Research output: Contribution to journal › Article
Cu3(SeO4)2(SeO3OH)2(H2O)16 - The First Example of a Linear Octahedral-Tetrahedral Heptamer in Inorganic Compounds. / Gurzhiy, V.V.; Al-Shuray, A.; Britvin, S.N.; Krivovichev, S.V.
In: European Journal of Inorganic Chemistry, No. 32, 2015, p. 5311-5313.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Cu3(SeO4)2(SeO3OH)2(H2O)16 - The First Example of a Linear Octahedral-Tetrahedral Heptamer in Inorganic Compounds
AU - Gurzhiy, V.V.
AU - Al-Shuray, A.
AU - Britvin, S.N.
AU - Krivovichev, S.V.
PY - 2015
Y1 - 2015
N2 - Cu-3(SeO4)(2)(SeO3OH)(2)(H2O)(16) (1) is a novel copper selenate hydrate and the first inorganic compound to contain linear octahedral-tetrahedral heptamers. The heptamers are formed by successive polymerization of two SeO3OH tetrahedra, two SeO4 tetrahedra, and three Cu(H2O)(4)O-2 octahedra. The linkages between the octahedra and tetrahedra are in the trans-configuration, which is in agreement with the Jahn-Teller distortion of the octahedral coordination geometry of Cu2+.
AB - Cu-3(SeO4)(2)(SeO3OH)(2)(H2O)(16) (1) is a novel copper selenate hydrate and the first inorganic compound to contain linear octahedral-tetrahedral heptamers. The heptamers are formed by successive polymerization of two SeO3OH tetrahedra, two SeO4 tetrahedra, and three Cu(H2O)(4)O-2 octahedra. The linkages between the octahedra and tetrahedra are in the trans-configuration, which is in agreement with the Jahn-Teller distortion of the octahedral coordination geometry of Cu2+.
U2 - 10.1002/ejic.201500927
DO - 10.1002/ejic.201500927
M3 - Article
SP - 5311
EP - 5313
JO - Berichte der deutschen chemischen Gesellschaft
JF - Berichte der deutschen chemischen Gesellschaft
SN - 0365-9496
IS - 32
ER -
ID: 3989244