOLECULAR STRUCTURE OF THE CO3RH(Μ2 - CO)2 (CO)8,(Μ4,Η2 - PHC2PH) CLUSTER. Journal of Organometallic Chemistry. 1994;(1):83-88.

Author

Tunik, S.P. ; Krym, V.R. ; Starova, G.L. ; Nikol’skii, A.B. ; Podkorytov, I.S. ; Ooi, S. ; Yamasaki, M. ; Shiro, M. / DARK AND PHOTOCHEMICAL REACTIONS OF CO3RH(CO)12 WITH DIPHENYLACETYLENE. CRYSTAL AND MOLECULAR STRUCTURE OF THE CO3RH(Μ2 - CO)2 (CO)8,(Μ4,Η2 - PHC2PH) CLUSTER. In: Journal of Organometallic Chemistry. 1994 ; No. 1. pp. 83-88.

BibTeX

@article{5ec8d9908864471ea4be361600e84720,
title = "DARK AND PHOTOCHEMICAL REACTIONS OF CO3RH(CO)12 WITH DIPHENYLACETYLENE. CRYSTAL AND MOLECULAR STRUCTURE OF THE CO3RH(Μ2 - CO)2 (CO)8,(Μ4,Η2 - PHC2PH) CLUSTER",
abstract = "Dark and photochemical reactions of Co3Rh(CO)12 with diphenylacetylene yield two butterfly clusters with the alkyne inserted into the tetrametal framework. One of them is the previously unknown cluster Co3Rh(μ - CO)2(CO)8(μ4,η2, - PhC2Ph). It was characterized by X-ray crystallography (dark violet compound crystallizing in monoclinic space group C2/c, a = 15.665(2), b = 17.947(5), c = 9.078(1) {\AA}, β = 93.91(1)°, v = 2546.1(8) {\AA}3, Z = 4). The 13C NMR study showed that the solid state structure is retained in solution. The second product is the Co2Rh2(μ - CO)2(CO)8(μ4,η2 - PhC2Ph) cluster obtained earlier and identified herein by its 13C NMR spectrum. The formation of this cluster is evidently caused by bimolecular metal-metal exchange between cluster molecules in the course of the reaction. {\textcopyright} 1994.",
author = "S.P. Tunik and V.R. Krym and G.L. Starova and A.B. Nikol{\textquoteright}skii and I.S. Podkorytov and S. Ooi and M. Yamasaki and M. Shiro",
year = "1994",
language = "English",
pages = "83--88",
journal = "Journal of Organometallic Chemistry",
issn = "0022-328X",
publisher = "Elsevier",
number = "1",

}

RIS

TY - JOUR

T1 - DARK AND PHOTOCHEMICAL REACTIONS OF CO3RH(CO)12 WITH DIPHENYLACETYLENE. CRYSTAL AND MOLECULAR STRUCTURE OF THE CO3RH(Μ2 - CO)2 (CO)8,(Μ4,Η2 - PHC2PH) CLUSTER

AU - Tunik, S.P.

AU - Krym, V.R.

AU - Starova, G.L.

AU - Nikol’skii, A.B.

AU - Podkorytov, I.S.

AU - Ooi, S.

AU - Yamasaki, M.

AU - Shiro, M.

PY - 1994

Y1 - 1994

N2 - Dark and photochemical reactions of Co3Rh(CO)12 with diphenylacetylene yield two butterfly clusters with the alkyne inserted into the tetrametal framework. One of them is the previously unknown cluster Co3Rh(μ - CO)2(CO)8(μ4,η2, - PhC2Ph). It was characterized by X-ray crystallography (dark violet compound crystallizing in monoclinic space group C2/c, a = 15.665(2), b = 17.947(5), c = 9.078(1) Å, β = 93.91(1)°, v = 2546.1(8) Å3, Z = 4). The 13C NMR study showed that the solid state structure is retained in solution. The second product is the Co2Rh2(μ - CO)2(CO)8(μ4,η2 - PhC2Ph) cluster obtained earlier and identified herein by its 13C NMR spectrum. The formation of this cluster is evidently caused by bimolecular metal-metal exchange between cluster molecules in the course of the reaction. © 1994.

AB - Dark and photochemical reactions of Co3Rh(CO)12 with diphenylacetylene yield two butterfly clusters with the alkyne inserted into the tetrametal framework. One of them is the previously unknown cluster Co3Rh(μ - CO)2(CO)8(μ4,η2, - PhC2Ph). It was characterized by X-ray crystallography (dark violet compound crystallizing in monoclinic space group C2/c, a = 15.665(2), b = 17.947(5), c = 9.078(1) Å, β = 93.91(1)°, v = 2546.1(8) Å3, Z = 4). The 13C NMR study showed that the solid state structure is retained in solution. The second product is the Co2Rh2(μ - CO)2(CO)8(μ4,η2 - PhC2Ph) cluster obtained earlier and identified herein by its 13C NMR spectrum. The formation of this cluster is evidently caused by bimolecular metal-metal exchange between cluster molecules in the course of the reaction. © 1994.

M3 - Article

SP - 83

EP - 88

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

IS - 1

ER -

ID: 5025838