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The new zeolite - dachiardite-K (IMA No. 2015-041) - the K-dominant member of the dachiardite series with the idealized formula (K 2 Ca)(Al 4 Si 20 O 48 )∙13H 2 O, has been found in salbands of opal-chalcedony hydrothermal veinlets cross-cutting hydrothermally altered effusive rocks of the Zvezdel paleovolcanic complex near the village of Austa, Momchilgrad Municipality, Eastern Rhodopes, Bulgaria. It occurs there in association with chalcedony, opal, dachiardite-Ca, dachiardite-Na, ferrierite-Mg, ferrierite-K, clinoptilolite-Ca, clinoptilolite-K, mordenite, smectite, celadonite, calcite, and barite. Dachiardite-K forms spherical radial aggregates, up to 8 mm in diameter, consisting of split needle-shaped individuals. Color is white to colorless. Perfect cleavage is observed on (100). D meas = 2.18(2), D calc = 2.169 g/cm 3 . The IR spectrum is given. Dachiardite-K is biaxial (+), a = 1.477 (calc.), b = 1.478(2), g = 1.481(2), 2V meas = 65(10)°. The chemical composition (electron microprobe, mean of 6 spot analyses, H 2 O determined by thermogravimetric method, wt %) is: K 2 O 4.51, CaO 3.27, BaO 0.41, A1 2 O 3 10.36, SiO 2 67.90, H 2 O 13.2, total 99.65. The empirical formula is: H 26.23 K 1.71 Ca 1.04 Ba 0.05 Al 3.64 Si 20.24 O 61 . The strongest lines of the powder X-ray diffraction pattern [d, Å (I, %) (hkl)] are: 9.76 (24) (001), 8.85 (58) (200), 4.870 (59) (002), 3.807 (16) (202), 3.768 (20) (112, 020), 3.457 (100) (220), 2.966 (17) (602). Dachiardite-K is monoclinic, space group C2/m, Cm or C2; unit-cell parameters refined from powder data are: a = 18.670(8), b = 7.511(3), c = = 10.231(4) Å, b = 107.79(3)°, V= 1366(1) Å 3 , Z = 1. The type specimen is deposited in the Earth and Man National Museum, Sofia, Bulgaria, with the registration number 23927.
Original language | Russian |
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Pages (from-to) | 68-79 |
Number of pages | 12 |
Journal | Zapiski Rossiiskogo Mineralogicheskogo Obshchestva |
Volume | 145 |
Issue number | 1 |
State | Published - 1 Jan 2016 |
ID: 42606689