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Crystal structures and thermal behavior of complexes of group 13 metal halides with pyridine-type ligands. / Sevastianova, T. N.; Davydova, E. I.; Kazakov, I. V.; Timoshkin, A. Yu.

In: Russian Chemical Bulletin, Vol. 64, No. 11, 01.11.2015, p. 2523-2535.

Research output: Contribution to journal › Review article › peer-review

Harvard

Sevastianova, TN, Davydova, EI, Kazakov, IV & Timoshkin, AY 2015, 'Crystal structures and thermal behavior of complexes of group 13 metal halides with pyridine-type ligands', Russian Chemical Bulletin, vol. 64, no. 11, pp. 2523-2535. https://doi.org/10.1007/s11172-015-1188-8, https://doi.org/10.1007/s11172-015-1188-8

APA

Sevastianova, T. N., Davydova, E. I., Kazakov, I. V., & Timoshkin, A. Y. (2015). Crystal structures and thermal behavior of complexes of group 13 metal halides with pyridine-type ligands. Russian Chemical Bulletin, 64(11), 2523-2535. https://doi.org/10.1007/s11172-015-1188-8, https://doi.org/10.1007/s11172-015-1188-8

Vancouver

Sevastianova TN, Davydova EI, Kazakov IV, Timoshkin AY. Crystal structures and thermal behavior of complexes of group 13 metal halides with pyridine-type ligands. Russian Chemical Bulletin. 2015 Nov 1;64(11):2523-2535. https://doi.org/10.1007/s11172-015-1188-8, https://doi.org/10.1007/s11172-015-1188-8

Author

Sevastianova, T. N. ; Davydova, E. I. ; Kazakov, I. V. ; Timoshkin, A. Yu. / Crystal structures and thermal behavior of complexes of group 13 metal halides with pyridine-type ligands. In: Russian Chemical Bulletin. 2015 ; Vol. 64, No. 11. pp. 2523-2535.

BibTeX

@article{25afc7efce384ed3957d10de81ee4e44,
title = "Crystal structures and thermal behavior of complexes of group 13 metal halides with pyridine-type ligands",
abstract = "Complexes of group 13 metal halides with pyridine-type ligands (pyridine, pyrazine, and 4, 4´-bipyridine) have molecular, polymeric, or ionic structures containing metal atoms with a coordination number of 4, 5, or 6 depending on the component ratio, the acceptor ability of the halide, the donor ability and the coordination mode of the ligand. The strongest donor-acceptor bond is formed in the 1 : 1 molecular complexes, and their transition to the gas phase is energetically most favorable. The acceptor ability of Lewis acids in the complexes decreases in the series AlCl3 > AlBr3 > GaCl3 > GaBr3 > GaI3. The stability of the complexes with respect to homogeneous dissociation correlates with the donor proton affinity. Group 13 metal trihalides act as catalysts for the pyrolysis of ligands.",
keywords = "4, 4´-bipyridine, complexes, crystal structure, group 13 metal halides, pyrazine, pyridine, thermal transformations",
author = "Sevastianova, {T. N.} and Davydova, {E. I.} and Kazakov, {I. V.} and Timoshkin, {A. Yu}",
note = "Publisher Copyright: {\textcopyright} 2015, Springer Science+Business Media New York.",
year = "2015",
month = nov,
day = "1",
doi = "10.1007/s11172-015-1188-8",
language = "English",
volume = "64",
pages = "2523--2535",
journal = "Russian Chemical Bulletin",
issn = "1066-5285",
publisher = "Springer Nature",
number = "11",

}

RIS

TY - JOUR

T1 - Crystal structures and thermal behavior of complexes of group 13 metal halides with pyridine-type ligands

AU - Sevastianova, T. N.

AU - Davydova, E. I.

AU - Kazakov, I. V.

AU - Timoshkin, A. Yu

N1 - Publisher Copyright: © 2015, Springer Science+Business Media New York.

PY - 2015/11/1

Y1 - 2015/11/1

N2 - Complexes of group 13 metal halides with pyridine-type ligands (pyridine, pyrazine, and 4, 4´-bipyridine) have molecular, polymeric, or ionic structures containing metal atoms with a coordination number of 4, 5, or 6 depending on the component ratio, the acceptor ability of the halide, the donor ability and the coordination mode of the ligand. The strongest donor-acceptor bond is formed in the 1 : 1 molecular complexes, and their transition to the gas phase is energetically most favorable. The acceptor ability of Lewis acids in the complexes decreases in the series AlCl3 > AlBr3 > GaCl3 > GaBr3 > GaI3. The stability of the complexes with respect to homogeneous dissociation correlates with the donor proton affinity. Group 13 metal trihalides act as catalysts for the pyrolysis of ligands.

AB - Complexes of group 13 metal halides with pyridine-type ligands (pyridine, pyrazine, and 4, 4´-bipyridine) have molecular, polymeric, or ionic structures containing metal atoms with a coordination number of 4, 5, or 6 depending on the component ratio, the acceptor ability of the halide, the donor ability and the coordination mode of the ligand. The strongest donor-acceptor bond is formed in the 1 : 1 molecular complexes, and their transition to the gas phase is energetically most favorable. The acceptor ability of Lewis acids in the complexes decreases in the series AlCl3 > AlBr3 > GaCl3 > GaBr3 > GaI3. The stability of the complexes with respect to homogeneous dissociation correlates with the donor proton affinity. Group 13 metal trihalides act as catalysts for the pyrolysis of ligands.

KW - 4, 4´-bipyridine

KW - complexes

KW - crystal structure

KW - group 13 metal halides

KW - pyrazine

KW - pyridine

KW - thermal transformations

UR - http://www.scopus.com/inward/record.url?scp=84988728238&partnerID=8YFLogxK

UR - https://www.webofscience.com/wos/woscc/full-record/WOS:000383959600001?SID=EUW1ED0A6DXmuEopGVik6LbicjemZ

U2 - 10.1007/s11172-015-1188-8

DO - 10.1007/s11172-015-1188-8

M3 - Review article

VL - 64

SP - 2523

EP - 2535

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 11

ER -

ID: 3979973