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Cu3(SeO4)2(SeO3OH)2(H2O)16 - The First Example of a Linear Octahedral-Tetrahedral Heptamer in Inorganic Compounds. / Gurzhiy, V.V.; Al-Shuray, A.; Britvin, S.N.; Krivovichev, S.V.

In: European Journal of Inorganic Chemistry, No. 32, 2015, p. 5311-5313.

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@article{3e0331c398384100ae7527b6922efd52,
title = "Cu3(SeO4)2(SeO3OH)2(H2O)16 - The First Example of a Linear Octahedral-Tetrahedral Heptamer in Inorganic Compounds",
abstract = "Cu-3(SeO4)(2)(SeO3OH)(2)(H2O)(16) (1) is a novel copper selenate hydrate and the first inorganic compound to contain linear octahedral-tetrahedral heptamers. The heptamers are formed by successive polymerization of two SeO3OH tetrahedra, two SeO4 tetrahedra, and three Cu(H2O)(4)O-2 octahedra. The linkages between the octahedra and tetrahedra are in the trans-configuration, which is in agreement with the Jahn-Teller distortion of the octahedral coordination geometry of Cu2+.",
author = "V.V. Gurzhiy and A. Al-Shuray and S.N. Britvin and S.V. Krivovichev",
year = "2015",
doi = "10.1002/ejic.201500927",
language = "English",
pages = "5311--5313",
journal = "Berichte der deutschen chemischen Gesellschaft",
issn = "0365-9496",
publisher = "Wiley-Blackwell",
number = "32",

}

RIS

TY - JOUR

T1 - Cu3(SeO4)2(SeO3OH)2(H2O)16 - The First Example of a Linear Octahedral-Tetrahedral Heptamer in Inorganic Compounds

AU - Gurzhiy, V.V.

AU - Al-Shuray, A.

AU - Britvin, S.N.

AU - Krivovichev, S.V.

PY - 2015

Y1 - 2015

N2 - Cu-3(SeO4)(2)(SeO3OH)(2)(H2O)(16) (1) is a novel copper selenate hydrate and the first inorganic compound to contain linear octahedral-tetrahedral heptamers. The heptamers are formed by successive polymerization of two SeO3OH tetrahedra, two SeO4 tetrahedra, and three Cu(H2O)(4)O-2 octahedra. The linkages between the octahedra and tetrahedra are in the trans-configuration, which is in agreement with the Jahn-Teller distortion of the octahedral coordination geometry of Cu2+.

AB - Cu-3(SeO4)(2)(SeO3OH)(2)(H2O)(16) (1) is a novel copper selenate hydrate and the first inorganic compound to contain linear octahedral-tetrahedral heptamers. The heptamers are formed by successive polymerization of two SeO3OH tetrahedra, two SeO4 tetrahedra, and three Cu(H2O)(4)O-2 octahedra. The linkages between the octahedra and tetrahedra are in the trans-configuration, which is in agreement with the Jahn-Teller distortion of the octahedral coordination geometry of Cu2+.

U2 - 10.1002/ejic.201500927

DO - 10.1002/ejic.201500927

M3 - Article

SP - 5311

EP - 5313

JO - Berichte der deutschen chemischen Gesellschaft

JF - Berichte der deutschen chemischen Gesellschaft

SN - 0365-9496

IS - 32

ER -

ID: 3989244