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Crystal structures and luminescence properties of halocuprates with trimethylsulfonium cations. / Петров, Андрей Андреевич; Luyi Chen, Luyi; Li, Mingming; Фатеев, Сергей; Петров, Андрей Витальевич; Хрусталев, В. Н.; Tarasov, Alexey B .

In: Dalton Transactions, Vol. 54, No. 22, 02.05.2025, p. 9088-9094.

Research output: Contribution to journal › Article › peer-review

Harvard

Петров, АА, Luyi Chen, L, Li, M, Фатеев, С, Петров, АВ, Хрусталев, ВН & Tarasov, AB 2025, 'Crystal structures and luminescence properties of halocuprates with trimethylsulfonium cations', Dalton Transactions, vol. 54, no. 22, pp. 9088-9094. https://doi.org/10.1039/D5DT00852B, https://doi.org/10.1039/D5DT00852B

APA

Петров, А. А., Luyi Chen, L., Li, M., Фатеев, С., Петров, А. В., Хрусталев, В. Н., & Tarasov, A. B. (2025). Crystal structures and luminescence properties of halocuprates with trimethylsulfonium cations. Dalton Transactions, 54(22), 9088-9094. https://doi.org/10.1039/D5DT00852B, https://doi.org/10.1039/D5DT00852B

Vancouver

Петров АА, Luyi Chen L, Li M, Фатеев С, Петров АВ, Хрусталев ВН et al. Crystal structures and luminescence properties of halocuprates with trimethylsulfonium cations. Dalton Transactions. 2025 May 2;54(22):9088-9094. https://doi.org/10.1039/D5DT00852B, https://doi.org/10.1039/D5DT00852B

Author

Петров, Андрей Андреевич ; Luyi Chen, Luyi ; Li, Mingming ; Фатеев, Сергей ; Петров, Андрей Витальевич ; Хрусталев, В. Н. ; Tarasov, Alexey B . / Crystal structures and luminescence properties of halocuprates with trimethylsulfonium cations. In: Dalton Transactions. 2025 ; Vol. 54, No. 22. pp. 9088-9094.

BibTeX

@article{f479bd662e0f41f1984f1f7fa428281f,
title = "Crystal structures and luminescence properties of halocuprates with trimethylsulfonium cations",
abstract = "We report the crystal structures, thermal stability, and luminescence properties of three trimethylsulfonium halocuprates: (TMS)Cu2I3, and two new bromide phases: (TMS)Cu2Br3 and (TMS)2CuBr3. (TMS)Cu2I3 and (TMS)Cu2Br3 are isostructural and contain double chains of edge-sharing [CuX4] tetrahedra, whereas (TMS)2CuBr3 features isolated [CuBr3]2− triangular units. All compounds exhibit direct bandgaps and demonstrate photoluminescence at low temperature, with (TMS)Cu2Br3 demonstrating temperature-dependent dual emission behavior, observed for the first time among related hybrid halocuprates. Through comparative analysis of optical properties with structurally related halocuprates and DFT calculations, we elucidate the structure–property relationships governing the observed luminescence behavior of ACu2X3-type halocuprates.",
author = "Петров, {Андрей Андреевич} and {Luyi Chen}, Luyi and Mingming Li and Сергей Фатеев and Петров, {Андрей Витальевич} and Хрусталев, {В. Н.} and Tarasov, {Alexey B}",
year = "2025",
month = may,
day = "2",
doi = "10.1039/D5DT00852B",
language = "English",
volume = "54",
pages = "9088--9094",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "22",

}

RIS

TY - JOUR

T1 - Crystal structures and luminescence properties of halocuprates with trimethylsulfonium cations

AU - Петров, Андрей Андреевич

AU - Luyi Chen, Luyi

AU - Li, Mingming

AU - Фатеев, Сергей

AU - Петров, Андрей Витальевич

AU - Хрусталев, В. Н.

AU - Tarasov, Alexey B

PY - 2025/5/2

Y1 - 2025/5/2

N2 - We report the crystal structures, thermal stability, and luminescence properties of three trimethylsulfonium halocuprates: (TMS)Cu2I3, and two new bromide phases: (TMS)Cu2Br3 and (TMS)2CuBr3. (TMS)Cu2I3 and (TMS)Cu2Br3 are isostructural and contain double chains of edge-sharing [CuX4] tetrahedra, whereas (TMS)2CuBr3 features isolated [CuBr3]2− triangular units. All compounds exhibit direct bandgaps and demonstrate photoluminescence at low temperature, with (TMS)Cu2Br3 demonstrating temperature-dependent dual emission behavior, observed for the first time among related hybrid halocuprates. Through comparative analysis of optical properties with structurally related halocuprates and DFT calculations, we elucidate the structure–property relationships governing the observed luminescence behavior of ACu2X3-type halocuprates.

AB - We report the crystal structures, thermal stability, and luminescence properties of three trimethylsulfonium halocuprates: (TMS)Cu2I3, and two new bromide phases: (TMS)Cu2Br3 and (TMS)2CuBr3. (TMS)Cu2I3 and (TMS)Cu2Br3 are isostructural and contain double chains of edge-sharing [CuX4] tetrahedra, whereas (TMS)2CuBr3 features isolated [CuBr3]2− triangular units. All compounds exhibit direct bandgaps and demonstrate photoluminescence at low temperature, with (TMS)Cu2Br3 demonstrating temperature-dependent dual emission behavior, observed for the first time among related hybrid halocuprates. Through comparative analysis of optical properties with structurally related halocuprates and DFT calculations, we elucidate the structure–property relationships governing the observed luminescence behavior of ACu2X3-type halocuprates.

UR - https://www.mendeley.com/catalogue/71c31b20-d46d-3481-bcbd-f4d2159d3e3f/

U2 - 10.1039/D5DT00852B

DO - 10.1039/D5DT00852B

M3 - Article

VL - 54

SP - 9088

EP - 9094

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 22

ER -

ID: 136064233